1、BS EN ISO 5667-14:2016Water quality SamplingPart 14: Guidance on quality assuranceand quality control of environmental watersampling and handling (ISO 5667-14:2014)BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO 5667-14:2016 BRITISH STANDARDNational forewor
2、dThis British Standard is the UK implementation of EN ISO 5667-14:2016. It is identical to ISO 5667-14:2014. It supersedes BS ISO 5667-14:2014The UK participation in its preparation was entrusted by Technical Committee EH/3, Water quality, to Subcommittee EH/3/6, Sampling. A list of organizations re
3、presented on this subcommittee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2016.Published by BSI Standards Limited 2016ISBN 97
4、8 0 580 92183 4 ICS 13.060.45 Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 December 2014.Amendments/corrigenda issued since publicationDate T e x t a f f e
5、 c t e d31 August 2016 T h i s c o r r i g e n d u m r e n u m b e r s B S I S O 5 6 6 7 - 1 4 : 2 0 1 4as BS EN ISO 5667-14:2016which is withdrawn.EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 5667-14 August 2016 ICS 13.060.45 English Version Water quality - Sampling - Part 14: Guidance
6、on quality assurance and quality control of environmental water sampling and handling (ISO 5667-14:2014) Qualit de leau - chantillonnage - Partie 14: Lignes directrices pour le contrle de la qualit dans lchantillonnage et la manutention des eaux environnementales (ISO 5667-14:2014) Wasserbeschaffenh
7、eit - Probenahme - Teil 14: Anleitung zur Qualittssicherung und Qualittskontrolle bei der Entnahme und Handhabung von umweltrelevanten Wasserproben (ISO 5667-14:2014) This European Standard was approved by CEN on 15 July 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations
8、 which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. Thi
9、s European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN memb
10、ers are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portug
11、al, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form
12、 and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 5667-14:2016 EEN ISO 5667-14:2016 (E) European foreword The text of ISO 5667-14:2014 has been prepared by Technical Committee ISO/TC 147 “Water quality” of the International Organization for Standardization (ISO) and has
13、been taken over as EN ISO 5667-14:2016 by Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2017, an
14、d conflicting national standards shall be withdrawn at the latest by February 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. Ac
15、cording to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germa
16、ny, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 5667-14:2014 has been approved by CEN as EN ISO 5667-1
17、4:2016 without any modification. iiBS EN ISO 5667-14:2016ISO 5667-14:2014(E)Contents PageForeword ivIntroduction vi1 Scope . 12 Normative references 13 Terms and definitions . 14 Sources of sampling error . 45 Sampling quality . 55.1 General . 55.2 Technical and personnel requirements . 65.3 Samplin
18、g manual . 65.4 Training of sampling staff 76 Strategy and organization . 76.1 Time, duration and frequency of sampling. 76.2 Sampling collection locations . 87 Sample collection and handling 87.1 Equipment and vehicle check prior to carrying out a sampling programme . 87.2 Preparation for sampling
19、on-site 97.3 Field measurements . 97.4 Taking the samples 98 Sample identification 129 Field sample protocol .1210 Transport and storage of samples .1211 Sampling quality control techniques .1311.1 General 1311.2 Replicate quality control samples . 1511.3 Field blank samples . 1611.4 Rinsing of equi
20、pment (sampling containers) 1711.5 Filtration recovery 1811.6 Technique 1 Spiked samples . 2011.7 Technique 2 Spiked environmental samples 2212 Analysis and interpretation of quality control data .2212.1 Shewhart control charts. 2212.2 Construction of duplicate control charts . 2313 Independent audi
21、ts.23Annex A (informative) Common sources of sampling error7.25Annex B (informative) Control charts 27Annex C (informative) Sub-sampling using a homogenizer 31Bibliography .34 ISO 2014 All rights reserved iiiBS EN ISO 5667-14:2016ISO 5667-14:2014(E)ForewordISO (the International Organization for Sta
22、ndardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the righ
23、t to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures
24、used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rule
25、s of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identif
26、ied during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on
27、the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT), see the following URL: Foreword Supplementary information .The committee responsible for this document is IS
28、O/TC 147, Water quality, Subcommittee SC 6, Sampling (general methods).This second edition cancels and replaces the first edition (ISO 5667-14:1998), which has been technically revised.ISO 5667 consists of the following parts, under the general title Water quality Sampling: Part 1: Guidance on the d
29、esign of sampling programmes Part 3: Preservation and handling of water samples Part 4: Guidance on sampling from lakes Part 5: Guidance on sampling of drinking water Part 6: Guidance on sampling of rivers and streams Part 7: Guidance on sampling of water and steam in boiler plants Part 8: Guidance
30、on sampling of wet deposition Part 9: Guidance on sampling from marine waters Part 10: Guidance on sampling of waste waters Part 11: Guidance on sampling of groundwaters Part 12: Guidance on sampling of bottom sediments; Part 13: Guidance on sampling of water, waste water and related sludges Part 14
