1、October 2010 Translation by DIN-Sprachendienst.English price group 6No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS
2、 61.060!$kUU“1725050www.din.deDDIN EN ISO 20869Footwear Test methods for outsoles, insoles, lining and insocks Water soluble content (ISO 20869:2010)English translation of DIN EN ISO 20869:2010-10Schuhe Prfverfahren fr Laufsohlen, Brandsohlen, Futter und Decksohlen Wasserlslicher Anteil (ISO 20869:2
3、010)Englische bersetzung von DIN EN ISO 20869:2010-10Chaussures Mthodes dessai applicables aux premires de montage, aux doublures, aux premiresde propret et aux semelles dusure Dtermination des substances solubles dans leau (ISO 20869:2010)Traduction anglaise de DIN EN ISO 20869:2010-10SupersedesDIN
4、 EN 12748:1999-11www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 8 pages10.10 DIN EN ISO 20869:2010-10 2 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 309 “Footwea
5、r” (Secretariat: AENOR, Spain) in collaboration with Technical Committee ISO/TC 216 “Footwear”. The responsible German body involved in its preparation was the Normenausschuss Materialprfung (Materials Testing Standards Committee), Working Committee NA 062-04-52 AA Schuhe. Amendments This standard d
6、iffers from DIN EN 12748:1999-11 as follows: a) the number of the standard has been changed; b) normative references have been updated; c) the temperature of the muffle oven has been changed to (690 10) C. Previous editions DIN EN 12748: 1999-11 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN I
7、SO 20869 May 2010 ICS 61.060 Supersedes EN 12748:1999English Version Footwear - Test methods for outsoles, insoles, lining and insocks - Water soluble content (ISO 20869:2010) Chaussures - Mthodes dessai applicables aux premires de montage, aux doublures, aux premires de propret et aux semelles dusu
8、re - Dtermination des substances solubles dans leau (ISO 20869:2010) Schuhe - Prfverfahren fr Laufsohlen, Brandsohlen, Futter und Decksohlen - Wasserlslicher Anteil (ISO 20869:2010)This European Standard was approved by CEN on 22 April 2010. CEN members are bound to comply with the CEN/CENELEC Inter
9、nal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN memb
10、er. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN membe
11、rs are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
12、Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membe
13、rs. Ref. No. EN ISO 20869:2010: E2 DIN EN ISO 20869:2010-10 EN ISO 20869:2010 (E) Contents Page Foreword3 1 Scope 4 2 Normative references 4 3 Terms and definitions .4 4 Apparatus .4 5 Reagents.5 6 Sampling.5 7 Test method5 7.1 Shaking in water 5 7.2 Filtrate .5 7.3 Total water solubles 5 7.4 Sulfat
14、ed ash of water solubles.5 8 Expression of results 6 9 Test report 6 3 Foreword This document (EN ISO 20869:2010) has been prepared by Technical Committee CEN/TC 309 “Footwear“, the secretariat of which is held by AENOR, in collaboration with Technical Committee ISO/TC 216 “Footwear“. This European
15、Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2010, and conflicting national standards shall be withdrawn at the latest by November 2010. Attention is drawn to the possibility that some of the elemen
16、ts of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12748:1999. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following co
17、untries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Sl
18、ovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN ISO 20869:2010-10 EN ISO 20869:2010 (E) 1 Scope This International Standard specifies a method for the determination of the water soluble contents for outsoles, insoles, lining and insocks. 2 Normative references The following referen
19、ced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 17709, Footwear Sampling location, preparation and duration of con
20、ditioning of samples and test pieces ISO 18454, Footwear Standard atmospheres for conditioning and testing of footwear and components for footwear 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 water soluble matter quantity of all those subs
