1、BRITISH STANDARD BS EN 1207:2005 Chemicals used for treatment of water intended for human consumption Tetrapotassium pyrophosphate The European Standard EN 1207:2005 has the status of a British Standard ICS 71.100.80 BS EN 1207:2005 This British Standard was published under the authority of the Stan
2、dards Policy and Strategy Committee on 31 March 2005 BSI 31 March 2005 ISBN 0 580 45794 X National foreword This British Standard is the official English language version of EN 1207:2005. It supersedes BS EN 1207:1998 which is withdrawn. The UK participation in its preparation was entrusted to Techn
3、ical Committee CII/59, Chemicals for drinking water treatment, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to
4、 in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions o
5、f a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or pro
6、posals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 17 and a back cover. The BSI copyright notice dis
7、played in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date Comments EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1207 March 2005 ICS 71.100.80 Supersedes EN 1207:1997 English version Chemicals used for treatment of water intended fo
8、r human consumption - Tetrapotassium pyrophosphate Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Pyrophosphate ttrapotassique Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Tetrakaliumdiphosphat This European Standard was approved by CEN
9、 on 3 February 2005. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards
10、 may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the
11、Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway
12、, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by an
13、y means reserved worldwide for CEN national Members. Ref. No. EN 1207:2005: EEN 1207:2005 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 5 2 Normative references 5 3 Description .6 4 Purity criteria8 5 Test methods9 6 Labelling - Transportation - Storage13 Annex A (informative) General inform
14、ation on tetrapotassium pyrophosphate.15 Bibliography 17 EN 1207:2005 (E) 3 Foreword This document (EN 1207:2005) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, ei
15、ther by publication of an identical text or by endorsement, at the latest by September 2005, and conflicting national standards shall be withdrawn at the latest by September 2005. This document supersedes EN 1207:1997. Significant technical differences between this edition and EN 1207:1997 are as fo
16、llows: a) deletion of reference to EU Directive 80/778/EEC of July 15, 1980 in order to take into account of the last Directive in force (see 1); b) replacement of ISO 5666-1 by EN 1483 and of EN 26595 by EN ISO 11969. According to the CEN/CENELEC Internal Regulations, the national standards organiz
17、ations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slov
18、enia, Spain, Sweden, Switzerland and United Kingdom. EN 1207:2005 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this document: a) this document provides no information as to whether the product may
19、be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this d
20、ocument does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this document is subject to regulation or control by National Authorities. EN 1207:2005 (E) 5 1 Scope This document is applicable to tetrapotassium
21、pyrophosphate used for treatment of water intended for human consumption. It describes the characteristics and specifies the requirements and the corresponding test methods for tetrapotassium pyrophosphate. It gives information on its use in water treatment. 2 Normative references The following refe
22、renced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references the latest edition of the referenced document (including any amendments) applies. EN 1483, Water quality Determination of mercury. EN ISO 3696, Water
23、for analytical laboratory use Specification and test methods (ISO 3696:1987). EN ISO 5961, Water quality - Determination of cadmium by atomic absorption spectrometry (ISO 5961:1994) . EN ISO 11885, Water quality - Determination of 33 elements by inductively coupled plasma atomic emission spectroscop
24、y (ISO 11885:1996). EN ISO 11969, Water quality - Determination of arsenic- Atomic absorption spectrometric method (hydride technique (ISO 11969:1996). ISO 2997, Phosphoric acid for industrial use - Determination of sulfate content - Method by reduction and titrimetry. ISO 3165, Sampling of chemical
25、 products for industrial use - Safety in sampling. ISO 3357, Sodium tripolyphosphate and sodium pyrophosphate for industrial use Determination of total phosphorus (V) oxide content - Quinoline phosphomolybdate gravimetric method. ISO 3360, Phosphoric acid and sodium phosphates for industrial use (in
26、cluding foodstuffs) - Determination of fluorine content - Alizarin complexone and lanthanum nitrate photometric method. ISO 6206, Chemical products for industrial use - Sampling - Vocabulary. ISO 6703-1, Water quality - Determination of cyanide Part 1: determination of total cyanide. ISO 8213, Chemi
27、cal products for industrial use - Sampling techniques - Solid chemical products in the form of particles varying from powders to coarse lumps. ISO 8288, Water quality - Determination of cobalt, nickel, copper, zinc, cadmium and lead Flame atomic absorption spectrometric methods. ISO 9174, Water qual
28、ity - Determination of chromium - Atomic absorption spectrometric methods. ISO 9965, Water quality - Determination of selenium - Atomic absorption spectrometric method (hydride technique). EN 1207:2005 (E) 6 3 Description 3.1 Identification 3.1.1 Chemical name Tetrapotassium pyrophosphate. 3.1.2 Syn
29、onym or common names Diphosphoric acid tetrapotassium salt: TKPP. 3.1.3 Relative molecular mass 330,0. 3.1.4 Empirical formula K 4 P 2 O 7 .3.1.5 Chemical formula K 4 P 2 O 7 .3.1.6 CAS Registry Number 1)7320-34-5. 3.1.7 EINECS reference 2)230-785-7. 3.2 Commercial form The tetrapotassium pyrophosph
