1、BRITISH STANDARD BS EN 13099:2003 Transportable gas cylinders Conditions for filling gas mixtures into receptacles The European Standard EN 13099:2003 has the status of a British Standard ICS 23.020.30 BS EN 13099:2003 This British Standard, was published under the authority of the Standards Policy
2、and Strategy Committee on 14 January 2004 BSI 14 January 2004 ISBN 0 580 43250 5 National foreword This British Standard is the official English language version of EN 13099:2003. It partially supersedes BS 5355:1976. The UK participation in its preparation was entrusted by Technical Committee PVE/3
3、, Gas containers, to Subcommittee PVE/3/7, Gas cylinders (receptacle) operations, which has the responsibility to: A list of organizations represented on this subcommittee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European pu
4、blications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the
5、necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the
6、interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 31 and a back cover. The BS
7、I copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date CommentsEUROPEANSTANDARD NORMEEUROPENNE EUROPISCHENORM EN13099 December2003 ICS23.020.30 Englishversion TransportablegascylindersConditionsforfillinggasmixture
8、s intoreceptacles BouteillesgaztransportablesConditionsderemplissage desmlangesdegazdansdesrcipients OrstbeweglicheGasflaschenBedingungenfrdasFllen vonGasgemischeninGefe ThisEuropeanStandardwasapprovedbyCENon3November2003. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulate
9、theconditionsforgivingthisEurope an Standardthestatusofanationalstandardwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheCentralSecretariatortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,G
10、erman).Aversioninanyotherlanguagemadebytra nslation undertheresponsibilityofaCENmemberintoitsownlanguageandnotifiedtotheCentralSecretariathasthesamestatusast heofficial versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,CzechRepublic,Denmark,Finland,France,Germany,Greece, Hungary,Ice
11、land,Ireland,Italy,Luxembourg,Malta,Netherlands,Norway,Portugal,Slovakia,Spain,Sweden,SwitzerlandandUn ited Kingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:ruedeStassart,36B1050Brussels 2003CEN Allrightsofexploitationinanyformandb
12、yanymeansreserved worldwideforCENnationalMembers. Ref.No.EN13099:2003:EEN13099:2003(E) 2 Contents page Foreword. 3 1 Scope . 4 2 Normativereferences . 4 3 Termsanddefinitions. 4 4 Principlesandrequirementsforfillinggasmixturesintoreceptacles . 6 4.1 Generalrequirements(allgasmixtures) . . 6 4.2 Forc
13、ompressedgasmixtures. 7 4.3 Forliquefiedgasmixtures . 7 4.3.1 Withacriticaltemperatureupto+65C. . 7 4.3.2 Withacriticaltemperatureabove+65C . . 8 5 Fitmentofpressurereliefdevices . 8 6 Gastable. . 8 AnnexA (informative) Furtherinformativeguidancenotesconcerningcompetentpersonsandthe formulationandch
14、eckingofinstructionsforfillinggasmixtures 19 A.1 Introductorynote . . 19 A.2 Competentpersons(gasmixinginstructions) 1 9 A.3 Formulationandcheckingproceduresforinstructionsforfillinggasmixtures. 19 A.4 Keypointsrequiringspecialconsiderationwhenformulatinginstructionsforfillinggas mixtures . 20 A.5 C
15、ontentofinstructionsforfillinggasmixtures . 20 AnnexB (informative) Compatibilitydataforsomecommonlyusedgasmixturecomponents 22 AnnexC (informative) Indexofgasmixtures . 27 Bibliography . 31EN13099:2003(E) 3 Foreword Thisdocument(EN13099:2003)hasbeenpreparedbyTechnicalCommitteeCEN/TC23“Transportable
16、gas cylinders”,thesecretariatofwhichisheldbyBSI. ThisEuropeanStandardshallbegiventhestatusofanationalstandard,eitherbypublicationofanidentical textorbyendorsement,atthelatestbyJune2004,andconflictingnationalstandardsshallbewithdrawnat thelatestbyJune2004. ThisEuropeanStandardhasbeensubmittedforrefer
17、enceintotheRIDand/orinthetechnicalannexesofthe ADR.Thereforeinthiscontextthestandardslistedinthenormativereferencesandcoveringbasic requirementsoftheRID/ADRnotaddressedwithinthepresentstandardarenormativeonlywhenthe standardsthemselvesarereferredtointheRIDand/orinthetechnicalannexesoftheADR. Annexes
