1、| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS EN 13132:2000 BS 2000-
2、466:2001 The European Standard EN 13132:2000 has the status of a British Standard ICS 75.160.20 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Methods of test for petroleum and its products BS 2000-466: Liquid petroleum products Unleaded petrol Determination of organic oxygen
3、ate compounds and total organically bound oxygen content by gas chromatography using column switching (Identical with IP 466/2001)This British Standard, having been prepared under the direction of the Sector Committee for Materials and Chemicals, was published under the authority of the Standards Co
4、mmittee and comes into effect on 15 August 2000 The Institute of Petroleum and BSI 08-2000 ISBN 0 580 36216 7 BS EN 13132:2000 Amendments issued since publication Amd. No. Date Comments National foreword This British Standard is the official English language version of EN 13132:2000. The UK particip
5、ation in its preparation was entrusted to Technical Committee PTI/13, Petroleum testing and terminology, which has the responsibility to: aid enquirers to understand the text; present to the responsible European committee any enquiries on the interpretation, or proposals for change, and keep the UK
6、interests informed; monitor related international and European developments and promulgate them in the UK. A list of organizations represented on this committee can be obtained on request to its secretary. The Institute of Petroleum publishes and sells all parts of BS 2000, and all BS EN petroleum t
7、est methods that would be part of BS 2000, both in its annual publication “Standard methods for analysis and testing of petroleum and related products and British Standard 2000 parts” and individually. Further information is available from: The Institute of Petroleum, 61 New Cavendish Street, London
8、 W1M 8AR. Tel: 020 7467 7100. Fax: 020 7255 1472. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by us