21、tances that, under certain conditions, are dissolved out of the material by water 3.2 water soluble inorganic substances sulfated ash of water soluble substances 3.3 water soluble organic substances difference between total water solubles and sulfated ash of water solubles 4 Apparatus The following
22、apparatus and material shall be used: 4.1 650 ml to 750 ml flask, with a wide neck and close-fitting glass or rubber stopper. 4.2 Fluted filter, 185 mm in diameter. 4.3 500 ml measuring vessel. DIN EN ISO 20869:2010-10 EN ISO 20869:2010 (E) 44.4 50 ml delivery pipette. 4.5 Quartz, platinum or porcel
23、ain evaporating basin, with flat bottom, to hold 50 ml, and suitable desiccators. 4.6 Funnel and 300 ml Erlenmeyer flask. 4.7 Appropriate shaker apparatus, capable of (50 10) rpm (0,867 0,167)s. 4.8 Thermometer. 4.9 Laboratory balance, with a sensitivity of 0,1 mg. 4.10 Analytical balance. 4.11 Suit
24、able oven, set to (102 2) C. 4.12 Water bath. 4.13 Muffle oven, set to (690 10) C. 5 Reagents 5.1 Distilled water. 5.2 1 mol/l sulfuric acid. 6 Sampling Test specimens shall be taken in accordance with ISO 17709. The material shall be ground and extracted with dichloromethane using a soxhlet apparat
25、us for a minimum of 30 refluxes of solvent. Condition the material for 24 h in accordance with ISO 18454. A minimum of two test pieces is necessary. 7 Test method 7.1 Shaking in water Shake mechanically at (50 10) rpm for 2 h, 10 g of conditioned ground and dichloromethane extracted material with 50
26、0 ml distilled water at (23 2) C in a wide-necked flask (4.1). 7.2 Filtrate Filter the contents of the flask through a fluted filter until clear. Discard the first 50 ml of the filtrate. Determine the soluble organic and inorganic substances in a further 50 ml of the subsequent filtrate. 7.3 Total w
27、ater solubles Evaporate on the water bath (4.12) until dry, exactly 50 ml of the filtrate in a previously weighed dish heated at (690 10) C, drying at (102 2) C for approximately 2 h; cool in the desiccator; and weigh quickly. Only one dish at a time shall be put into a small desiccator and at most
28、two into a large desiccator. Repeat drying until the reduction in mass amounts to less than 2 mg, but not for more than 8 h. DIN EN ISO 20869:2010-10 EN ISO 20869:2010 (E) 57.4 Sulfated ash of water solubles Thoroughly wet the residue obtained in accordance with 7.3 in the dish with a few drops of 1
29、 mol/l sulfuric acid (5.2), fume over a low flame until no sulfuric acid vapour is visible. Heat until red hot. Transfer to the muffle oven (4.13) at (690 10) C for 15 min. Cool in the desiccator and weigh as quickly as possible. Repeat the addition of acid, heating, cooling and weighing until the m
30、ass of the residue is constant. NOTE If the mass of water soluble inorganic matter is likely to be less than 2,0 %, a 100 ml or 200 ml aliquot portion should be used. 8 Expression of results 8.1 The total water solubles, mws, in per cent, is given by Equation (1) dwsc10 100rmm= (1) where rdis the ma
31、ss of dry residue, in grams; mcis the original mass of the component, in grams. 8.2 Sulfated ash of water solubles, msaws, in per cent, is given by Equation (2) sisawsc10 100rmm= (2) where rsiis the mass of sulfated residue from ignition, in grams. 8.3 Water soluble organic substances are the differ
32、ence between the total water soluble substances and the water soluble inorganic substances. The result is the average of the two values obtained for each test piece. All values are calculated on the basis of fat free conditional samples. 9 Test report The test report shall include, at least, the fol
33、lowing information: a) a reference to this International Standard, i.e. ISO 20869:2010; b) results, expressed in accordance with Clause 8, rounded up or down to one decimal place; c) full identification of the sample; d) reference to this method of test; e) date of testing. DIN EN ISO 20869:2010-10 EN ISO 20869:2010 (E) 6