18、A,BandCareinformative. ThisdocumentincludesaBibliography. AccordingtotheCEN/CENELECInternalRegulations,thenationalstandardsorganizationsofthefollowing countriesareboundtoimplementthisEuropeanStandard:Austria,Belgium,CzechRepublic,Denmark, Finland,France,Germany,Greece,Hungary,Iceland,Ireland,Italy,L
19、uxembourg,Malta,Netherlands, Norway,Portugal,Slovakia,Spain,Sweden,SwitzerlandandtheUnitedKingdom.EN13099:2003(E) 4 1Scope ThisEuropeanStandardspecifiesthegeneralrequirementsforfillingreceptacles,manifoldedgascylinders (bundles),tubesanddrumswithgasmixtures.Gasmixingdataforsomecommonlyusedgasmixture
20、 componentsandfurtherguidancenotesaregivenininformativeannexes. Fillingrequirementsforthefollowingareexcludedfromthisstandard: cryogenic gases; LPG; beveragesandotherliquidfoodstuffs,pressurizedwithcarbondioxideorothergasorpreviousblended gasmixture; aerosolspressurizedwithagasorpreviouslyblendedgas
21、mixture,usedasapropellant; singlecomponentliquefiablegasesandliquidswhichhavebeenpressurizedwithagasforsafety reasonsorforthepurposeofproductwithdrawalfromtheliquidphase. 2 Normativereferences ThisEuropeanStandardincorporatesbydatedorundatedreference,provisionsfromotherpublications. Thesenormativere
22、ferencesarecitedattheappropriateplacesinthetext,andthepublicationsarelisted hereafter.Fordatedreferences,subsequentamendmentstoorrevisionsofanyofthesepublicationsapplyto thisEuropeanStandardonlywhenincorporatedinitbyamendmentorrevision.Forundatedreferencesthe latesteditionofthepublicationreferredtoa
23、pplies(includingamendments). ISO38071, CylindersforacetyleneBasicrequirementsPart1:Cylinderswithoutfusibleplugs. ISO38072, CylindersforacetyleneBasicrequirementsPart2:Cylinderswithfusibleplugs. ISO7866, GascylindersRefillableseamlessaluminiumalloygascylindersDesign,constructionand testing. ISO11621,
24、 GascylindersProceduresforchangeofgasservice. 3 Termsanddefinitions ForthepurposesofthisEuropeanStandard,thefollowingtermsanddefinitionsapply. 3.1 gas substance,which: a)at 50 Chasavapourpressuregreaterthan300kPa(3bar);or b) iscompletelygaseousat20Catthestandardpressureof101,3kPaEN13099:2003(E) 5 3.
25、2 gasmixture mixtureoftwoormorecomponents,eitherliquidorgaseous,whichhavebeendeliberatelyfilledforusefrom thereceptacleasablendedmixture,whichfulfilsthecriteriaforagas(see3.1) 3.3 compressedgasmixture 1) gasmixturewhichremainsasagasatatemperatureof50C 3.4 liquefiedgasmixture 1) gasmixturewhichwillli
26、quefyatatemperatureabove50C 3.5 gasreceptacles 3.5.1 cylinders transportablepressurereceptaclesofawatercapacitynotexceeding150l 3.5.2 tubes seamlesstransportablepressurereceptaclesofawatercapacityexceeding150landofnotmorethan3000l 3.5.3 pressuredrums weldedtransportablepressurereceptaclesofawatercap
27、acityexceeding150l andofnotmorethan1000l (e.g.cylindricalreceptaclesequippedwithrollinghoops,receptaclesonskidsandreceptaclesequippedin frames) 3.5.4 bundlesofcylinders(alsoknownasframes) transportableassembliesofcylinderswhichareinterconnectedbyamanifoldandheldfirmlytogether 3.6 fillingdegree(ADR 1
28、/RID2:fillingratio) massofgasinkgwhichcanbefilledinto1lofcylinderwatercapacity;normallyappliedtoliquefiedgases only NOTE Thewatercapacitystampedonthecylindercanapplytotheminimumdesignedwatercapacitywithout internalfittings,inwhichcase,thenetwatercapacityneedstobeascertained. 3.7 fillingdegreereferen
29、cetemperature temperatureatwhichtheliquiddensityistobeevaluatedforcalculatingthefillingdegree(see4.3) 3.8 developedpressure pressureachievedbythecontentsofagascylinderfilledaccordingtothestandardwhenraisedtothe referencetemperaturefordevelopedpressure NOTE Allpressuresaregiveninbargaugeunlessotherwi
30、sestated. 1) Gasmixturescontainingcondensablecomponentscanthemselvesbeclassifiedas“compressedgasmixtures“ or“liquefiedgasmixtures“dependingonthepartialpressure(s)ofthecondensablecomponent(s)inthemixture.EN13099:2003(E) 6 3.9 developedpressurereferencetemperature thatchosentorepresenttheexpectedmaxim