9、ing the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunit
10、y from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 21 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued.(8523($167$1$5 1250(8523e(11( (8523b,6&+(1250 (1
11、 0DUFK ,&6 (QJOLVKYHUVLRQ /LTXLGSHWUROHXPSURGXFWV8QOHDGHGSHWUROHWHUPLQDWLRQRI RUJDQLFRJHQDWHFRPSRXQGVDQGWRWDORUJDQLFDOOERXQG RJHQFRQWHQWEJDVFKURPDWRJUDSKXVLQJFROXPQVZLWFKLQJ 3URGXLWSpWUROLHUVOLTXLGHV(VVHQFHVDQVSORPE pWHUPLQDWLRQGHVFRPSRVpVRJpQpVRUJDQLTXHVHWGHOD WHQHXUWRWDOHHQRJqQHRUJDQLTXHSDUFKURPDW
12、RJUDSKLH HQSKDVHJDHXVHDYHFFRPPXWDWLRQGHFRORQQHV 7KLV(XURSHDQ6WDQGDUGZDVDSSURYHGE&(1RQ)HEUXDU &(1PHPEHUVDUHERXQGWRFRPSOZLWKWKH&(1&(1(/(&,QWHUQDO5HJXODWLRQVZKLFKVWLSXODWHWKHFRQGLWLRQVIRUJLYLQJWKLV(XURSH DQ 6WDQGDUGWKHVWDWXVRIDQDWLRQDOVWDQGDUGZLWKRXWDQDOWHUDWLRQ8SWRGDWHOLVWVDQGELEOLRJUDSKLFDOUHIHUHQFHV
13、FRQFHUQLQJV XFKQDWLRQDO VWDQGDUGVPDEHREWDLQHGRQDSSOLFDWLRQWRWKH&HQWUDO6HFUHWDULDWRUWRDQ&(1PHPEHU 7KLV(XURSHDQ6WDQGDUGHLVWVLQWKUHHRIILFLDOYHUVLRQV(QJOLVK)UHQFK*HUPDQ$YHUVLRQLQDQRWKHUODQJXDJHPDGHEWUD QVODWLRQ XQGHUWKHUHVSRQVLELOLWRID&(1PHPEHULQWRLWVRZQODQJXDJHDQGQRWLILHGWRWKH&HQWUDO6HFUHWDULDWKDVWKHVD
14、PHVWDWXVDVW KHRIILFLDO YHUVLRQV &(1PHPEHUVDUHWKHQDWLRQDOVWDQGDUGVERGLHVRI$XVWULD%HOJLXP&HFK5HSXEOLFHQPDUN)LQODQG)UDQFH*HUPDQ*UHHFH ,FHODQG,UHODQG,WDO/XHPERXUJ1HWKHUODQGV1RUZD3RUWXJDO6SDLQ6ZHGHQ6ZLWHUODQGDQG8QLWHG.LQJGRP (8523($1 &200,77( )25 67$1$5,=$7,21 &20,7e(8523e(1(1250$/,6$7,21 (8523b,6&+(6.20
15、,7()h5125081* &HQWUDO6HFUHWDULDWUXHGH6WDVVDUW%UXVVHOV &(1 $OOULJKWVRIHSORLWDWLRQLQDQIRUPDQGEDQPHDQVUHVHUYHG ZRUOGZLGHIRU&(1QDWLRQDO0HPEHUV 5HI1R(1(3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, )RUHZRUG 7KLV(XURSHDQ6WDQGDUGKDVEHHQSUHSDUHGE7HFKQLFDO&RPPLWWHH&(17&3HWUROHXP SURGXFWVOXEULFDQWVDQGUHODWHGSURGXFWVWKH6
