1、September 2014Translation by DIN-Sprachendienst.English price group 15No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I
2、CS 13.060.20; 67.250!%:D“2239633www.din.deDDIN EN 12873-1Influence of materials on water intended for human consumption Influence due to migration Part 1: Test method for factory-made products made from orincorporating organic or glassy (porcelain/vitreous enamel) materials;English version EN 12873-
3、1:2014,English translation of DIN EN 12873-1:2014-09Einfluss von Materialien auf Trinkwasser Einfluss infolge der Migration Teil 1: Prfverfahren fr fabrikmig hergestellte Produkte aus oder mit organischen oderglasartigen Materialien (Emails/Emaillierungen);Englische Fassung EN 12873-1:2014,Englische
4、 bersetzung von DIN EN 12873-1:2014-09Influence des materiaux en contact avec leau destine la consommation humaine Influence de la migration Partie 1: Mthode dessai des matriaux de fabrication industrielle constitus de oucontenant des matriaux organiques ou vitreux (emaux vitrifis);Version anglaise
5、EN 12873-1:2014,Traduction anglaise de DIN EN 12873-1:2014-09SupersedesDIN EN 12873-1:2004-04www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 35 pages08.14 DIN EN 12873-1:2014-09 2 A comma is used as the decimal marker. National foreword
6、 This document (EN 12873-1:2014) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (DIN Standards Committee Water Practice), Working Committee NA 119-04-14 AA We
7、rkstoffe und Bauteile im Kontakt mit Trinkwasser (CEN/TC 164/WG 3). Amendments This standard differs from DIN EN 12873-1:2004-04 as follows: a) procedures for testing porcelain/vitreous enamel materials have been included; b) test temperatures have been defined more precisely; c) the use of chromic
8、acid has been removed because of safety concerns; d) the examples of extended collection and analysis of migration waters are now more systematic; e) the standard has been editorially revised. Previous editions DIN EN 12873-1: 2004-04 EN 12873-1 July 2014 ICS 13.060.20; 67.250 Supersedes EN 12873-1:
9、2003English Version Influence of materials on water intended for human consumption - Influence due to migration - Part 1: Test method for factory-made products made from or incorporating organic or glassy (porcelain/vitreous enamel) materials Influence des matriaux en contact sur leau destine lacons
10、ommation humaine - Influence de la migration - Partie 1:Mthode dessai des matriaux de fabrication industrielleconstitus de ou contenant des matriaux organiques ouvitreux (maux vitrifis)Einfluss von Materialien auf Trinkwasser - Einfluss infolge der Migration - Teil 1: Prfverfahren fr fabrikmig herge
11、stellte Produkte aus oder mit organischen oder glasartigen Materialien (Emails/Emaillierungen) This European Standard was approved by CEN on 14 May 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the sta
12、tus of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, G
13、erman). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croa
14、tia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUn
15、ited Kingdom. CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 12873-1:2014 EEUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMIT
16、EE FR NORMUNGEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 12873-1:2014 (E) 2 Contents PageForeword 4 Introduction . 5 1 Scope 6 2 Normative references 6 3 Terms and definitions . 6 4 Principle 8 5 Reagents . 8 5.1 Waters to be used for testing . 8 5.2 Cleaning liquids for glassware . 9 5.3 Othe
17、r reagents . 9 6 Apparatus . 9 7 Test samples and test pieces . 9 7.1 Sampling, transport and storage of test samples 9 7.2 Test piece preparation 10 7.2.1 General 10 7.2.2 Pipes and hoses. 10 7.2.3 Fittings and ancillaries 10 7.2.4 Factory applied linings (excluding glassy materials) 11 7.2.5 Geome
18、mbranes 11 7.2.6 Glassy materials 11 7.2.7 Other homogeneous products . 11 7.2.8 Other non-homogeneous products . 11 7.3 Surface area-to-volume ratio (S/V) . 12 8 Pre-treatment of test pieces . 12 8.1 General 12 8.2 Test pieces to be tested at (23 2) C (Cold water test) 12 8.2.1 Flushing 12 8.2.2 St
19、agnation with test water 12 8.3 Test pieces to be tested at elevated temperature (60 C and/or 85 C) 13 8.3.1 Flushing 13 8.3.2 Stagnation with test water at elevated temperature . 13 8.4 Prewashing . 13 9 Test procedure . 13 9.1 Migration of substances . 13 9.1.1 General 13 9.1.2 Cold water test pro
20、cedure 13 9.1.3 Elevated temperature test procedure 14 9.2 Procedural blank tests 14 9.3 Analysis 14 10 Calculation of test results . 14 10.1 Calculation of the concentration of the substances in the migration water . 14 10.2 Calculation of the migration rate of the measured substances 15 11 Test re
21、port 15 11.1 Content of the test report 15 11.2 General information . 15 DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 3 11.3 Information on the test procedure . 1611.4 Test results 17 Annex A (normative) Arrangement for flushing pipes with nominal size greater than DN 80 18 Annex B (informative) Additi
22、onal procedures for testing non-homogeneous products and pipes with nominal size greater than DN 80 21 B.1 Arrangements for testing 21 B.2 Flushing of the test piece . 21 B.3 Blank test 21 B.4 Sealing 21 B.5 Calculation of the surface area-to-volume ratio (S/V) value for test arrangement 1 24 Annex
23、C (informative) Examples of extended collection and analysis of migration waters . 26 Annex D (informative) Procedural tests using standard additions (positive controls) . 28 Annex E (informative) Flow diagrams for migration test procedure for cold water temperature and elevated temperature 29 Annex
24、 F (informative) Description of a cell system for testing glassy materials . 31 Bibliography 33 DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 4 Foreword This document (EN 12873-1:2014) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This Eur
25、opean Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2015, and conflicting national standards shall be withdrawn at the latest by January 2015. Attention is drawn to the possibility that some of the el
26、ements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12873-1:2003. The major revisions of EN 12873-1:2003 are: the inclusion of procedures for testing glassy (porcelain