31、umtemperatureinnormalservice NOTE Allpressuresaregiveninbargaugeunlessotherwisestated. 3.10 settledpressure( P 15 ) pressureofthecontentofthecylinderat+15C NOTE Allpressuresaregiveninbargaugeunlessotherwisestated. 3.11 testpressure pressureatwhichthecylinderishydraulicallyorpneumaticallytested NOTE1
32、Thetestpressureshouldnotbeexceededunderanyforeseeablenormalconditions(forexampleduringfilling). NOTE2Allpressuresaregiveninbargaugeunlessotherwisestated. 3.12 criticaltemperature temperatureabovewhichthesubstancecannotexistintheliquidstate 3.13 pressurereliefdevice devicewhichisfittedtothecylinderor
33、cylindervalveanddesignedtorelievegaspressureintheeventof abnormalconditionsresultinginthedevelopmentofexcessivepressureinsidethereceptacle 3.14 compatible relatestotheinteractionofgasandreceptacles/cylinderequipment(partsincontactwithgas)underthe conditionsofuse.Hencethetermcompatibleimpliesasatisfa
34、ctorygas/cylinder/cylinderequipment combination.Thecomponentsofagasmixturearecalled“compatible“,ifatnormaltemperaturesduring transportandstoragenodangerousreactionsareliabletooccurintheblendedmixturewhichendangerthe safetyofthecylinder.Hencethetermcompatibleimpliesasatisfactorycombinationofgasmixtur
35、e componentswitheachotherandwiththecylinder/cylinderequipment. 3.15 tareweight sumofthemassesofthereceptaclesandotherfittingsnotremovedduringthecylinderfillingoperation,such asvalve,diptubeandanypermanentlyorsemipermanentlyfixedvalveprotectiondevice 3.16 competentpersonforgasmixinginstructions perso
36、nwhohasreceivedanappropriatelevelofformalscientificeducationtoenablehimtocarryouthiswork 4 Principlesandrequirementsforfillinggasmixturesintoreceptacles 4.1Generalrequirements(allgasmixtures) 4.1.1 Thegasmixturetobefilledshallbecompatiblewiththereceptacles,thecylindervalveandother fittingsthatmaybei
37、ncontactwiththegas. 4.1.2 Thegasmixturecomponentsshallnotreactwitheachother,duringoraftermixing,inanymanner whichmayaffecttheintegrityofthereceptaclesorwhichmaybedangerous.EN13099:2003(E) 7 4.1.3 Thereceptacles,whenpresentedforfilling,shallbewithinthespecifiedperiodforperiodicinspection andtest. 4.1
38、.4 Thereceptaclesshallbeequippedwithasuitablevalvewiththeappropriatevalveoutlet. 4.1.5 Thereceptaclesandvalveshallbeinserviceablecondition. 4.1.6 Thereceptaclesshallbecorrectlyidentifiedfortheintendedgasmixture. 4.1.7 Thereshallbewrittenfillinginstructionspreparedbycompetentpersonsavailableforeachga
39、s mixture(seeinformativeannexA). 4.2Forcompressedgasmixtures Themaximumsettledpressureshallbethelowerofthefollowingvalues: a) twothirdsofthetestpressure(forcompressedgases);or b) thepressure,which,whenthecylindercontentisraisedtothereferencetemperatureat65Cproducesa developedpressurethatdoesnotexcee
40、dthecylindertestpressure. 4.3Forliquefiedgasmixtures 4.3.1 Withacriticaltemperatureupto+65C Themaximumfillingdegreeshallbesuchthattheinternalpressureat+65Cdoesnotexceedthetest pressureofthereceptacles. Forgasesandgasmixtureswithinsufficientdata,themaximumpermissiblefillingdegree(FD)shallbe determine
41、dasfollows: h g 4 10 5 , 8 P d FD - where FDisthemax.permissiblefillingdegree(inkg/l) d g isthegasdensity(at+15C,1bar)(inkg/m) P h istheminimumtestpressure(inbar) Ifthedensityofthegasisunknown,themaximumpermissiblefillingdegreeshallbedeterminedasfollows: 338 10 3 h - R MM P FD where FDisthemax.permi
42、ssiblefillingdegree(inkg/l) P h h istheminimumtestpressure(inbar) MM isthemolarmass(ing/mol) Ris8,31451 10 2 bar l mol 1 K 1 (gasconstant)EN13099:2003(E) 8 4.3.2 Withacriticaltemperatureabove+65C Themaximumpermissiblemassofcontentsperlitrewatercapacity(fillingfactor)equals0,95timesthe densityoftheli
43、quidphaseat+50C.Inaddition,thevapourphaseshallnotdisappearbelow60C.Thetest pressureshallbeatleastequaltothevapourpressureoftheliquidat+65C,minus100kPa(1bar). 5 Fitmentofpressurereliefdevices Thefillingconditionsdefinedinthisstandardaredesignedtogivesafeoperationinnormalusewithouta pressurereliefdevice.Iffittedtheselectionofpressurereliefdeviceisatthediscretionofthegas supplier/cylinderowner. Pressurereliefdevicesshallnotbefittedtoreceptacl
