1、June 2007DEUTSCHE NORM English price group 7No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 91.080.40!,y$W“9860152www.
2、din.deDDIN EN 14629Products and systems for the protection and repair of concretestructures Test methods Determination of chloride content in hardened concreteEnglish version of DIN EN 14629:2007-06Produkte und Systeme fr den Schutz und die Instandsetzung von Betontragwerken Prfverfahren Bestimmung
3、des Chloridgehaltes in FestbetonEnglische Fassung DIN EN 14629:2007-06www.beuth.deDocument comprises 12 pages 09.07DIN EN 14629:2007-06 2 National foreword This standard has been prepared by CEN/TC 104 “Concrete and related products” (Secretariat: DIN, Germany). The responsible German body involved
4、in its preparation was the Normenausschuss Bauwesen (Building and Civil Engineering Standards Committee), Technical Committee NA 005-07-06 AA Schutz, Instandsetzung und Verstrkung. EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 14629March 2007ICS 91.100.30English VersionProducts and systems for t
5、he protection and repair of concretestructures - Test methods - Determination of chloride content inhardened concreteProduits et systmes pour la protection et la rparation desstructures en bton - Mthodes dessais - Mesurage dutaux de chlorure dun bton durciInstandsetzung von Betontragwerken - Prfverf
6、ahren -This European Standard was approved by CEN on 7 September 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographic
7、al references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN me
8、mber into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, L
9、atvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brusse
10、ls 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 14629:2007: EBestimmung des Chloridgehaltes in FestbetonProdukte und Systeme fr den Schutz und dieEN 14629:2007 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 5 2 Normati
11、ve references 5 3 Materials and apparatus5 3.1 Chemicals .5 3.2 Apparatus .5 4 Test procedure .6 4.1 Sampling.6 4.2 Grinding 7 4.3 Chemical analysis7 5 Test report 9 Bibliography 10 EN 14629:2007 (E) 3 Foreword This document (EN 14629:2007) has been prepared by Technical Committee CEN/TC 104 “Concre
12、te and related products”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2007, and conflicting national standards shall be withdrawn at the late
13、st by September 2007. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. It has been prepared by sub-committee 8 “Products and systems fo
14、r the protection and repair of concrete structures“ (Secretariat AFNOR). This European Standard is one of a series dealing with products and systems for the protection and repair of concrete structures. It describes a method for determining the chloride content of hardened concrete. According to the
15、 CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuani
16、a, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. EN 14629:2007 (E) 4 Introduction Steel reinforcement in concrete may be at risk of corrosion if the concrete is contaminated by chlorides. ENV 1504-9 defines t
17、he principles for protection and repair of concrete structures which have suffered or may suffer damage or deterioration and gives guidance on the selection of products and systems which are appropriate for this intended use. EN 1504-10 requires that the concentration of chlorides be considered when
18、 decisions about the removal of concrete are made. To establish whether there is a risk of corrosion of the steel reinforcement due to a higher chloride content within the concrete than the critical threshold value, the chloride content within the concrete cover and especially at the surface of the
19、steel reinforcement should be determined. Assessment may be made in the field using a variety of rapid test methods, which are not included in this standard. For accurate determination of chloride content, concrete samples need to be taken from the structure, prepared for chemical analysis and analy
20、sed. For chemical analysis of the concrete with respect to the chloride content either Volhards method or potentiometric titration are used as the reference methods. The chloride content may be expressed as a percentage of chloride by mass of cement or of concrete. The chloride content by mass of ce
21、ment may be derived using either an assumed value for the cement content of the concrete or a value which has been determined by chemical analysis or from construction records. EN 14629:2007 (E) 5 1 Scope This standard describes two methods for the determination of the total (free and bound) acid so
22、luble chloride content of hardened concrete or mortar. This information is intended for use in estimating the risk of chloride induced corrosion of the steel reinforcement. It may be used on samples of powder obtained either by drilling or from cores or fragments removed from concrete structures or
23、on other appropriate laboratory specimens. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amen
24、dments) applies. ISO 384, Laboratory glassware - Principles of design and construction of volumetric glassware 3 Materials and apparatus 3.1 Chemicals Deionised water with an electrical conductivity less than 2S/cm; Nitric acid (5 mol/l); Silver nitrate solution (0,02 mol/l); Ammonium thiocyanate (N
25、H4SCN) solution (0,1 mol/l); Ammonium ferric sulfate indicator solution (100 ml of a cold saturated solution of NH4Fe(SO4)2and 10 ml diluted nitric acid); 3,5,5-trimethylhexanol. NOTE For the potentiometric method, additional reagents may be required as specified by the electrode manufacturer to ens
26、ure the proper functioning of the electrode. These will be specified in the manufacturers instructions for the electrode. 3.2 Apparatus Crushing and grinding equipment (as required to prepare samples); 1,18 mm sieve or smaller; ventilated oven, controlled to maintain a temperature of (105 5) C; bala
27、nce capable of weighing up to 5 g to an accuracy of 1 mg; desiccator; burette, accurate to 0,05 ml; 250 ml glass beaker; magnetic stirrer; EN 14629:2007 (E) 6 heat source; vacuum filtering facility (Buchner funnel, filtration flask, medium-textured filter paper); 250 ml volumetric flask; pipettes ac
28、curate to 0,1 ml; if required, potentiometric titration facility (eg. Ag/AgCl electrode or similar, high resistance mV-meter, burette accurate to 0,05 ml or automatic titration equipment). All volumetric glassware shall be of class A accuracy as defined in ISO 384. 4 Test procedure 4.1 Sampling 4.1.
