1、BS EN 1482-3:2016Fertilizers and liming materials Sampling and samplepreparationPart 3: Sampling of static heapsBSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN 1482-3:2016 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 148
2、2-3:2016.The UK participation in its preparation was entrusted to TechnicalCommittee CII/37, Fertilisers and related chemicals.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of
3、a contract. Users are responsible for its correctapplication. The British Standards Institution 2016. Published by BSI StandardsLimited 2016ISBN 978 0 580 89190 8ICS 65.080Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the au
4、thority of theStandards Policy and Strategy Committee on 31 August 2016.Amendments issued since publicationDate Text affectedBS EN 1482-3:2016EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1482-3 August 2016 ICS 65.080 English Version Fertilizers and liming materials - Sampling and sample prep
5、aration - Part 3: Sampling of static heaps Engrais et amendements minraux basiques - chantillonnage et prparation de lchantillon - Partie 3 : chantillonnage des tas statiques Dngemittel und Kalkdnger - Probenahme und Probenvorbereitung - Teil 3: Probenahme aus statischen Haufwerken This European Sta
6、ndard was approved by CEN on 12 June 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning s
7、uch national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its o
8、wn language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
9、 Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NOR
10、MUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 1482-3:2016 EBS EN 1482-3:2016EN 1482-3:2016 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scop
11、e 5 2 Normative references 5 3 Terms and definitions . 5 4 Sampling plans and quantitative data . 5 4.1 General 5 4.2 Characterization of the lot to be sampled 6 4.3 Sampling plan . 6 4.3.1 General 6 4.3.2 Elements of the sampling plan . 6 4.4 Determination of the volume/mass of the lot. 8 4.5 Deter
12、mination of sampling units and sampling points . 8 4.5.1 Determination of the number and location of the sampling units 8 4.5.2 Minimum total number of sampling units . 8 4.5.3 Determination of sampling units from which incremental samples shall be taken . 8 4.5.4 Determination of the minimum number
13、 of sampling points from which sub-samples are to be taken 8 4.6 Quantitative data . 8 4.6.1 Determination of the minimum mass of increments . 8 4.6.2 Mass of increments . 9 4.6.3 Aggregate/reduced and final samples . 9 5 Incremental sampling methods . 9 5.1 General 9 5.2 Sampling apparatus 9 5.3 Pr
14、ocedure 11 5.4 Aggregate and reduced samples . 12 6 Final samples . 12 6.1 Division into final samples . 12 6.2 Practical arrangements for final (laboratory) samples . 12 6.2.1 Final sample packaging materials . 12 6.2.2 Dealing with final samples 12 7 Sampling report 12 Annex A (informative) Determ
15、ination of mass/volume of a static heap 13 A.1 Volume of a conical heap without edgewise limitation 13 A.2 Volume of a storage box, partly filled (rectangular base, three flanks closed) . 13 A.3 Determination of the mass . 14 Annex B (informative) Alternative method according to GOST . 15 Bibliograp
16、hy . 16 BS EN 1482-3:2016EN 1482-3:2016 (E) 3 European foreword This document (EN 1482-3:2016) has been prepared by Technical Committee CEN/TC 260 “Fertilizers and liming materials”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, eit
17、her by publication of an identical text or by endorsement, at the latest by February 2017, and conflicting national standards shall be withdrawn at the latest by February 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN s
18、hall not be held responsible for identifying any or all such patent rights This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association. EN 1482 “Fertilizers and liming materials Sampling and sample preparation” consists of three par
19、ts: Part 1: Sampling; Part 2: Sample preparation; Part 3: Sampling of static heaps. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Rep
20、ublic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS
21、EN 1482-3:2016EN 1482-3:2016 (E) 4 Introduction The establishment of European Standards for methods of sampling and analysis is of utmost importance to guarantee a uniform application and control of the European legislation in all Member States. Standardized methods of sampling and analysis are esse
22、ntial elements in guaranteeing a high level of quality and safety of EC fertilizers for the benefit of purchasers. In order to avoid any improper use of the term “EC fertilizer” Member States are required to check the nutrient content of such fertilizers. To achieve this, representative sampling is
23、essential for reliable analytical results. Competent authorities have limited resources for conformity assessment and these are most efficiently deployed at the downstream end of the supply chain. The purpose of Regulation (EC) No 2003/2003 1 is to ensure that the fertilizer meets European requireme
24、nts and complies with the declaration of the required characteristics applied to it when delivered to a purchaser. EN 1482-1:2007 might not fully satisfy the needs of Member States when a large quantity of fertilizer is stored in a static heap that cannot be realistically put into motion. An evaluat
25、ion was requested to be carried out by CEN to see what, if any, static heaps of fertilizer could be representatively sampled at affordable costs see (see 3). The fundamental principle of representative sampling is that every particle has an equal chance of being sampled. This principle cannot easily
26、 be complied with in the case of bulk static heaps of solid fertilizers as a large proportion of the material cannot practically be reached by any sampling device. Wherever possible, this fertilizer should be sampled during transfer, during the building up of the heap, during dispatch or where it ca
27、n practically be moved solely for sampling purposes. However, in some cases, sampling in the way described is not practicable. The European Commission asked CEN/TC 260/WG 1 to draft a European Standard in response to mandate M/454, which requires the development of a method of sampling static heaps
28、that could not be sampled according to EN 1482-1:2007. This states that the sampling of static heaps should only be carried out when the product is in motion. In response to the mandate, sampling methods to sample static heaps have been developed and standardized as specified in this document. BS EN
