1、December 2016 English price group 13No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 71.100.80This standard has been
2、 included in the body of DVGW Technical Rules.!%b.“2596311www.din.deDIN EN 12678Chemical used for treatment of water intended for human consumption Potassium peroxomonosulfate;English version EN 12678:2016,English translation of DIN EN 12678:2016-12Produkte zur Aufbereitung von Wasser fr den menschl
3、ichen Gebrauch Kaliumperoxomonosulfat;Englische Fassung EN 12678:2016,Englische bersetzung von DIN EN 12678:2016-12Produits chimiques utiliss pour le traitement de leau destine la consommation humaine Peroxomonosulfate de potassium;Version anglaise EN 12678:2016,Traduction anglaise de DIN EN 12678:2
4、016-12SupersedesDIN EN 12678:200810www.beuth.deDocument comprises 28 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.12.16 DIN EN 12678:2016-12 2 A comma is used as the decimal marker. National foreword This document (EN 12678:
5、2016) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was DIN-Normenausschuss Wasserwesen (DIN Standards Committee Water Practice), DIN-DVGW Joint Working Committee NA 119-07-13 AA Aufbereitungss
6、toffe und -anlagen. Users of this standard are advised of the reservations stated in the Introduction of the European Standard and should note that national regulations exist in Germany dealing with water for human consumption, in particular the Trinkwasserverordnung (TrinkwV 2001) (German Drinking
7、Water Ordinance). The DIN Standards corresponding to the International Standards referred to in this document are as follows, whereby EN ISO Standards are only listed below if these have not been published as DIN EN ISO Standards with the same number: EN ISO 3696 DIN ISO 3696 Amendments This standar
8、d differs from DIN EN 12678:2008-10 as follows: a) a NOTE stating that potassium peroxomonosulfate is to comply with the EU Biocides Regulation has been added; b) the risk and safety labelling (Subclause 6.2) has been updated in accordance with EU Regulation 1272/2008; c) normative references have b
9、een updated. Previous editions DIN EN 12678: 2000-09, 2008-10 National Annex NA (informative) Bibliography DIN ISO 3696, Water for analytical laboratory use Specification and test methods Verordnung ber die Qualitt von Wasser fr den menschlichen Gebrauch (Trinkwasserverordnung TrinkwV 2001) (German
10、Drinking Water Ordinance), as of 10 March 2016 (BGBI. I p. 459)*)*)Obtainable from: Bundesministerium der Justiz (German Federal Ministry of Justice) (Internet: http:/www.gesetze-im-internet.de). EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 12678 May 2016 ICS 71.100.80 Supersedes EN 12678:20
11、08English Version Chemical used for treatment of water intended for human consumption - Potassium peroxomonosulfate Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Peroxomonosulfate de potassium Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch
12、 - Kaliumperoxomonosulfat This European Standard was approved by CEN on 18 March 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists
13、 and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under t
14、he responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugo
15、slav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN
16、DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 12678:2016 EEN 12678:2016 (E) 2 Contents Page European foreword .
17、 4 Introduction 5 1 Scope 6 2 Normative references 6 3 Description 6 3.1 Identification 6 3.1.1 Chemical name . 6 3.1.2 Synonym or common name . 6 3.1.3 Relative molecular mass . 6 3.1.4 Empirical formula of triple salt 6 3.1.5 CAS Registry Number . 7 3.1.6 EINECS reference . 7 3.2 Commercial form .
18、 7 3.3 Physical properties of triple salt . 7 3.3.1 Appearance and odour 7 3.3.2 Density 7 3.3.3 Solubility in water . 7 3.3.4 Vapour pressure 7 3.3.5 Boiling point at 100 kPa . 7 3.3.6 Melting point . 7 3.3.7 Specific heat 7 3.3.8 Viscosity (dynamic) 7 3.3.9 Critical temperature 7 3.3.10 Critical p
19、ressure 8 3.3.11 Physical hardness . 8 3.4 Chemical properties . 8 4 Purity criteria . 8 4.1 General 8 4.2 Composition of commercial product 8 4.3 Impurities and main by-products . 8 4.4 Chemical parameters . 8 5 Test methods 9 5.1 Sampling . 9 5.2 Analysis . 9 5.2.1 Determination of potassium perox
20、omonosulfate (KHSO5) (active ingredient) . 9 5.2.2 Chemical parameters 12 6 Labelling - Transportation - Storage . 14 6.1 Means of delivery . 14 6.2 Labelling according to the EU Legislation 15 6.3 Transportation regulations and labelling . 15 6.4 Marking 15 6.5 Storage . 15 6.5.1 Generals . 15 6.5.
21、2 Long term stability . 15 DIN EN 12678:2016-12EN 12678:2016 (E) 3 6.5.3 Storage incompatibilities . 16 Annex A (informative) General information on potassium peroxomonosulfate . 17 A.1 Origin 17 A.1.1 Raw materials 17 A.1.2 Manufacturing process . 17 A.2 Use 17 A.2.1 Function . 17 A.2.2 Form in whi
22、ch it is used 17 A.2.3 Treatment dose . 17 A.2.4 Means of application 17 A.2.5 Secondary effects 17 A.2.6 Removal of excess product 18 Annex B (normative) General rules relating to safety 19 B.1 Rules for safe handling and use . 19 B.2 Emergency procedures . 19 B.2.1 First aid 19 B.2.2 Spillage . 19
23、 B.2.3 Fire . 19 Annex C (normative) Determination of arsenic, antimony and selenium (atomic absorption spectrometry hydride technique) 20 C.1 Safety precautions 20 C.2 General principle 20 C.3 Interferences 20 C.4 Reagents . 20 C.5 Apparatus 22 C.6 Procedure 24 C.6.1 Preparation of the apparatus .
