1、BS EN ISO2082:2008ICS 25.220.40NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDMetallic and otherinorganic coatings Electroplatedcoatings of cadmiumwith supplementarytreatments on iron orsteel (ISO 2082:2008)This British Standard was published under theauthority
2、 of the StandardsPolicy and StrategyCommittee on BSI 2009ISBN 978 0 580 54193 3Amendments/corrigenda issued since publicationDate CommentsBS EN ISO 2082:2008National forewordThis British Standard is the UK implementation of EN ISO 2082:2008. Itsupersedes BS EN 12330:2000 which is withdrawn.The UK pa
3、rticipation in its preparation was entrusted to TechnicalCommittee STI/33, Electrodeposited and related coatings.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Us
4、ers are responsible for its correct application.Compliance with a British Standard cannot confer immunityfrom legal obligations.28 February 2009EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 2082December 2008ICS 25.220.40 Supersedes EN 12330:2000 English VersionMetallic and other inorganic co
5、atings - Electroplated coatings ofcadmium with supplementary treatments on iron or steel (ISO2082:2008)Revtements mtalliques et autres revtementsinorganiques - Dpts lectrolytiques de cadmium avectraitements supplmentaires sur fer ou acier (ISO2082:2008)Metallische berzge - Galvanische Cadmiumberzge
6、aufEisenwerkstoffen mit zustzlicher Behandlung (ISO2082:2008)This European Standard was approved by CEN on 19 December 2008.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard with
7、out any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language m
8、ade by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France
9、, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMU
10、NGManagement Centre: Avenue Marnix 17, B-1000 Brussels 2008 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 2082:2008: EBS EN ISO 2082:2008EN ISO 2082:2008 (E) 3 Foreword This document (EN ISO 2082:2008) has been prepared by Tech
11、nical Committee ISO/TC 107 “Metallic and other inorganic coatings“ in collaboration with Technical Committee CEN/TC 262 “Metallic and other inorganic coatings“, the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of
12、an identical text or by endorsement, at the latest by June 2009, and conflicting national standards shall be withdrawn at the latest by June 2009. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be hel
13、d responsible for identifying any or all such patent rights. This document supersedes EN 12330:2000. WARNING Because of regulations, the alteration of which is for the time being outside the competence of the CEN members, this European Standard contains an A-deviation as detailed in Annex ZA (inform
14、ative). According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
15、 Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 2082:2008 has been approved by CEN as a EN ISO 2082:2008 without any modification. BS EN ISO 2082:20
16、08EN ISO 2082:2008 (E) 4 Annex ZA (informative) Adeviations A-deviation: National deviation due to regulations, the alteration of which is for the time being outside the competence of the CEN/ CENELEC member. This European Standard does not fall under any Directive of the EU. In the relevant CEN/CEN
17、ELEC countries these A-deviations are valid instead of the provisions of the European Standard until they have been removed. Clause Deviation General Germany (Gefahrstoffverordnung; Chemikalien-Verbotsverordnung) In Germany, the Gefahrstoffverordnung and the Chemikalien-Verbotsverordnung are applica
18、ble and cadmium electroplating is permitted only for special purposes, for which special standards exist. BS EN ISO 2082:2008ISO 2082:2008(E) ISO 2008 All rights reserved iiiContents Page Foreword iv Introduction v 1 Scope . 1 2 Normative references . 2 3 Terms, definitions, abbreviated terms and sy
19、mbols. 3 3.1 Terms and definitions. 3 3.2 Abbreviated terms 3 3.3 Symbols . 3 4 Information to be supplied by the purchaser to the electroplater. 3 4.1 Essential information . 3 4.2 Additional information 4 5 Designation . 4 5.1 General. 4 5.2 Designation specification 4 5.3 Designation of heat trea
20、tment requirements . 5 5.4 Examples . 5 6 Requirements 5 6.1 Appearance . 5 6.2 Thickness 6 6.3 Conversion coatings and other supplementary treatments. 6 6.4 Adhesion of cadmium and chromate coatings 6 6.5 Accelerated corrosion testing . 7 6.6 Stress relief heat treatment before cleaning and metal d
21、eposition 8 6.7 Hydrogen-embrittlement-relief heat treatment after electroplating. 8 7 Sampling 9 Annex A (normative) Designation of chromate conversion coatings and other supplementary treatments . 10 Annex B (normative) Measurement of average thickness of coating on small articles . 12 Annex C (in
22、formative) Additional information on corrosion resistance, rinsing and drying, processing parts in bulk and dyeing of chromate conversion coatings 13 Bibliography . 15 BS EN ISO 2082:2008ISO 2082:2008(E) iv ISO 2008 All rights reservedForeword ISO (the International Organization for Standardization)
23、 is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be repre
24、sented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are
25、 drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an Internationa
26、l Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 2082 was prepa
27、red by Technical Committee ISO/TC 107, Metallic and other inorganic coatings, Subcommittee SC 3, Electrodeposited coatings and related finishes. This third edition cancels and replaces the second edition (ISO 2082:1986), which has been technically revised. BS EN ISO 2082:2008ISO 2082:2008(E) ISO 200
28、8 All rights reserved vIntroduction Electrodeposits of cadmium are used to protect iron and steel from corrosion. Cadmium is anodic and corrodes sacrificially, thus protecting ferrous basis metals even when exposed through pores or pits in the cadmium. Electrodeposited cadmium coatings have traditio
29、nally been applied to iron or steel from alkaline cyanide solutions, but in recent years, environmental concerns and regulations have led to increased use of acid sulphate, neutral chloride and acid fluoborate cadmium solutions. Because the appearance and serviceability of electroplated cadmium coat
30、ings are influenced by the surface condition of the basis metal, agreement should be reached between the interested parties that the surface of the basis metal is satisfactory for electroplating. Cadmium is highly toxic and health, safety and environmental concerns are eliminating its non-essential
31、uses. There remain, nevertheless, critical applications, often aerospace-related, where the unique properties of electrodeposited cadmium coatings, for example, their corrosion resistance, intrinsic lubricity, ductility, electrical conductivity and low contact resistance, make continued use of cadmi
32、um coatings necessary. The corrosion resistance of electroplated cadmium coatings and their tendency to tarnish when handled can be improved by applying chromate conversion and other supplementary coatings. Chemical conversion coatings that do not contain hexavalent chromium are commercially availab
33、le and their use is becoming more and more popular. The appearance of these substitutes may be different from those produced with hexavalent chromium. Other conversion coatings that are chromium-free are also available. Substitutes are required to satisfy the corrosion requirements given in this Int
34、ernational Standard. BS EN ISO 2082:2008BS EN ISO 2082:2008INTERNATIONAL STANDARD ISO 2082:2008(E) ISO 2008 All rights reserved 1Metallic and other inorganic coatings Electroplated coatings of cadmium with supplementary treatments on iron or steel DANGER Cadmium vapour is highly toxic by inhalation.
