1、December 2015English price group 28No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 97.200.50!%Jqi“2397870www.din.de
2、DIN EN 71-5Safety of toys Part 5: Chemical toys (sets) other than experimental sets;English version EN 71-5:2015,English translation of DIN EN 71-5:2015-12Sicherheit von Spielzeug Teil 5: Chemisches Spielzeug (Sets) ausgenommen Experimentierksten;Englische Fassung EN 71-5:2015,Englische bersetzung v
3、on DIN EN 71-5:2015-12Scurit des jouets Partie 5: Jeux chimiques (coffrets) autres que les coffrets dexpriences;Version anglaise EN 71-5:2015,Traduction anglaise de DIN EN 71-5:2015-12SupersedesDIN EN 71-5:2013-08www.beuth.deDTranslation by DIN-Sprachendienst.In case of doubt, the German-language or
4、iginal shall be considered authoritative.Document comprises 82 pages12.15 DIN EN 71-5:2015-12 2 A comma is used as the decimal marker. National foreword This standard includes safety requirements. This document (EN 71-5:2015) has been prepared by Technical Committee CEN/TC 52 “Safety of toys” (Secre
5、tariat: DS, Denmark). The responsible German body involved in its preparation was DIN-Normenausschuss Sicherheits-technische Grundstze (DIN Standards Committee Safety Design Principles), Working Committee NA 095-05-01-02 AK Sicherheit von Spielzeug Chemische Eigenschaften. Amendments This standard d
6、iffers from DIN EN 71-5:2013-08 as follows: a) the term “ceramic and vitreous enamelling materials supplied in miniature workshop set” (previ-ously Subclause 3.4) has been deleted and the terms following have been renumbered; b) the requirements for “ceramic and vitreous enamelling materials supplie
7、d in miniature workshop set” (previously Clause 5) have been deleted; c) the chemical substance “phthalic acid esters with straight-chain aliphatic (C6 upwards except C8) alcohols and mixtures of these esters” in Table 1 (previously Table 2) has been deleted; d) the chemical substance “polyvinylpyrr
8、olidone homo and copolymers” has been added in Table 4 (previously Table 5); e) the chemical substances “acrylic homo and copolymers”, “hydrophilic polyurethane containing neither free isocyanate-groups nor aromatic amino-compounds”, “polymers and copolymers of monomers permitted for materials inten
9、ded to come into contact with foodstuffs”, “polyvinyl homo and copolymers”, “poly (vinyl alcohol) ”, “dextrin”, and “starch or modified starch” have been added in Table 7 (previously Table 8); f) the chemical substances “petroleum fraction (60 C to 140 C)” and “petroleum fraction (135 C to 210 C)” i
10、n Tables 11 and 15 (previously Tables 12 and 16) have been replaced by “petroleum fraction (35 C to 160 C)” and “hydrocarbons, C9 - C16, hydrotreated, dearomatized”; g) the test methods for determination of elements in ceramic and vitreous enamelling materials (previously Subclause 11.2) and for pht
11、halic acid esters have been deleted; h) Annex C, “Maximum permitted element concentrations for the compounds permitted in ceramic and vitreous enamelling materials” has been deleted; i) in Annex D, (previously Annex E) the information on phthalates (previously E.4) has been deleted; j) the Directive
12、s 67/548/EEC, 1999/45/EC and 76/768/EEC have been deleted from the Bibliography and the Regulation (EC) No 1223/2009 has been included. Previous editions DIN EN 71-5: 1993-07, 2013-08 DIN EN 71-5/A1: 2006-03 DIN EN 71-5/A2: 2009-10 EN 71-5 September 2015 ICS 97.200.50 Supersedes EN 71-5:2013English
13、Version Safety of toys - Part 5: Chemical toys (sets) other than experimental sets Scurit des jouets - Partie 5: Jouets chimiques (coffrets) autres que les coffrets dexpriences Sicherheit von Spielzeug - Teil 5: Chemisches Spielzeug (Sets) ausgenommen Experimentierksten This European Standard was ap
14、proved by CEN on 10 August 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nation
15、al standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own languag
16、e and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, H
17、ungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any
18、 form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-5:2015 EEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGContents PageEuropean foreword . 5 Introduction 7 1 Scope 8 2
19、 Normative references 8 3 Terms and definitions . 9 4 Plaster of Paris (gypsum) moulding sets . 10 4.1 Marking 10 4.2 First aid information . 10 4.3 Safety rules . 10 5 Oven-hardening plasticised PVC modelling clay sets 11 5.1 Chemical substances . 11 5.2 Marking 11 5.3 First aid information . 11 5.