29、1 Sampling plan Sampling shall be in accordance with a plan prepared for the assessment or repair works by a suitably qualified person. When specifying the locations from which concrete is to be removed, specific care shall be taken of the load bearing capacity and reinforcement of the elements to b
30、e sampled. The plan shall take into account: the size, form, location, orientation, age and structural design of the structure; the results of visual surveys and any other available information about possible deterioration; the aggregate size and the heterogeneous nature of the concrete; exposure co
31、nditions, eg. salt water splash zones. On site checks shall be carried out to ensure that the concrete to be sampled is representative of the elements to be investigated and to confirm the location of reinforcement, which should not be damaged during sampling. The plan shall specify the approximate
32、number, location and depth of samples, including the depth increments. Typically increments do not exceed 25 mm, and it is usual to discard the surface layer. NOTE All holes or damage to the structure from sampling should be repaired or protected immediately to prevent further deterioration. 4.1.2 C
33、ollecting powder samples When drilling for powder samples the diameter of the drilling tool and therefore the number of drill holes required to obtain a sufficient sample size is determined by the maximum aggregate size. The powder is collected in separate depth increments, as specified in the sampl
34、ing plan. A minimum sample size of approximately 1 g is required. NOTE A drill diameter of 20 mm and two holes is normally sufficient to provide 1 g of powder per mm depth of increment. For concrete containing aggregates of maximum size of 20 mm a 20 mm drill should be used. A sample of at least 20
35、g is normally collected to ensure that it is representative of all of the concrete constituents and not just the aggregate. For larger aggregate sizes a larger drill diameter and sample size should be used. EN 14629:2007 (E) 7 4.1.3 Taking core samples A core diameter of 30 mm to 50 mm, depending on
36、 the maximum aggregate size, is usually recommended. Larger sizes may be required for large aggregate sizes. Cores shall be marked to indicate their location and orientation with respect to the original concrete surface. For determination of chloride profiles related to the distance from the concret
37、e surface, the cores may be cut into slices as specified in the sampling plan, without using cooling fluid, or may be ground in increments to obtain powder samples. 4.2 Grinding Where the sample requires grinding, it shall be dried in an oven to constant weight at (105 5) C and then allowed to cool
38、to room temperature, for example in a desiccator. When cool it shall be ground to a fine powder to pass a 1,18 mm sieve or smaller, and then homogenised. 4.3 Chemical analysis 4.3.1 General requirements The mass of samples shall be given in grams to the nearest 0,001 g and volumes given in millilitr
39、es to the nearest 0,05 ml. Approximately one sample out of every 20 samples (or one sample from every batch if less than 20 samples in the batch) shall be an interlaboratory standard concrete dust specimen of known chloride content. Occasional duplicate analyses, in which the same sample is analysed
40、 twice and the results compared, shall also be carried out to confirm the accuracy of the analysis. NOTE In selecting samples for duplicate analyses note should be taken of the results obtained, in particular of any results which fall outside general trends such as a reduction of chloride concentrat
41、ion with sample depth. 4.3.2 Dissolving chlorides Between 1 g and 5 g of concrete powder shall be weighed and placed in a 250 ml beaker, wetted with 50 ml water, and 10 ml of 5 mol/l nitric acid added, followed by 50 ml hot water. NOTE 1 Adding concentrated acid allows the lab to use a dispenser. Th
42、is saves time and avoids cross contamination. The addition of hot water quickens boiling and avoids spitting. The mixture shall be heated until boiling and boiled for at least 3 min, stirring continuously. If necessary the mixture shall be filtered immediately using medium-textured paper, washing th
43、e beaker, the stirrer and the residue on the filter. NOTE 2 It is not necessary to filter the solution for potentiometric titration. 4.3.3 Blank solution Carry out the same procedure with no concrete test portion. 4.3.4 Determination of chloride content 4.3.4.1 Volhards Method (Method A) Add 5 ml of
44、 silver nitrate solution by pipette into the test solution and stir vigorously to precipitate the chloride. EN 14629:2007 (E) 8 If the chloride content is high, and a large amount of precipitate is formed, a floculating agent such as 3,5,5-trimethylhexanol may be added. It can be added after the sil
45、ver nitrate, so the chloride level can be judged from the amount of precipitate formed. NOTE The smell of 3,5,5-trimethylhexanol is overpowering and it is recommended to use it as little as possible. Add 5 drops of indicator solution and titrate with the ammonium thiocyanate solution one drop at a t
46、ime, while continually agitating the solution until the faint reddish-brown coloration no longer disappears. Record the volume V1of solution used in the titration. An early end-point, at less than 1 ml of ammonium thiocyanate addition, indicates that the test solution demands more silver nitrate sol
47、ution than the 5,0 ml already added. In this case a further 5 ml of AgNO3shall be added and the titration continued until the end point is reached a second time. Record the volume V1of solution used to reach the second end point. This procedure may be repeated up to three times. If the sample contai
48、ns too much chloride then repeat from the beginning (4.3.2) with a smaller sample mass. Calculate the chloride content as percent of chloride ion by mass of sample using the following formula: CC = 3.545 * f * (V2-V1) / m V1volume of the ammonium thiocyanate solution used in the titration ml; V2volu
49、me of the ammonium thiocyanate solution used in the blank titration ml; m mass of the concrete sample g; f molarity of silver nitrate solution. 4.3.4.2 Potentiometric titration (Method B) The chloride content is determined with 0,1 M silver nitrate solution in a potentiometric titration. Consumption of silver nitrate solution (V3) in the titration is noted. The first derivative method is to be used. First derivative is a technique of adding small aliquots of titrant to the sample, recording the potential
