1、 ENGINEERING MATERIAL SPECIFICATIONDate Action Revisions 2006 04 28 N-STATUS Replaced by WSK-M4D673-A A. Reaume/M. Masserant 2005 10 11 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.8, 3.9 & 4 1991 02 01 Released EP00E01089481000 M. Siewert Printed copies are uncontrolled Copyright 2006, Ford Global Tec
2、hnologies, LLC Page 1 of 5 POLYAMIDE (PA) 66, HEAT STABILIZED 30% GLASS WSK-M4D642-A3 FIBER REINFORCED, REDUCED MOISTURE ABSORPTION MOLDING COMPOUND NOT TO BE USED FOR NEW DESIGN 1. SCOPE The material defined by this specification is a heat stabilized 30% glass fiber reinforced polyamide 66 molding
3、compound with reduced moisture absorption. 2. APPLICATION This specification was released originally for material used for adjuster screws of head lamp. NOTICE: This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties
4、due to moisture absorption or loss in the service/assembly environment. 3. REQUIREMENTS 3.0 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.3 CONDITIONING AND TEST CON
5、DITIONS All test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% (test according to ISO 960, Method B/ASTM D 789). All test materials immediately after processing have to be sealed in containers that are impermeable to water vapor. If the moisture
6、 content exceeds 0.2%, condition the material for a minimum of 16 h at 40 - 50 C at a reduced pressure below 133 Pa. Conduct tests in a controlled atmosphere of 23 +/- 2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until immediately before testi
7、ng. 3.4 MOLDING COMPOUND 3.4.1 Glass Fiber Content 28 - 32% (ISO 3451/4, test temperature 600 +/- 25 C, test portion 1 g) 3.4.2 Melt Temperature 250 265 C (ISO 1218, Method B/ASTM D 789 or DSC - ASTM E 794) ENGINEERING MATERIAL SPECIFICATIONWSK-M4D642-A3 Printed copies are uncontrolled Copyright 200
8、6, Ford Global Technologies, LLC Page 2 of 5 3.5 MOLDED TEST SPECIMEN 3.5.1 Preparation of Test Specimens Unless otherwise specified all tests shall be carried out on injection molded one-end gated test specimens. The following dimensions are required: A. 150 min x 10 x 4.0 +/- 0.2 mm (Tensile Bar,
9、ISO 3167) B. 120 x 10 x 4.0 +/- 0.2 mm Specimens with shorter dimensions shall be cut from the center portion of the test specimen A and/or B. The specimens shall be prepared according to ISO 294. No annealing allowed. 3.5.2 Density 1.34 - 1.39 g/cm3(ISO 1183, Method A/ASTM D 792, Method A1) 3.5.3 T
10、ensile Strength at Max Load, min 170 MPa (ISO R 527/ASTM D 638M, 150 x 10 x 4.0 +/- 0.2 mm specimen, 5 mm/minute test speed) 3.5.4 Flexural Modulus, min 8 GPa (ISO 178/ASTM D 790M, Method I, Procedure A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 64 mm support span) 3.5.5 Shear Modulus at 23 C 1.61 - 2.68 G
11、Pa (ASTM D 4065, forced constant amplitude, fixed frequency of 1 Hz +/- 15%, strain level below 1%. Specimen approx. 60 x 10 x 4.0 +/- 0.2 mm cut from the center of specimen A. Specimen length between clamps 35 - 40 mm. Soak time at each temperature interval - 3 minutes minimum) Additionally, a Shea
12、r Modulus vs. Temperature curve shall be plotted for -50 to +240 C temperature range, at 5 C minimum intervals. The plotted curve must be within tolerance range shown on page 5. 3.5.6 Impact Strength, Izod, min (ISO 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens
13、for each test) 3.5.6.1 At 23 +/- 2 C 8.0 kJ/m23.5.6.2 At -40 +/- 2 C 8.0 kJ/m2The test specimens must be conditioned for minimum of 6 h at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box, if not possible, test can be conducted outside,
14、but within 5 s. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D642-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 3 of 5 3.5.7 Heat Deflection Temperature, min (ISO 75/ASTM D 648, 120 x 10 x 4.0 +/- 0.2 mm specimen) 3.5.7.1 At 1.82 MPa 210 C 3.5.7.2 At 0.45 MPa 240 C
15、 3.5.8 Heat Aging Performance (ISO 188/ASTM D 573, 150 +/- 50 air changes/h, 1000 h at 140 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.5.8.1 Im
16、pact Strength, Izod Change +/- 25% (Test Method per para 3.5.6.1, specimens to be notched before heat aging) 3.6 FLAMMABILITY (ISO 3795) Burn Rate, max 100 mm/minute The specimen size required for material approval is 355 x 100 x 1.0 +/- 0.1 mm with a smooth surface. 3.7 FOGGING (FLTM BO 116-03) Fog
17、 Number, min 90 Formation of excessive amounts of clear film or droplets is cause for rejection. 5. GENERAL INFORMATION The information given below is provided for clarification and assistance in meeting the requirements of this specification. 5.1 COEFFICIENT OF LINEAR THERMAL EXPANSION 2.4 - 3.3-5/
18、 C (ASTM D 696) 5.2 MOLD SHRINKAGE (ISO 2577, approx. 150 x 100 x 3.2 +/- 0.2 mm injection molded specimen) 5.2.1 Molding Shrinkage . After 48 h at 23 +/- 2 C 0.2 - 1.5% ENGINEERING MATERIAL SPECIFICATIONWSK-M4D642-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page
19、 4 of 5 5.2.2 Post Shrinkage (Separate specimens required for each test) . After 48 h at 80 C 0.01 - 0.04% . After 30 minutes at 120 C 0.01 - 0.10% 5.3 WATER ABSORPTION 0.3 - 0.8% (ISO 62, 24 h/ASTM D 570, 24 h, 50 +/- 1 mm diameter, 3.2 +/- 0.2 mm thick specimen) 5.4 IMPACT STRENGTH, IZOD, min (ISO
20、 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens minimum) 5.4.1 After Moisture Conditioning 16 kJ/m2The notched specimens shall be immersed for 48 h in distilled water at 50 +/- 1 C and subsequently conditioned for 1 h at 23 +/- 2 C and 50 +/- 5% relative humidity prior to test and tested under the same conditions within 1 h. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D642-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 5 of 5