20、4 Safety rules . 12 6 Moulding sets . 12 6.1 Polystyrene granules sets . 12 6.1.1 Chemical substances . 12 6.1.2 Marking 12 6.1.3 First aid information . 12 6.1.4 Safety rules . 13 6.2 Embedding sets . 13 6.2.1 General . 13 6.2.2 Packaging 13 6.2.3 Marking 13 6.2.4 First aid information . 13 6.2.5 S
21、afety rules . 13 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets 14 7.1 General . 14 7.2 Adhesives 14 7.2.1 Water-based adhesives 14 7.2.2 Solvent-based adhesives 17 7.3 Water-based paints or lacquers 20 7.3.1 General . 20 7.3.2
22、 Packaging 20 7.3.3 Marking 20 7.3.4 First aid information . 21 7.3.5 Safety rules . 21 7.4 Solvent-based paints, lacquers, thinners and cleaning solvents 21 7.4.1 General . 21 7.4.2 Packaging 22 7.4.3 Marking 22 7.4.4 First aid information . 22 DIN EN 71-5:2015-12 EN 71-5:2015 (E) 27.4.5 Safety rul
23、es 23 8 Marking 23 8.1 General . 23 8.2 Marking of the primary packaging . 23 8.2.1 General . 23 8.2.2 Manufacturers identification 23 8.2.3 Warning phrases . 23 8.3 Marking of individual containers and any packagings . 24 9 Instructions for use 24 9.1 General . 24 9.2 Contents list 24 9.3 Advice fo
24、r adult supervision . 24 9.4 Safety rules 25 9.5 Instructions for carrying out the activities . 25 9.6 Spills and disposal of chemicals 25 10 Test methods 26 10.1 General . 26 10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets 26 10.2.1 Principle . 26 1
25、0.2.2 Standards and reagents 26 10.2.3 Apparatus 27 10.2.4 Preparation of standard solutions . 28 10.2.5 Sampling 29 10.2.6 Sample preparation . 30 10.2.7 Procedure 30 10.2.8 Evaluation of results 31 10.2.9 Test report 33 10.3 Determination of the emission of benzene, toluene and xylenes from oven-h
26、ardening plasticised PVC modelling clay sets and polystyrene granules sets . 33 10.3.1 Principle . 33 10.3.2 Standards and reagents 34 10.3.3 Apparatus 34 10.3.4 Preparation of standard solutions . 36 10.3.5 Sampling 36 10.3.6 Sample preparation . 36 10.3.7 Procedure 36 10.3.8 Evaluation of results
27、36 10.3.9 Test report 37 10.3.10 Critical control points . 37 10.4 Determination of styrene content in polystyrene granules 37 10.4.1 Principle . 37 10.4.2 Standards and reagents 37 10.4.3 Apparatus 38 10.4.4 Preparation of the standard solutions 39 10.4.5 Sampling 39 10.4.6 Sample preparation . 39
28、10.4.7 Procedure 39 10.4.8 Evaluation of results 39 10.4.9 Test report 39 10.5 Determination of organic solvents . 40 10.5.1 General . 40 DIN EN 71-5:2015-12EN 71-5:2015 (E)310.5.2 Principle 42 10.5.3 Standards and reagents . 43 10.5.4 Apparatus 44 10.5.5 Preparation of the standard solutions . 46 1
29、0.5.6 Sampling 53 10.5.7 Sample preparation . 53 10.5.8 Procedure 55 10.5.9 Evaluation of results . 60 10.5.10 Test report 61 10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers an
30、d modifiers in solvent-based paints or lacquers 61 10.6.1 Principle 61 10.6.2 Determination of total extract . 62 10.6.3 Identification of nitrocellulose 63 10.6.4 Determination of plasticisers 65 10.6.5 Determination of film-forming agents . 65 10.6.6 Determination of the modifiers 71 10.6.7 Test r
31、eport 71 Annex A (normative) Environmental, health and safety precautions for using the methods of analysis . 72 Annex B (informative) Organic solvents . 73 Annex C (informative) Validation of test methods 75 Annex D (informative) Rationale . 76 D.1 General remark . 76 D.2 Primary packaging (4.1; 5.