24、24 C.6.2 Preparation of calibration solutions . 24 C.6.3 Preparation of test solutions and standard solutions . 24 C.6.4 Determination of arsenic with sodium borohydride . 24 C.6.5 Determination of selenium with sodium borohydride . 25 C.6.6 Determination of antimony with sodium borohydride 25 C.7 C
25、alculation. 25 Bibliography . 26 DIN EN 12678:2016-12EN 12678:2016 (E) 4 European foreword This document (EN 12678:2016) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national stand
26、ard, either by publication of an identical text or by endorsement, at the latest by November 2016, and conflicting national standards shall be withdrawn at the latest by November 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent right
27、s. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12678:2008. Significant technical difference between this edition and EN 12678:2008 is as follows: deletion of reference to EU Directive 67/548/EEC of June 27, 1967 in order
28、 to take into account the latest Regulation in force (see 3). According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estoni
29、a, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 12678:2016-12EN 12
30、678:2016 (E) 5 Introduction In respect of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of t
31、he Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE 1 Conformity with this European Standard does not confer or i
32、mply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. NOTE 2 This product is a biocide and needs to comply with the relevant legislation in force.
33、 In the European Union, at the time of publication, this legislation is REGULATION (EU) No 528/2012 1). DIN EN 12678:2016-12EN 12678:2016 (E) 6 1 Scope This European Standard is applicable to potassium peroxomonosulfate used for treatment of water intended for human consumption. It describes the cha
34、racteristics of potassium peroxomonosulfate and specifies the requirements and the corresponding test methods for potassium peroxomonosulfate. It gives information on its use in water treatment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this d
35、ocument and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1233, Water quality Determination of chromium Atomic absorption spectrometric methods
36、EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) EN ISO 12846, Water quality Determination of mercury Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) ISO 3165, Sampling of chemical products for industrial use Safety
37、in sampling ISO 6206, Chemical products for industrial use Sampling Vocabulary ISO 8213, Chemical products for industrial use Sampling techniques Solid chemical products in the form of particles varying from powders to coarse lumps ISO 8288, Water quality Determination of cobalt, nickel, copper, zin
38、c, cadmium and lead Flame atomic absorption spectrometric methods 3 Description 3.1 Identification 3.1.1 Chemical name Potassium peroxomonosulfate triple salt. 3.1.2 Synonym or common name Potassium peroxomonosulfate, Potassium monopersulfate, Potassium hydrogenperoxomonosulfate, Pentapotassium-bis(
39、peroxomonosulfate)bis(sulfate). 3.1.3 Relative molecular mass Triple salt: 614,76. (Active ingredient KHSO5: 152,17). 3.1.4 Empirical formula of triple salt K5H3S4O18(2 KHSO5.KHSO4.K2SO4). Active ingredient KHSO5. DIN EN 12678:2016-12EN 12678:2016 (E) 7 3.1.5 CAS Registry Number1)70693-62-8. 3.1.6 E
40、INECS reference2)274-778-7. 3.2 Commercial form Potassium peroxomonosulfate as commercial product exists as a triple salt comprising potassium peroxomonosulfate (2KHSO5) potassium hydrogen sulfate (KHSO4) and potassium sulfate (K2SO4). 3.3 Physical properties of triple salt 3.3.1 Appearance and odou
41、r The product is white, odourless, granular, free-flowing salt. 3.3.2 Density The bulk density of the product is approximately between 1 g/cm3and 1,2 g/cm3.3.3.3 Solubility in water The solubility of the product is: approximately 250 g/l at 20 C; approximately 300 g/l at 50 C; approximately 330 g/l
42、at 70 C. 3.3.4 Vapour pressure Not applicable. 3.3.5 Boiling point at 100 kPa3)Not applicable. 3.3.6 Melting point The product decomposes above 60 C. 3.3.7 Specific heat Not applicable. 3.3.8 Viscosity (dynamic) Not applicable. 3.3.9 Critical temperature Not applicable. 1) Chemical Abtracts Service
43、Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. 3) 100 kPa = 1 bar DIN EN 12678:2016-12EN 12678:2016 (E) 8 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties Potassium peroxomonosulfate is a powerful oxidizing
44、agent. Aqueous solutions of the product exhibit a strongly acid reaction; a mass fraction solution of 3 % has a pH value of 2 at 20 C. The standard reduction potential E0of potassium peroxomonosulfate for the reaction: HSO5-+ 2H+ 2e- HSO4-+ H2O (1) is: + 1,82 V at 25C 4 Purity criteria 4.1 General T
45、his European Standard specifies the minimum purity requirements for potassium peroxomonosulfate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impuritie
46、s may be present and, if so, this shall be notified to the user and when necessary to the relevant authorities. Users of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for human consumption, taking into accou
47、nt raw water quality, required dosage, contents of other impurities and additives used in the product not stated in the product standard. Limits have been given for impurities and chemicals parameters where these are likely to be present in significant quantities from the current production process
48、and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. 4.2 Composition of commercial product The commercial product shall contain KHSO5(potassium peroxomonosulfate) at a
49、mass fraction greater than 45 percent or the manufacturers declared values. Typical composition in mass fraction should be approximately: 45 % potassium peroxsomonosulfate (KHSO5), 25 % potassium hydrogen sulfate (KHSO4), and 30 % potassium sulfate (K2SO4). 4.3 Impurities and main by-products See 4.1. 4.4 Chemical parameters NOTE For the purpose of this European Standard, “chemical parameters” are those defined in the EU Directive