16、HFUHWDULDWRIZKLFKLVKHOGE11, 7KLV(XURSHDQ6WDQGDUGVKDOOEHJLYHQWKHVWDWXVRIDQDWLRQDOVWDQGDUGHLWKHUESXEOLFDWLRQRIDQ LGHQWLFDOWHWRUEHQGRUVHPHQWDWWKHODWHVWE6HSWHPEHUDQGFRQIOLFWLQJQDWLRQDO VWDQGDUGVVKDOOEHZLWKGUDZQDWWKHODWHVWE6HSWHPEHU $FFRUGLQJWRWKH&(1&(1(/(&,QWHUQDO5HJXODWLRQVWKHQDWLRQDOVWDQGDUGVRUJDQLDWL
17、RQVRIWKH IROORZLQJFRXQWULHVDUHERXQGWRLPSOHPHQWWKLV(XURSHDQ6WDQGDUG$XVWULD%HOJLXP&HFK 5HSXEOLFHQPDUN)LQODQG)UDQFH*HUPDQ*UHHFH,FHODQG,UHODQG,WDO/XHPERXUJ 1HWKHUODQGV1RUZD3RUWXJDO6SDLQ6ZHGHQ6ZLWHUODQGDQGWKH8QLWHG.LQJGRP ,QWKLVVWDQGDUGDQQH$LVQRUPDWLYHDQGDQQH%LVLQIRUPDWLYH3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%
18、6, 6FRSH 7KLV(XURSHDQ6WDQGDUGVSHFLILHVDJDVFKURPDWRJUDSKLFPHWKRGXVLQJFROXPQVZLWFKLQJIRUWKH TXDQWLWDWLYHGHWHUPLQDWLRQRILQGLYLGXDORUJDQLFRJHQDWHFRPSRXQGVLQWKHUDQJH PP WR PP DQGWRWDORUJDQLFDOOERXQGRJHQXS PPLQXQOHDGHGSHWUROKDYLQJDILQDO ERLOLQJSRLQWQRWJUHDWHUWKDQ& 127(7KHILQDOERLOLQJSRLQWFDQEHPHDVXUHGEXVL
19、QJSU(1,62 127()XUWKHSXUSRVHVRIWKLV(XURSHDQ6WDQGDUGWKHWHUPV PPDQG 99 DUHXVHGWRUHSUHVHQWUHVSHFWLYHOWKHPDVVIUDFWLRQDQGWKHYROXPHIUDFWLRQ 7KLV(XURSHDQ6WDQGDUGLVDSSOLFDEOHWRWKHGHWHUPLQDWLRQRIRJHQFRQWDLQLQJFRPSRXQGVDQG WRWDORUJDQLFDOOERXQGRJHQLQXQOHDGHGSHWUROLQOLQHZLWKWKHUHOHYDQW(8LUHFWLYHV :$51,1*7KHXVHRI
20、WKLVVWDQGDUGFDQLQYROYHKDDUGRXVPDWHULDOVRSHUDWLRQVDQGHTXLSPHQW 7KLVVWDQGDUGGRHVQRWSXUSRUWWRDGGUHVVDOORIWKHVDIHWSUREOHPVDVVRFLDWHGZLWKLWVXVH,WLV WKHUHVSRQVLELOLWRIWKHXVHURIWKLVVWDQGDUGWRHVWDEOLVKDSSURSULDWHVDIHWDQGKHDOWKSUDFWLFHV DQGGHWHUPLQHWKHDSSOLFDELOLWRIUHJXODWRUOLPLWDWLRQVSULRUWRXVH 1RUPDWLYHUHI
21、HUHQFHV 7KLV(XURSHDQ6WDQGDUGLQFRUSRUDWHVEGDWHGRUXQGDWHGUHIHUHQFHSURYLVLRQVIURPRWKHU SXEOLFDWLRQV7KHVHQRUPDWLYHUHIHUHQFHVDUHFLWHGDWWKHDSSURSULDWHSODFHVLQWKHWHWDQGWKH SXEOLFDWLRQVDUHOLVWHGKHUHDIWHU)RUGDWHGUHIHUHQFHVVXEVHTXHQWDPHQGPHQWVWRRUUHYLVLRQVRI DQRIWKHVHSXEOLFDWLRQVDSSOWRWKLVVWDQGDUGRQOZKHQLQFRU
22、SRUDWHGLQLWEDPHQGPHQWRU UHYLVLRQ)RUXQGDWHGUHIHUHQFHVWKHODWHVWHGLWLRQRIWKHSXEOLFDWLRQUHIHUUHGWRDSSOLHV (1,62 3HWUROHXPOLTXLGV0DQXDOVDPSOLQJ,62LQFOXGLQJ $PHQGPHQW (1,62 3HWUROHXPOLTXLGV$XWRPDWLFSLSHOLQHVDPSOLQJ,62 (1,62 &UXGHSHWUROHXPDQGOLTXLGSHWUROHXPSURGXFWV/DERUDWRUGHWHUPLQDWLRQRI GHQVLW+GURPHWHUPH