32、2; 6.1.2; 6.2.2; 7.2.1.2.2; 7.2.2.6; 7.3.2; 7.4.3; 8.2) . 76 D.3 Minimum age (4.1; 5.2;6.1.2; 6.2.3; 7.2.1.2.3; 7.2.1.3.3; 7.2.2.6; 7.3.3; 7.4.3) . 76 D.4 Benzene (5.1, Table 2; 7.2.2.4, Table 11; 7.4.1, Table 15) . 76 D.5 Preservatives (6.2.1; 7.2.1.1; 7.3.1) . 77 Annex E (informative) Significant
33、technical changes between this European Standard and the previous version . 78 Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC 79 Bibliography . 80 DIN EN 71-5:2015-12 EN 71-5:2015 (E) 4European foreword This document (EN 7
34、1-5:2015) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by March 2016, and conflicting n
35、ational standards shall be withdrawn at the latest by March 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supers
36、edes EN 71-5:2013. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive 2009/48/EC, see informative Annex ZA, which is an integral pa
37、rt of this document. The significant changes from the previous edition of this standard are detailed in Annex E. This standard is Part 5 of the European Standard for safety of toys, EN 71. This Part 5 of the EN 71 series is intended to be read in conjunction with EN 71, Part 1, Part 2 and Part 3, pa
38、rticularly the Introduction and Clause 1 of Part 1. EN 71, Safety of toys, consists of the following parts: Part 1: Mechanical and physical properties; Part 2: Flammability; Part 3: Migration of certain elements; Part 4: Experimental sets for chemistry and related activities; Part 5: Chemical toys (
39、sets) other than experimental sets; Part 7: Finger paints Requirements and test methods; Part 8: Activity toys for domestic use; Part 9: Organic chemical compounds Requirements; Part 10: Organic chemical compounds Sample preparation and extraction; Part 11: Organic chemical compounds Methods of anal
40、ysis; Part 12: N-Nitrosamines and N-nitrosatable substances; Part 13: Olfactory board games, gustative board games, cosmetic kits and gustative kits; DIN EN 71-5:2015-12EN 71-5:2015 (E)5 Part 14: Trampolines for domestic use. NOTE 1 In addition to the above parts of EN 71, the following guidance doc
41、uments have been published: CEN Report, CR 14379, Classification of toys Guidelines, CEN Technical Report CEN/TR 15071, Safety of toys National translations of warnings and instructions for use in EN 71, and CEN Technical Report CEN/TR 15371, Safety of toys Replies to requests for interpretation of
42、EN 711, EN 712, and EN 718. NOTE 2 Words in italics are defined in Clause 3 (Terms and definitions). According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
43、Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the Un
44、ited Kingdom. DIN EN 71-5:2015-12 EN 71-5:2015 (E) 6Introduction This European Standard is intended to reduce the risks which may present health hazards to a child when the chemical toys are used as intended or in a foreseeable way, bearing in mind the behaviour of children. When using these chemica
45、l toys, potential risks should be kept to a minimum by inclusion of appropriate information to give special attention to possible hazards, risks and other problems. Chemical Abstract Service Registry Number (CAS) and European Inventory of Existing Chemical Substances Number (EINECS) given in various
46、 tables are provided for information purposes only. DIN EN 71-5:2015-12EN 71-5:2015 (E)71 Scope This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: those classifi
47、ed as dangerous by the EU-legislation applying to dangerous substances and dangerous mixtures 5; substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and any other chemical su
48、bstance(s) and mixture(s) delivered with the chemical toy. NOTE The terms “substance” and “mixture” are defined in the REACH regulation No. (EC)1907/2006 and in the CLP regulation (EC) No. 1272/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instru
49、ctions for use and first aid information. This Part of EN 71 applies to: plaster of Paris (gypsum) moulding sets; oven-hardening plasticised PVC modelling clay sets; polystyrene granules sets; embedding sets; adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets. 2 Normative references The following documents, in whole or in part, are normatively referenced