27、/vitreous enamel) materials. This inclusion enabled an improvement of the title of the standard; the test temperatures, outlined in Clause 4 Principle, are more specific; the use of chromic acid is removed because of safety concerns; the examples of extended collection and analysis of migration wate
28、rs (Annex C) are more systematic. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav
29、Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 5 Introduct
30、ion In respect of potential adverse effects on the quality of water intended for human consumption caused by the materials, it is called to mind that, while awaiting the adoption of verifiable European acceptance criteria, the relevant national regulations remain in force. This European Standard has
31、 been drawn up with the objective to describe a test method to determine the migration of substances from products made from, or incorporating, organic and glassy (porcelain/vitreous enamel) material for use in contact with water intended for human consumption. Annex A, which is normative, describes
32、 an alternative arrangement for flushing pipes having a nominal size greater than DN 80. Annex B, which is informative, describes additional procedures for testing non-homogeneous products and pipes having a nominal size greater than DN 80. Annex C, which is informative, describes a schedule for the
33、 preparation of migration waters. Annex D, which is informative, describes procedural tests using standard additions (positive controls). Annex E, which is informative, describes the migration test procedure in a schematic manner. Annex F, which is informative, provides information on a Cell system
34、for testing glassy materials. This European Standard will result in one of a series of standards on test methods which support the appropriate standards. This standard, Part 1, is the first in a series of standards for dealing with the influence of migration from materials on water intended for huma
35、n consumption, including: Part 1: Test method for factory-made products made from or incorporating organic and glassy (porcelain/vitreous enamel) materials; Part 2: Test method for non-metallic and non-cementitious site-applied products; Part 3: Test method for ion exchange and absorbent resins; Par
36、t 4: Test method for membrane water treatment systems. DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 6 1 Scope This European Standard specifies a procedure to determine the migration of substances from factory-made or factory-applied products for use in contact with water intended for human consumption.
37、 Materials used to make such products include plastics, rubber and glassy (porcelain/vitreous enamel) materials. This European Standard is applicable to products intended to be used under various conditions for the transport and storage of water intended for human consumption, including raw water us
38、ed for the production of water intended for human consumption. It covers the extraction by water of substances from the finished products. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For d
39、ated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 15826, Vitreous and porcelain enamels - Terminology EN ISO 7393-2, Water quality - Determination of free chlorine and total chlorine - Part 2:
40、 Colorimetric method using N, N-diethyl-1, 4-phenylenediamine, for routine control purposes (ISO 7393-2) EN ISO 28764, Vitreous and porcelain enamels - Production of specimens for testing enamels on sheet steel, sheet aluminium and cast iron (ISO 28764) 3 Terms and definitions For the purposes of th
41、is document, the following terms and definitions apply. 3.1 test technical operation that consists of the determination of one or more characteristics of a given product 3.2 test procedure specified technical method for performing a test 3.3 test report document that presents test results and other
42、information relevant to a test 3.4 test laboratory laboratory that performs tests 3.5 product manufactured item, in its finished form, that comes into contact with water intended for human consumption, or a component part of a manufactured item 3.6 homogeneous product a product where the water conta
43、ct surface is made from the same material as the remainder of the product DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 7 3.7 non-homogeneous product product where the water contact surface is made from a material that differs from those comprising the remainder of the product 3.8 fitting, ancillary com
44、plete functional unit made up of one or more components or materials, parts of which are in contact with water, e.g. taps, valves, water meters, water heaters, water filters, pipe connectors and flexible hose assemblies 3.9 test sample sample of a product submitted for testing 3.10 test piece test s
45、ample, or a part of it, that is tested 3.11 tap water water intended for human consumption (see also 5.1.1) 3.12 test water water used for migration testing (5.1.2 and 5.1.3) 3.13 prewashing water water used for prewashing (5.1.4) 3.14 blank water test water (5.1.2 and 5.1.3) which has been kept at
46、the same specified conditions as migration water (3.18) but without contact with test pieces 3.15 migration period period of time (24 h or 72 h, see Clause 4) in which the migration is carried out under specified conditions 3.16 migration movement of a substance or substances from test pieces into t
47、est water 3.17 migration water test water after exposure to a test piece under specified conditions 3.18 migration rate the mass of a measured substance or substances (in mg) migrating from one square decimetre of a test piece into the test water in one day at a specified temperature (C) 3.19 lining
48、 layer of material applied to a product and intended to come into contact with drinking water, e.g. the inside surfaces of pipes, fittings or storage vessels DIN EN 12873-1:2014-09EN 12873-1:2014 (E) 8 Note 1 to entry: Excluded are layers, such as coatings, not intended for contact with drinking wat
49、er, e.g. as applied to the outside surfaces of pipes and fittings for corrosion protection. 3.20 geomembranes flexible water impermeable membranes normally used to avoid draining of stored water into surrounding soil and sub-soil strata 3.21 glassy material porcelain, vitreous enamel coating (as defined in EN 15826) that is in contact with water and applied to a variety of products that produce or store water at elevated temperature 4 Princip