23、WKRG,62 (1,62 :DWHUIRUDQDOWLFDOODERUDWRUXVH6SHFLILFDWLRQDQGWHVWPHWKRGV ,62 (1,62 &UXGHSHWUROHXPDQGOLTXLGRUVROLGSHWUROHXPSURGXFWVHWHUPLQDWLRQRIGHQVLW RUUHODWLYHGHQVLW&DSLOODUVWRSSHUHGSNQRPHWHUDQGJUDGXDWHGELFDSLOODU SNQRPHWHUPHWKRGV,62 (1,62 &UXGHSHWUROHXPDQGSHWUROHXPSURGXFWVHWHUPLQDWLRQRIGHQVLW2VFLOO
24、DWLQJ 8WXEHPHWKRG,62 SU(1,623HWUROHXPSURGXFWVHWHUPLQDWLRQRIGLVWLOODWLRQFKDUDFWHULVWLFVDWDWPRVSKHUHSUHVVXUH ,62,6 (8LUHFWLYH(&RXQFLOLUHFWLYHRQWKHDSSURLPDWLRQRIWKHODZVRIWKH0HPEHU6WDWHVFRQFHUQLQJWKH OHDGFRQWHQWRISHWURO(8LUHFWLYH(&RXQFLOLUHFWLYHRQFUXGHRLOVDYLQJVWKURXJKWKHXVHRIVXEVWLWXWHIXHO FRPSRQHQWVLQ
25、SHWURO3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, 3ULQFLSOH 2JHQFRQWDLQLQJRUJDQLFFRPSRXQGVDUHLVRODWHGIURPWKHVDPSOHXVLQJDILUVWFDSLOODUFROXPQ ,QDVHFRQGFDSLOODUFROXPQWKHRJHQFRQWDLQLQJRUJDQLFFRPSRXQGVDUHVHSDUDWHGDQG GHWHFWHGLQGLYLGXDOOXVLQJDIODPHLRQLDWLRQGHWHFWRU 127(*XLGDQFHRQWKHFROXPQVZLWFKLQJWHFKQLTXHLVJLYHQL
26、QDQQH% 5HDJHQWVDQGPDWHULDOV 8VHRQOUHDJHQWVRIUHFRJQLHGDQDOWLFDOJUDGHDQGZDWHUFRQIRUPLQJWRJUDGHRI (1,62 &DUULHUJDV +GURJHQKHOLXPRUQLWURJHQIUHHRIKGURFDUERQV :$51,1*+GURJHQLVHSORVLYHZKHQPLHGZLWKDLUDWFRQFHQWUDWLRQVUDQJLQJDSSURLPDWHO IURP 99WR 99$OOMRLQWVDQGOLQHVFDUULQJKGURJHQVKDOOEHPDGHJDVWLJKWWR SUHYHQWO
27、HDNDJHRIKGURJHQLQWRDFRQILQHGVSDFH 5HDJHQWVIRUWKHSUHSDUDWLRQRIFDOLEUDWLRQVDPSOHV 5HDJHQWVVKDOOEHQRWOHVVWKDQ PPSXUH &DOLEUDWLRQVDPSOHVPDEHFRPELQDWLRQVRIWKHIROORZLQJUHDJHQWV PHWKDQRO &+ 2+ PHWKODOFRKRO0(2+ HWKDQRO &+ &+ 2+ HWKODOFRKRO(72+ SURSDQRO &+ &+ &+ 2+ SURSODOFRKRO13$ SURSDQRO &+ &+2+ LVRSURSODO
28、FRKRO,3$ EXWDQRO &+ &+ 2+ EXWODOFRKRO1%$ EXWDQRO &+ &+2+&+ &+ VHFEXWODOFRKRO6%$ PHWKOSURSDQRO &+ &2+ WHUW EXWODOFRKRO7%$ PHWKOSURSDQRO &+ &+&+ 2+ LVREXWODOFRKRO,%$ SHQWDQRO &+ &+2+&+ &+ &+ VHFDPODOFRKRO6$ WHUW EXWOPHWKOHWKHU &+ &2&+ PHWKOWHUWLDUEXWOHWKHU07%( PHWKO WHUWSHQWOHWKHU &+ &2&+ &+ &+ WHUWLD
