1、 ENGINEERING MATERIAL SPECIFICATIONDate Action Revisions 2006 05 02 N-STATUS Replaced by WSK-M4D704-A1 A. Reaume/M. Masserant 2005 11 29 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.8, 3.9 & 4 1991 02 01 Released EP00E01089481000 M. Siewert Printed copies are uncontrolled Copyright 2006, Ford Global Te
2、chnologies, LLC Page 1 of 5 POLYAMIDE (PA) 66, HEAT STABILIZED WSK-M4D704-A3 40% MINERAL FILLED, REDUCED MOISTURE ABSORPTION MOLDING COMPOUND NOT TO BE USED FOR NEW DESIGN 1. SCOPE The material defined by this specification is a heat stabilized 40% mineral filled polyamide 66 molding compound with r
3、educed moisture absorption. 2. APPLICATION This specification was released originally for material used for the backplate of exterior mirror. NOTICE: This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties due to mois
4、ture absorption or loss in the service/assembly environment. 3. REQUIREMENTS 3.0 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.3 CONDITIONING AND TEST CONDITIONS All
5、 test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% (test according to ISO 960, Method B/ASTM D 789). All test materials immediately after processing have to be sealed in containers that are impermeable to water vapor. If the moisture content ex
6、ceeds 0.2%, condition the material for a minimum of 16 h at 40 - 50 C at a reduced pressure below 133 Pa. Conduct tests in a controlled atmosphere of 23 +/- 2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until immediately before testing. 3.4 MOL
7、DING COMPOUND 3.4.1 Mineral Content 38 - 42% (ISO 3451/4, test temperature 600 +/- 25 C, test portion 1 g) 3.4.2 Melt Temperature 250 - 265 C (ISO 1218, Method B/ASTM D 789 or DSC - ASTM E 794) ENGINEERING MATERIAL SPECIFICATIONWSK-M4D704-A3 Printed copies are uncontrolled Copyright 2006, Ford Globa
8、l Technologies, LLC Page 2 of 5 3.5 MOLDED TEST SPECIMEN 3.5.1 Preparation of Test Specimens Unless otherwise specified all tests shall be carried out on injection molded one-end gated test specimens. The following dimensions are required: A. 150 min x 10 x 4.0 +/- 0.2 mm (Tensile Bar, ISO 3167) B.
9、120 x 10 x 4.0 +/- 0.2 mm Specimens with shorter dimensions shall be cut from the center portion of the test specimen A and/or B. The specimens shall be prepared according to ISO 294. No annealing allowed. 3.5.2 Density 1.44 - 1.50 g/cm3(ISO 1183, Method A/ASTM D 792, Method A1) 3.5.3 Tensile Streng
10、th at Max Load, min 80 MPa (ISO R 527/ASTM D 638M, 150 x 10 x 4.0 +/- 0.2 mm specimen, 5 mm/minute test speed) 3.5.4 Flexural Modulus, min 6.0 GPa (ISO 178/ASTM D 790M, Method I, Procedure A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 64 mm support span) 3.5.5 Shear Modulus at 23 C 2.01 - 3.36 GPa (ASTM D 4
11、065, forced constant amplitude, fixed frequency of 1 Hz +/- 15%, strain level below 1%. Specimen approx. 60 x 10 x 4.0 +/- 0.2 mm cut from the center of specimen A. Specimen length between clamps 35-40 mm. Soak time at each temperature interval - 3 minutes minimum) Additionally, a Shear Modulus vs.
12、Temperature curve shall be plotted for -50 to +240 C temperature range, at 5 C minimum intervals. The plotted curve must be within tolerance range shown on page 5. 3.5.6 Impact Strength, Izod, min (ISO 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens for each test)
13、 3.5.6.1 At 23 +/- 2 C 4 kJ/m23.5.6.2 At -40 +/- 2 C kJ/m2The test specimens must be conditioned for minimum of 6 h at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box, if not possible, test can be conducted outside, but within 5 s. ENGI
14、NEERING MATERIAL SPECIFICATIONWSK-M4D704-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 3 of 5 3.5.7 Heat Deflection Temperature, min (ISO 75/ASTM D 648, 120 x 10 x 4.0 +/- 0.2 mm specimen) 3.5.7.1 At 1.82 MPa 80 C 3.5.7.2 At 0.45 MPa 200 C 3.5.8 Heat Aging Per
15、formance (ISO 188/ASTM D 573, 150 +/- 50 air changes/h, 1000 h at 140 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.5.8.1 Impact Strength, Izod C
16、hange +/- 25% (Test Method per para 3.5.6.1, specimens to be notched before heat aging) 3.6 FLAMMABILITY (ISO 3795) Burn Rate, max 100 mm/minute The specimen size required for material approval is 355 x 100 x 1.0 +/- 0.1 mm with a smooth surface. 3.7 FOGGING (FLTM BO 116-03) Fog Number, min 90 Forma
17、tion of excessive amounts of clear film or droplets is cause for rejection. 5. GENERAL INFORMATION The information given below is provided for clarification and assistance in meeting the requirements of this specification. 5.1 COEFFICIENT OF LINEAR THERMAL EXPANSION 3.6 - 4.6-5/ C (ASTM D 696) 5.2 M
18、OLD SHRINKAGE (ISO 2577, approx. 150 x 100 x 3.2 +/- 0.2 mm injection molded specimen) 5.2.1 Molding Shrinkage . After 48 h at 23 +/- 2 C 1.0 - 1.6% 5.2.2 Post Shrinkage (Separate specimens required for each test) . After 48 h at 80 C 0.05 - 0.15% . After 30 minutes at 120 C 0.10 - 0.25% ENGINEERING
19、 MATERIAL SPECIFICATIONWSK-M4D704-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 4 of 5 5.3 WATER ABSORPTION 0.15 - 0.50% (ISO 62, 24 h/ASTM D 570, 24 h, 50 +/- 1 mm diameter, 3.2 +/- 0.2 mm thick specimen) 5.4 IMPACT STRENGTH, IZOD, min (ISO 180, Method A/ASTM
20、 D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens minimum) 5.4.1 After Moisture Conditioning 5 kJ/m2The notched specimens shall be immersed for 48 h in distilled water at 50 +/- 1 C and subsequently conditioned for 1 h at 23 +/- 2 C and 50 +/- 5% relative humidity prior to test and tested under the same conditions within 1 h. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D704-A3 Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 5 of 5