30、ate is available in a number of different forms (see 3.3.1). Different commercial forms, solids or dissolved in water are possible. All concentrations mentioned refer to the active matter and shall be calculated accordingly. NOTE Tetrapotassium pyrophosphate can be a component of mixtures sold for w
31、ater treatment purposes. 3.3 Physical properties 3.3.1 Appearance Solid : the product is a white powder. Liquid : the product is a clear solution. 1) Chemical Abstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. EN 1207:2005 (E) 7 3.3.2 Density Solid :
32、 the bulk density of product is equal to 400 g/dm 3 . Liquid : the density of solution is 1,046 g/ml for a product concentration of 50 g/l at 20C. 3.3.3 Solubility in water The solubility in water is approximately 1 300 g/l at 25 C. 3.3.4 Vapour pressure Not applicable. 3.3.5 Boiling point at 100 kP
33、a 3)Not applicable. 3.3.6 Melting point For the solid product. 1 100 C. 3.3.7 Specific heat Not known. 3.3.8 Viscosity (dynamic) For the solid product it is not applicable. For the liquid the viscosity is equal to 5 mPa.s for a product concentration of 50 g/l. 3.3.9 Critical temperature Not applicab
34、le. 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties The solutions of tetrapotassium pyrophosphate have alkaline reactions. The pH value of a solution of a mass fraction of 1 % is approximately 10. 3) 100 kPa = 1 bar. EN 1207:2005 (E) 8 4 Puri
35、ty criteria 4.1 General This document specifies the minimum purity requirements for tetrapotassium pyrophosphate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing proces
36、s other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. NOTE Users of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for human consumption,
37、 taking into account raw water quality, required dosage, contents of other impurities and additives used in the products not stated in this document. Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantities from the current producti
38、on process and raw materials. If the production process or raw materials lead to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. 4.2 Composition of commercial product The product shall conform to the following requirements on a dry ma
39、ss basis: phosphate content expressed as P 2 O 5: mass fraction of (43 1,0) %; potassium content expressed as K 2 O : mass fraction of (57 1,0) %. 4.3 Impurities and main by-products The product shall conform to the requirements specified in Table 1. Table 1 Impurities Impurity Limit mg/kg of dry pr
40、oduct Sulfate (SO 4 2 - ) max. 500 Fluoride (F - ) max. 10 4.4 Chemical parameters Content of various chemical parameters depends on the origin of the raw materials, most of these elements are present only as traces. The product shall conform to the requirements specified in Table 2. EN 1207:2005 (E
41、) 9 Table 2 Chemical parameters Parameter Limit mg/kg of dry product Antimony (Sb) max. 3 Arsenic (As) max. 3 Cadmium (Cd) max. 3 Chromium (Cr) max. 10 Cyanide (CN) max. 5 Lead (Pb) max. 10 Mercury (Hg) max. 1 Nickel (Ni) max. 10 Selenium (Se) max. 3 NOTE Pesticides and polycyclic aromatic hydrocarb
42、ons are not relevant in tetrapotassium pyrophosphate. For parametric values of tetrapotassium pyrophosphate on trace metal content in drinking water, see 1. 5 Test methods 5.1 Sampling 5.1.1 General Observe the recommendations of ISO 3165 and take account of ISO 6206. 5.1.2 Solid Prepare the laborat
43、ory sample(s) required by the relevant procedure described in ISO 8213. 5.1.3 Liquid 5.1.3.1 Sampling from drums and bottles 5.1.3.1.1 General 5.1.3.1.1.1 Mix the contents of each container to be sampled by shaking the container, by rolling it or by rocking it from side to side, taking care not to d
44、amage the container or spill any of the liquid. 5.1.3.1.1.2 If the design of the container is such (for example, a narrow-necked bottle) that it is impracticable to use a sampling implement, take a sample by pouring after the contents have been thoroughly mixed. Otherwise, proceed as described in 5.
45、1.3.1.1.3. 5.1.3.1.1.3 Examine the surface of the liquid. If there are signs of surface contamination, take samples from the surface as described in 5.1.3.1.2. Otherwise, take samples as described in 5.1.3.1.3. 5.1.3.1.2 Surface sampling Take a sample using a suitable ladle. Lower the ladle into the
46、 liquid until the rim is just below the surface, so that the surface layer runs into it. Withdraw the ladle before it fills completely and allow any liquid adhering to the ladle EN 1207:2005 (E) 10 to drain off. If necessary, repeat this operation so that, when the other selected containers have bee
47、n sampled in a similar manner, the total volume of sample required for subsequent analysis is obtained. 5.1.3.1.3 Bottom sampling Take a sample using an open sampling tube, or a bottom-valve sampling tube, suited to the size of container and the viscosity of the liquid. When using an open sampling t
48、ube, close it at the top and then lower the bottom end to the bottom of the container. Open the tube and move it rapidly so that the bottom of the tube traverses the bottom of the container before the tube is filled. Close the tube, withdraw it from the container and allow any liquid adhering at the
49、 outside of the tube to drain off. When using a bottom-valve sampling tube, close the valve before lowering the tube into the container and then proceed in a similar manner to that when using an open sampling tube. 5.1.3.1.4 Sampling from tanks and tankers From each access point, take samples as follows: a) from the surface of the liquid, using a ladle as described in 5.1.3.1.2; b) from the bottom of the tank or tanker, using a sampling tube as described in 5.1.3.1.3 or