29、UDPOPHWKOHWKHU7$0( HWKO WHUW SHQWOHWKHU &+ &2&+ &+ &+ &+ HWKOWHUWLDUDPOHWKHU(7$( DFHWRQH &+ &2 EXWDQRQH &+ &+ &2&+ PHWKOHWKONHWRQH0(. WHUW EXWOHWKOHWKHU &+ &2&+ &+ HWKOWHUWLDUEXWOHWKHU(7%(3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, ,QWHUQDOVWDQGDUGV 8VHRQHRIWKHUHDJHQWVOLVWHGLQ,IDOORIWKHVHUHDJHQWVDUHOLNHOWREH
30、SUHVHQWLQWKHVDPSOH XQGHUWHVWXVHDGLIIHUHQWRUJDQLFRJHQDWHFRPSRXQGRIWKHVDPHSXULWDQGVLPLODUYRODWLOLW 3HWUROFRQWDLQLQJQRRUJDQLFRJHQDWHFRPSRXQGVRUQKHSWDQH 3HWUROZKLFKKDVEHHQHDPLQHGWRHQVXUHWKDWLWFRQWDLQVQRRUJDQLFRJHQDWHFRPSRXQGV GHWHFWDEOHEWKLVPHWKRGRUQKHSWDQH $SSDUDWXV 8VXDOODERUDWRUDSSDUDWXVDQGJODVVZDUHW
31、RJHWKHUZLWKWKHIROORZLQJ *DVFKURPDWRJUDSKLFDVVHPEO *DVFKURPDWRJUDSK SURYLGHGZLWKDPHDQVIRUFROXPQVZLWFKLQJHTXLSSHGZLWKD SURJUDPPDEOHRYHQWHPSHUDWXUHFRQWUROOHURUFRQWUROOHUVLQWKHFDVHRIGXDORYHQJDV FKURPDWRJUDSKVDQGDIODPHLRQLDWLRQGHWHFWRU), 127(,WLVUHFRPPHQGHGWKDWDVVWHPFRQVWUXFWHGHQWLUHORIJODVVIURPWKHVDPSOH
32、 LQMHFWLRQSRUWXSWRWKHGHWHFWRUVVWHPLVXVHGVLQFHSHWUROPDFRQWDLQRUJDQLFRJHQDWH FRPSRXQGVZKLFKFDQJLYHULVHWRFRUURVLRQDQGFKDQJHVRIUHWHQWLRQWLPHVLQVVWHPV FRQVWUXFWHGXVLQJPHWDOV 7ZRFDSLOODUFROXPQV 127(5HFRPPHQGHGFROXPQVDUHGHVFULEHGLQDQQH% 7KHFROXPQVVKDOOEHFRDWHGZLWKDVXLWDEOHSKDVHVRWKDWWKHUHTXLUHGUHVROXWLRQEH
33、WZHHQWKH FRPSRQHQWVDQGEHWZHHQWKHFRPSRQHQWVDQGWKHPDWULWREHGHWHUPLQHGVKDOOEHDWOHDVW DIWHUHOXWLRQIURPWKHVHFRQGFROXPQ 7KHUHVROXWLRQ 5EHWZHHQSHDNV$DQG%VHHILJXUHVKDOOEHFDOFXODWHGDVIROORZV % $ $ % Z Z W W 5 + = ZKHUH W $ LVWKHUHWHQWLRQWLPHRIFRPSRQHQW$LQV W % LVWKHUHWHQWLRQWLPHRIFRPSRQHQW%LQV Z $ LVWKHSHDNZ
34、LGWKDWKDOIKHLJKWRIFRPSRQHQW$LQV Z % LVWKHSHDNZLGWKDWKDOIKHLJKWRIFRPSRQHQW%LQV LVDIDFWRURULJLQDWLQJIURPDSHDNUHVROXWLRQHTXDWLRQ3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, .H 6WDUW =HUROLQH %DVHOLQH 7LPHDLV 7LPHDLV 127( W 1 LVWKHKROGXSWLPHHURRIWKHFROXPQLHWKHWLPHWDNHQIRUDQLQHUWFRPSRQHQW VXFKDVPHWKDQHWRWUDYHOWKUR
