1、June 2007DEUTSCHE NORM English price group 7No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 75.160.10!,y6;“9861924www.
2、din.deDDIN EN 15536Derivatives from coal pyrolysis Coal tar based oils: wash oils Specifications and test methodsEnglish version of DIN EN 15536:2007-06Derivate der Kohlenpyrolyse Steinkohlenteerle: Waschle Anforderungen und PrfverfahrenEnglische Fassung DIN EN 15536:2007-06www.beuth.deDocument comp
3、rises 10 pages 09.07DIN EN 15536:2007-06 2 National foreword This standard has been prepared by CEN/TC 317 “Derivatives from coal pyrolysis” (Secretariat: IBN/BIN, Belgium). The responsible German body involved in its preparation was the Normenausschuss Materialprfung (Materials Testing Standards Co
4、mmittee, Technical Committee NA 062-02-81 AA Prfverfahren fr Kohlen-stoff und Graphit. The DIN Standard corresponding to the International Standard referred to in the EN is as follows: ISO 3733 DIN ISO 3733 National Annex NA (informative) Bibliography DIN ISO 3733, Petroleum products and bituminous
5、materials Determination of water Distillation method EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 15536March 2007ICS 75.160.10English VersionDerivatives from coal pyrolysis - Coal tar based oils: wash oils -Specifications and test methodsProduits drivs de la pyrolyse de la houille - Huiles dego
6、udron de houille: huiles de lavage - Caractristiques etmthodes dessaisDerivate der Kohlenpyrolyse - Steinkohlenteerle:Waschle - Anforderungen und PrfverfahrenThis European Standard was approved by CEN on 4 February 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which
7、stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standar
8、d exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standard
9、s bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
10、EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15536:2007: EEN 15536:2007
11、(E) 2 Contents Foreword3 1 Scope 4 2 Normative references 4 3 Terms and Definitions .4 4 Sampling.4 5 Specifications and test methods5 Annex A (informative) Usage warnings.6 A.1 Compostion Data on components 6 A.2 First aid measures .6 A.3 Handling and storage 6 A.4 Disposal considerations .7 Biblio
12、graphy 8 EN 15536:2007 (E) 3 Foreword This document (EN 15536:2007) has been prepared by Technical Committee CEN/TC 317 “Derivatives from coal pyrolysis”, the secretariat of which is held by IBN/BIN. This European Standard shall be given the status of a national standard, either by publication of an
13、 identical text or by endorsement, at the latest by September 2007, and conflicting national standards shall be withdrawn at the latest by September 2007. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this Eu
14、ropean Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United K
15、ingdom. EN 15536:2007 (E) 4 1 Scope This European Standard specifies and defines test methods for coal tar wash oils. Annex A specifies usage warnings for industrial purposes. The main purposes of these oils are to dissolve hydrocarbon derivatives in coke oven gas to clean greasy metal pieces. 2 Nor
16、mative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1014-1, Wood preservatives C
17、reosote and creosoted timber Methods of sampling and analysis Part. 1: Procedure for sampling creosote EN 13991: 2003, Derivatives from coal pyrolysis Coal tar based oils: creosotes Specifications and tests methods EN ISO 3405, Petroleum products Determination of distillation characteristics at atmo
18、spheric pressure (ISO 3405:2000) EN ISO 3675, Crude petroleum and liquid petroleum products Laboratory determination of density Hydrometer method (ISO 3675:1998) ISO 760, Determination of water Karl Fischer method (General method) DIN 51405,2004-01 Testing of mineral oil hydrocarbons, similar liquid
19、s and solvents for paints and varnishes Analysis by gas chromatography General working principles 3 Terms and Definitions For the purposes of this European Standard, the following term and definition applies. 3.1 wash oil common commercial name for a coal tar distillation cut or a preparation based
20、on several distillates of coal tar used to dissolve hydrocarbons in various areas of application NOTE Wash oil consists primarily of aromatic hydrocarbons, tar acids and tar bases 4 Sampling Samples for assessing the characteristics listed in Table 1 shall be in accordance with EN 1014-1. EN 15536:2
21、007 (E) 5 5 Specifications and test methods Table 1 Specifications and test methods for wash oils Parameters Test methods Water content (% m/m) Distillation range (C) Starting point 90 % m/m Crystallization temperature (C) Naphthalene content (%) Density at 20C (kg/m3) 150 360 10 10 1 000 to 1 080 I
22、SO 760aEN ISO 3405 EN13991: 2003, Annex A DIN 51405bEN ISO 3675 aAlternatively, ISO 3733 may be used. bAlternatively, ASTM E-260 may be used EN 15536:2007 (E) 6 Annex A (informative) Usage warnings1)A.1 Compostion Data on components CAS. N Designation: not applicable Identification number(s): EINECS
23、 Number: not applicable. EU Number: not applicable. Description: Complex mixture of polynuclear aromatic and heterocyclic hydrocarbons. Dangerous components: See MSDS. A.2 First aid measures General information: instantly remove any clothing spoiled by the product. After inhalation: Supply fresh air
24、 and consult a doctor in case of symptoms. After skin contact: Wash immediately with soap and water and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: In case of persistent symptoms consult doctor. A.3 Handling and storage Handling: I
25、nformation for safe handling: No special measures required; precautions against electrostatic charging. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and containers: No special requirements. Information about st
26、orage in one common storage facility: Keep the container tightly sealed. Further information about storage conditions: None. 1) The latest published edition of the Material Safety Data sheet of the product applies. EN 15536:2007 (E) 7 A.4 Disposal considerations Product: European waste catalogue: Th
27、e waste code classification is to be carried out according to the European Waste Catalogue (EWC) specific for each specific branch of industry and each type of process. Uncleaned packaging: Recommendation: Disposal should be according to official regulations. Recommended cleaning agent: Water, if necessary with a cleaning agent. EN 15536:2007 (E) 8 Bibliography 1 ISO 3733, Petroleum products and bituminous materials Determination of water Distillation method 2 ASTM E260-96 (2006) Standard Practice for Packed Column Gas Chromatography