35、 During heat treatment, all precautions should be taken to ensure that no person is exposed to it. Attention is also drawn to the danger arising from welding, soldering or heating and other operations, in which the possibility that cadmium will be vaporised exists. Because of its toxicity, cadmium s
36、hould not be employed as a coating for any article that will come in contact with food or beverages or containers in contact with these items or any household goods. WARNING This International Standard may not be compliant with some countries health, safety and environmental legislations and calls f
37、or the use of substances and/or procedures that may be injurious to health if adequate safety measures are not taken. This International Standard does not address any health hazards, safety or environmental matters and legislations associated with its use. It is the responsibility of the producers,
38、purchasers and/or user of this International Standard to establish appropriate health, safety and environmentally acceptable practices and take appropriate actions to comply with any national, regional and/or international rules and regulations. Compliance with this International Standard does not,
39、of itself, confer immunity from legal obligations. 1 Scope This International Standard specifies the requirements of electroplated coatings of cadmium with supplementary treatments on iron and steel. It includes information that is to be supplied by the purchaser to the electroplater, and describes
40、coating requirements, including those for heat treatment before and after electroplating. It is not applicable to coatings applied to sheet, strip or wire in the non-fabricated form, to close-coiled springs, or for purposes other than protective, intrinsic lubricity, ductility, electrical conductivi
41、ty and low contact resistance use. This International Standard does not specify requirements for the surface condition of the basis metal prior to electrodeposition with cadmium. The coating thickness that can be applied to threaded components can be limited by dimensional requirements, including cl
42、ass or fit. BS EN ISO 2082:2008ISO 2082:2008(E) 2 ISO 2008 All rights reserved2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the refe
43、renced document (including any amendments) applies. ISO 1463, Metallic and oxide coatings Measurement of coating thickness Microscopical method ISO 2064, Metallic and other inorganic coatings Definitions and conventions concerning the measurement of thickness ISO 2080, Metallic and other inorganic c
44、oatings Surface treatment, metallic and other inorganic coatings Vocabulary ISO 2177, Metallic coatings Measurement of coating thickness Coulometric method by anodic dissolution ISO 2178, Non-magnetic coatings on magnetic substrates Measurement of coating thickness Magnetic method ISO 2819, Metallic
45、 coatings on metallic substrates Electrodeposited and chemically deposited coatings Review of methods available for testing adhesion ISO 3497, Metallic coatings Measurement of coating thickness X-ray spectrometric methods ISO 3543, Metallic and non-metallic coatings Measurement of thickness Beta bac
46、kscatter method ISO 3613, Chromate conversion coatings on zinc, cadmium, aluminium-zinc alloys and zinc-aluminium alloys Test methods ISO 3892, Conversion coatings on metallic materials Determination of coating mass per unit area Gravimetric methods ISO 4518, Metallic coatings Measurement of coating
47、 thickness Profilometric method ISO 4519, Electrodeposited metallic coatings and related finishes Sampling procedures for inspection by attributes ISO 9587, Metallic and other inorganic coatings Pretreatment of iron or steel to reduce the risk of hydrogen embrittlement ISO 9588, Metallic and other i
48、norganic coatings Post-coating treatments of iron or steel to reduce the risk of hydrogen embrittlement ISO 10289, Methods for corrosion testing of metallic and other inorganic coatings on metallic substrates Rating of test specimens and manufactured articles subjected to corrosion tests ISO 10587,
49、Metallic and other inorganic coatings Test for residual embrittlement in both metallic-coated and uncoated externally-threaded articles and rods Inclined wedge method ISO 15724, Metallic and other inorganic coatings Electrochemical measurement of diffusible hydrogen in steels Barnacle electrode method ASTM B117, Standard Practice for Operating Salt Spray (Fog) Apparatus BS EN ISO 2082:2008ISO 2082:2008(E) ISO 2008 All rights reserved 33 Terms, definitions, abbreviated terms