35、XJKWKHFROXPQZLWKRXWFKURPDWRJUDSKWDNLQJSODFH )LJXUH&DOFXODWLRQRIWKHUHVROXWLRQEHWZHHQSHDNV$DQG% HYLFHIRUWKHFRQWURORIWKHIORZRIFDUULHUJDV 5HFRUGHUDQGRULQWHJUDWRU $QDPSOLILHUDQGSRWHQWLRPHWULFUHFRUGLQJGHYLFHRUDQLQWHJUDWRURUGDWDSURFHVVRUVVWHPV JLYLQJDUHDYDOXHVFRUUHVSRQGLQJWRWKHSHDNDUHD ,QMHFWLRQGHYLFH 7HVW
36、VDPSOHFRQWDLQHU QRUPDOOZLWKDFDSDFLWRIEHWZHHQPODQGPOILWWHGZLWKD VHOIVHDOLQJUXEEHUVHSWXPFRDWHGZLWKSROWHWUDIOXRURHWKOHQH37)(3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, 6DPSOLQJ 8QOHVVRWKHUZLVHVSHFLILHGLQWKHFRPPRGLWVSHFLILFDWLRQVDPSOHVVKDOOEHWDNHQLQDFFRUGDQFH ZLWK(1,62RU(1,62DQGRULQDFFRUGDQFHZLWKWKHUHTXLUHPHQWVR
37、IQDWLRQDO VWDQGDUGVRUUHJXODWLRQVIRUWKHVDPSOLQJRISHWURO 3URFHGXUH 6HWWLQJXSWKHDSSDUDWXV *HQHUDO 3UHSDUHWKHHTXLSPHQWDQGVHWWKHWHVWFRQGLWLRQVLQDFFRUGDQFHZLWKWKHPDQXIDFWXUHUV LQVWUXFWLRQV &DUULHUJDV $GMXVWWKHSUHVVXUHDQGIORZUDWHRIWKHFDUULHUJDVWROHYHOVVXFKWKDWWKHUHVROXWLRQVDUHLQ DFFRUGDQFHZLWK &DOLEUDWLRQ
38、3UHSDUHWKHFDOLEUDWLRQVDPSOHEFRPELQLQJNQRZQPDVVHVRIRUJDQLFRJHQDWHFRPSRXQGV ZLWKWKHLQWHUQDOVWDQGDUGDQGGLOXWLQJWKHPWRDNQRZQPDVVZLWKWKHSHWURORUQKHSWDQH 127(7KHFDOLEUDWLRQVDPSOHVKRXOGFRQWDLQWKHVDPHRUJDQLFRJHQDWHFRPSRXQGVLQ VLPLODUSURSRUWLRQVDVSUHVHQWLQWKHVDPSOHXQGHUWHVW ,QMHFWDVXLWDEOHTXDQWLWRIWKHSUHSDUH
39、GFDOLEUDWLRQVDPSOHLQWRWKHJDVFKURPDWRJUDSKVXFKWKDW WKHFDSDFLWRIWKHFROXPQVDQGRWKHUFRPSRQHQWVLVQRWHFHHGHGDQGWKHOLQHDULWRIWKHGHWHFWRU LVQRWLPSDLUHG HWHUPLQHDQGUHFRUGWKHUHWHQWLRQWLPHV W L IRUDOOWKHFRPSRQHQWVLWREHHYDOXDWHG&DOFXODWH WKHFDOLEUDWLRQIDFWRU I L IRUDOOWKHFRPSRQHQWVLWREHHYDOXDWHGXVLQJWKHHTXDWLRQ
40、 P $ $ P I VW L VW L L = ZKHUH P L LVWKHPDVVLQJUDPVRIFRPSRQHQWLLQWKHFDOLEUDWLRQVDPSOH $ VW LVWKHSHDNDUHDLQPLFURYROWVHFRQGVRULQVTXDUHPLOOLPHWUHVRIWKHLQWHUQDO VWDQGDUG $ L LVWKHSHDNDUHDLQPLFURYROWVHFRQGVRULQVTXDUHPLOOLPHWUHVRIFRPSRQHQWL P VW LVWKHPDVVLQJUDPVRIWKHLQWHUQDOVWDQGDUGLQWKHFDOLEUDWLRQVDPSOH 5HFRUGWKHFDOLEUDWLRQIDFWRUIRUHDFKFRPSRQHQW3DJH (1 ,QVWLWXWHRI3HWUROHXPDQG%6, HWHUPLQDWLRQRIGHQVLW HWHUPLQHWKHGHQVLWDW& r V RIWKHVDPSOHLQDFFRUGDQFHZLWK(1,62 (1,62RU(1,62