29、 1482-3:2016EN 1482-3:2016 (E) 5 1 Scope This European Standard is applicable to the sampling of mineral fertilizers and liming materials supplied or ready for supply to third parties, as a lot or in smaller lots, where such supply or readiness for supply is subject to legal requirements. This Europ
30、ean Standard specifies plans and methods of sampling of a lot of solid fertilizer or liming material, if sampling in motion is not possible, to obtain samples from static bulk heaps in order to ascertain compliance with legal requirements, in particular in relation to the accuracy of compulsory or p
31、ermitted statutory declarations. The methods specified in this document are not applicable to obtain samples for physical analysis or for the chemical analysis which may be altered by particle granulometric segregation. This European Standard is applicable to single nutrient fertilizers, to uniform
32、complex fertilizers and to milled or granulated liming materials. The methods described in this document are not suitable for sampling other types of fertilizer, for example blended fertilizers. NOTE The term fertilizer is used throughout the body of this European Standard and includes liming materi
33、als unless otherwise indicated. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenc
34、ed document (including any amendments) applies. EN 1482-1:2007, Fertilizers and liming materials - Sampling and sample preparation - Part 1: Sampling 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 1482-1:2007 and the following apply. 3.1 fertilizer s
35、olid inorganic material designated for use as a fertilizer including liming materials 3.2 sampling point point in the sampling unit from which a sub-sample is taken Note 1 to entry: For the definition of sub-sample, see EN 14821:2007, Note in 3.5. 3.3 static heap quantity of fertilizer stored in bul
36、k in a single mass 4 Sampling plans and quantitative data 4.1 General The objective of sampling is to acquire a sample of the lot to establish its composition and properties. The methods to be used for sampling static heaps are specified in the following clauses. BS EN 1482-3:2016EN 1482-3:2016 (E)
37、6 4.2 Characterization of the lot to be sampled Before a sampling plan is determined, a description of the characteristics of the lot that is intended to be sampled shall be undertaken. In particular, the following physical characteristics shall be noted: kind/type, texture, colour, storage conditio
38、ns, e.g. uncovered/covered, foreign matters. If the owner of the material is applying the same description and statutory information to the whole lot, sampling should proceed in accordance with this document. Only if there is evidence of deterioration or contamination should consideration be given t
39、o the dividing of the lot into parts from which separate samples should be taken. 4.3 Sampling plan 4.3.1 General The sampling plan shall be determined after the characteristics according to 4.2 have been considered. Any variations from the stated sampling plan shall be documented in written form. T
40、he sampling plan shall define the course of the sampling process, and associated provisions, in reproducible manner. Sampling only around the base of the heap or from a single part of the heap does not supply a representative sample. 4.3.2 Elements of the sampling plan Within the sampling plan, the
41、following elements shall be stated: boundary of the lot, determination of the volume/mass of the lot, determination of the number and location of sampling units, determination of sampling units from which the increments shall be taken, if necessary, preparation of a sketch-map of the sampling areas
42、(see Figure 1), determination of the minimum number of sampling points from which sub-samples are to be taken to form the incremental sample, determination of minimum volume/mass of increments. BS EN 1482-3:2016EN 1482-3:2016 (E) 7 Key 1 conveyor belt 1 to 32 number of sampling units of equivalent s
43、urface 10 random selected sampling units for sampling + sampling points (random distribution in the sampling unit) top ring 2 sampling units (180 each) second ring 6 sampling units (60 each) third ring 8 sampling units (45 each) fourth ring 16 sampling units (22,5 each) Characteristics of the heap:
44、angle of repose: 36 base diameter: 12 m height: 5,3 m circumference: 37,70 m ridge: 8 m volume: 200 m3Figure 1 Example of sampling plan for a conical heap (developed) BS EN 1482-3:2016EN 1482-3:2016 (E) 8 4.4 Determination of the volume/mass of the lot The volume/mass of the lot should either be det
45、ermined by reference to production/purchase/sales records of the owner or, if this is not possible, shall be estimated by the methods described in Annex A. 4.5 Determination of sampling units and sampling points 4.5.1 Determination of the number and location of the sampling units The total minimum n
46、umber of sampling units depends on the size of the lot. Each sampling unit will be represented by approximately the same surface area. 4.5.2 Minimum total number of sampling units The total number of sampling units into which the lot has to be divided shall be determined in accordance with Table 1.
47、Table 1 Number of sampling units that the lot needs be divided into Lot size t Minimum number of sampling units 25 or less 10 More than 25 and up to 400 The nearest whole even number above the square root of 4 times the quantity, in tonnes, present More than 400 40 4.5.3 Determination of sampling un
48、its from which incremental samples shall be taken Select randomly a minimum of 10 sampling units from the total number of sampling units determined in accordance with 4.5.2 using random number tables or a random number generator. Incremental samples shall be taken from the selected sampling units. 4
49、.5.4 Determination of the minimum number of sampling points from which sub-samples are to be taken The number of sub-samples to be taken from the material in the selected sampling units shall be determined by reference to the minimum quantity of the incremental sample required according to 4.6.2 and the quantity of material delivered on each occasion by the sampling device. Sub-samples shall comprise of a quantity of material taken at randomly selected points in each selected sampling unit. These shall be mixed to form the in