31、: Guidance on quality assurance and quality control of environmental water sampling and handling Part 15: Guidance on preservation and handling of sludge and sediment samplesiv ISO 2014 All rights reservedBS EN ISO 5667-14:2016ISO 5667-14:2014(E) Part 16: Guidance on biotesting of samples Part 17: G
32、uidance on sampling of suspended sediments Part 19: Guidance on sampling of marine sediments Part 20: Guidance on the use of sampling data for decision making Compliance with thresholds and classification systems Part 21: Guidance on sampling of drinking water distributed by tankers or means other t
33、han distribution pipes Part 22: Guidance on design and installation of groundwater sample points Part 23: Guidance on passive sampling in surface waters ISO 2014 All rights reserved vBS EN ISO 5667-14:2016ISO 5667-14:2014(E)IntroductionSampling is the first step in carrying out chemical, physical an
34、d biological examinations. Therefore, the goal of sampling should be to obtain a representative sample for the research question and to supply it to the laboratory in the correct manner. Errors caused by improper sampling, sample pre-treatment, transport and storage cannot be corrected.This part of
35、ISO 5667 specifies quality assurance and quality control procedures and provides additional guidance on sampling of the various types of water covered in the specific parts of ISO 5667.Quality control procedures are necessary for the collection of environmental water samples for the following reason
36、s:a) to monitor the effectiveness of sampling methodology;b) to demonstrate that the various stages of the sample collection process are adequately controlled and suited to the intended purpose, including adequate control over sources of error such as sample contamination, loss of determinand and sa
37、mple instability. To achieve this, quality control procedures should provide a means of detecting sampling error, and hence a means of rejecting invalid or misleading data resulting from the sampling process;c) to quantify and control the sources of error which arise in sampling. Quantification give
38、s a guide to the significance that sampling plays in the overall accuracy of data; andd) to provide information on suitably abbreviated quality assurance procedures that might be used for rapid sampling operations such as pollution incidents or groundwater investigations.This part of ISO 5667 is one
39、 of a group of International Standards dealing with the sampling of waters. It should be read in conjunction with the other parts of ISO 5667 and in particular with parts 1 and 3.The general terminology is in accordance with that published.vi ISO 2014 All rights reservedBS EN ISO 5667-14:2016Water q
40、uality Sampling Part 14: Guidance on quality assurance and quality control of environmental water sampling and handlingWARNING Consider and minimize any risks and obey safety rules. See ISO 5667-1 for certain safety precautions, including sampling from boats and from ice-covered waters.1 ScopeThis p
41、art of ISO 5667 provides guidance on the selection and use of various quality assurance and quality control techniques relating to the manual sampling of surface, potable, waste, marine and ground waters.NOTE The general principles outlined in this part of ISO 5667 might, in some circumstances, be a
42、pplicable to sludge and sediment sampling.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the
43、 referenced document (including any amendments) applies.ISO 5667-1:2006, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniquesISO 5667-3:2012, Water quality Sampling Part 3: Preservation and handling of water samples3 Terms and definitionsFor the purpos
44、es of this document, the following terms and definitions apply.3.1accuracycloseness of agreement between a test result or measurement result and the true valueNote 1 to entry: In practice, the accepted reference value is substituted for the true value.Note 2 to entry: The term accuracy, when applied
45、 to a set of test or measurement results, involves a combination of random components and a common systematic error or bias component.Note 3 to entry: Accuracy refers to a combination of trueness and precision.SOURCE: ISO 3534-2:2006, 3.3.13.2biasdifference between the expectation of the test result
46、s or measurement result and a true valueNote 1 to entry: Bias is the total systematic error as contrasted to random error. There may be one or more systematic error components contributing to the bias. A larger systematic difference from the true value is reflected by a larger bias value.INTERNATION
47、AL STANDARD ISO 5667-14:2014(E) ISO 2014 All rights reserved 1BS EN ISO 5667-14:2016ISO 5667-14:2014(E)Note 2 to entry: The bias of a measuring instrument is normally estimated by averaging the error of indication over an appropriate number of repeated measurements. The error of indication is the: “
48、indication of a measuring instrument minus a true value of the corresponding input quantity”.Note 3 to entry: In practice, the accepted reference value is substituted for the true value.SOURCE: ISO 3534-2:2006, 3.3.23.3precisioncloseness of agreement between independent test/measurement results obta
49、ined under stipulated conditionsNote 1 to entry: Precision depends only on the distribution of random errors and does not relate to the true value or the specified value.Note 2 to entry: The measure of precision is usually expressed in terms of imprecision and computed as a standard deviation of the test results or measurement results. Less precision is reflected by a larger standard deviation.Note 3 to entry: Quantitative measures of precision depend critically on the stipulated conditions. Repeatabili
