1、 ENGINEERING MATERIAL SPECIFICATIONDate Action Revisions 2005 11 18 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.8, 3.9 & 4 1990 12 03 Released EP00E01031542000 M. Siewert Printed copies are uncontrolled Copyright 2005, Ford Global Technologies, LLC Page 1 of 5 POLYAMIDE (PA) 46, HEAT STABILIZED MOLDIN
2、G WSK-M4D671-A2 COMPOUND 1. SCOPE The material defined by this specification is a polyamide 46 molding compound prepared by polycondensation of diaminobutane and adipic acid and stabilized against hot air. 2. APPLICATION This specification was released originally for material used for plugs. NOTICE:
3、 This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties due to moisture absorption or loss in the service/assembly environment. 3. REQUIREMENTS 3.0 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers an
4、d part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.3 CONDITIONING AND TEST CONDITIONS All test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% (test according to ISO 960, Method B/ASTM
5、D 789). All test materials immediately after processing have to be sealed in containers that are impermeable to water vapor. If the moisture content exceeds 0.2%, condition the material for a minimum of 16 h at 40 - 50 C at a reduced pressure below 133 Pa. Conduct tests in a controlled atmosphere of
6、 23 +/- 2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until immediately before testing. 3.4 MOLDING COMPOUND 3.4.1 Melt Temperature 287 - 295 C (ISO 1218, Method B/ASTM D 789, or DSC-ASTM E 794) 3.5 MOLDED TEST SPECIMEN 3.5.1 Preparation of Tes
7、t Specimens Unless otherwise specified all tests shall be carried out on injection molded one-end gated test specimens. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D671-A2Printed copies are uncontrolled Copyright 2005, Ford Global Technologies, LLC Page 2 of 5 The following dimensions are required: A. 1
8、50 min x 10 x 4.0 +/- 0.2 mm (Tensile Bar, ISO 3167) B. 120 x 10 x 4.0 +/- 0.2 mm Specimens with shorter dimensions shall be cut from the center portion of the test specimen A and/or B. The specimens shall be prepared according to ISO 294. No annealing allowed. 3.5.2 Density 1.16 - 1.20 g/cm (ISO 11
9、83, Method A/ASTM D 792, Method A1) 3.5.3 Tensile Strength at Yield, min 90 MPa (ISO R 527/ASTM D 638M, 150 x 10 x 4.0 +/- 0.2 mm specimen, 50 mm/minute test speed) 3.5.3.1 Elongation at Yield, min 10% (Test Method according to para 3.5.3) 3.5.4 Flexural Modulus, min 2.6 GPa (ISO 178/ASTM D 790M, Me
10、thod I, Procedure A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 64 mm support span) 3.5.5 Shear Modulus at 23 C 0.90 - 1.35 GPa (ASTM D 4065, forced constant amplitude, fixed frequency of 1 Hz +/- 15%, strain level below 1%. Specimen approx. 60 x 10 x 4.0 +/- 0.2 mm cut from the center of specimen A) Additi
11、onally, a Shear Modulus vs. Temperature curve shall be plotted for -50 to +280 C temperature range, at 5 C minimum intervals. The plotted curve must be within tolerance range shown on page 5. 3.5.6 Impact Strength, Izod, min (ISO 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen,
12、 10 specimens for each test) 3.5.6.1 At 23 +/- 2 C 6 kJ/m 3.5.6.2 At -20 +/- 2 C 3 kJ/m 3.5.6.3 At -40 +/- 2 C 2 kJ/m The test specimens must be conditioned for minimum of 6 h at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box, if not p
13、ossible, test can be conducted outside, but within 5 s. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D671-A2Printed copies are uncontrolled Copyright 2005, Ford Global Technologies, LLC Page 3 of 5 3.5.7 Heat Deflection Temperature, min (ISO 75/ASTM D 648, 120 x 10 x 4.0 +/- 0.2 mm specimen) 3.5.7.1 At 1
14、82 MPa 145 C 3.5.7.2 At 0.45 MPa 270 C 3.5.8 Heat Aging Performance (ISO 188/ASTM D 573, 150 +/- 50 air changes/h, 1000 h at 160 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the ag
15、ed properties determination) 3.5.8.1 Tensile Strength at Max Load, Change +/- 25% (Test Method per para 3.5.3) 3.6 FLAMMABILITY (ISO 3795) Burn Rate, max 100 mm/minute The specimen size required for material approval is 355 x 100 x 1.0 +/- 0.1 mm with a smooth surface. 3.7 FOGGING (FLTM BO 116-03) F
16、og Number, min 90 Formation of excessive amounts of clear film or droplets is cause for rejection. 5. GENERAL INFORMATION The information given below is provided for clarification and assistance in meeting the requirements of this specification. 5.1 COEFFICIENT OF LINEAR THERMAL EXPANSION 6.3 - 7.3-
17、5/ C (ASTM D 696) 5.2 MOLD SHRINKAGE (ISO 2577, approx. 150 x 100 x 3.2 +/- 0.2 mm injection molded specimen) 5.2.1 Molding Shrinkage . After 48 h at 23 +/- 2 C 1.5 - 2.4% 5.2.2 Post Shrinkage (Separate specimens required for each test) . After 48 h at 80 C 0.01 - 0.02% . After 30 minutes at 120 C 0
18、01 - 0.03% ENGINEERING MATERIAL SPECIFICATIONWSK-M4D671-A2Printed copies are uncontrolled Copyright 2005, Ford Global Technologies, LLC Page 4 of 5 5.3 WATER ABSORPTION 2.0 - 2.4% (ISO 62, 24 h/ASTM D 570, 24 h, 50 +/- 1 mm diameter, 3.2 +/- 0.2 mm thick specimen) 5.4 IMPACT STRENGTH, IZOD, min (IS
19、O 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens minimum) 5.4.1 After Moisture Conditioning 40 kJ/m The notched specimens shall be immersed for 48 h in distilled water at 50 +/- 1 C and subsequently conditioned for 1 h at 23 +/- 2 C and 50 +/- 5% relative humidity prior to test and tested under the same conditions within 1 h. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D671-A2Printed copies are uncontrolled Copyright 2005, Ford Global Technologies, LLC Page 5 of 5
