1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions REV 00 2013 07 04 Released New Specification Y. Bankowski, NA Controlled document at www.MATS Copyright 2013, Ford Global Technologies, LLC Page 1 of 7 THERMOPLASTIC OLEFIN ELASTOMER (TPO), 10% MINERAL FILLED, WSS-M4D1039-A1 MOLDED-IN-COLOR,
2、INTERIOR 1. SCOPE The material defined by this specification is a molded-in-color, talc filled thermoplastic olefin elastomer (TPO) that is UV stabilized for unpainted interior applications with medium impact and stiffness. 2. APPLICATION This specification was released originally for material used
3、for interior trim components such as the 2013 Escape lower IP retainer. 2.1 LIMITATIONS This material is not intended for painted applications. This material should not be used as a hard instrument panel substrate with a seamless passenger airbag. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUC
4、TION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.1.1 Many 4D resin specifications prior to 2011, identified certain requirements with the symbol (s), which indicated that the mean and +/- 3 sigma valu
5、es were to be reported. The specification minimum, maximum or range was established using 3 sigma data. For 2011 and beyond, refer to Table 1 for number of samples required for each test to establish specification limits. 3.1.2 This specification is based on virgin materials. Materials with post-con
6、sumer, post industrial, or repolymerised recycled materials as defined by WRS-M99P42-A1 are preferred and should be used whenever feasible. 3.1.3 The use of regrind is permitted, for economic / environmental reasons, with compliance as indicated in Ford Engineering CAD and Drafting Standard E-4. 3.1
7、4 Materials used in interior applications must meet the requirements outlined in WSS-M99P2222-D1/Latest, Performance, Vehicle Interior Environment Quality Material/Component Requirements. Data must be included in material submission package. 3.1.5 Performance Criteria: Parts using this specificatio
8、n shall meet the appropriate performance specification, WSS-M15P4-F/Latest for Hard, Interior, Molded-in-Color component performance. ENGINEERING MATERIAL SPECIFICATION WSS-M4D1039-A1 Copyright 2013, Ford Global Technologies, LLC Page 2 of 7 3.2 SAMPLE PREPARATION Unless otherwise specified all test
9、s shall be carried out on injection molded, one-end gated test specimens. The test specimens A and D shall be molded using molding conditions defined in ISO 1873-2. No annealing is allowed. See Table 1 for the number of specimens required. Specimens shall be as follows: Specimen A 150 minimum x 10 x
10、 4.0 +/- 0.2 mm (ISO 527-2, Specimen Type 1A) Specimen B 355 x 100 x 1.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A. 80 x 10 x 4.0 +/- 0.2 mm Specimen E 100 mm diameter x 3.2 mm Specimen F 80 mm diameter x 3.2 mm Specimen G 90 mm x 200 mm Specimen H 50
11、 +/- 1 mm diameter x 3.2 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.3 APPEARANCE 3.3.1 Weathering Resistance Rating 4 min (FLTM BO 116-01, 3609.6 kJ/m2 exposure Specimen C from smooth polished mold, ISO 105-A02 / AATCC Evaluation Procedure 1) Every 526.4kJ/m2 remove the samples from the weatherome
12、ter and allow them to cool for one hour. Conduct a tactile evaluation and report any tackiness. Visually evaluate and report any spewing or other exudation. After exposure the material shall show no fading or color change in excess of specified AATCC rating. In addition, there shall be no cracking,
13、crazing or other deterioration. Use regional choice colors for initial approval and report color house used. For color durability submissions, test all program colors. 3.3.2 Resistance to Scratch and Mar (FLTM BO 162-01, Specimen I) Scratch Rating 2 at 2N, max Whitening/Color Change Rating 1 at 15N,
14、 max Marring Rating 2 at 2N, max These values are derived from colored and grained samples in agreement with Materials Engineering. Details regarding color house, let down ratio, colors, grain, etc can be found in the approval package. 3.4 MATERIAL PROPERTIES 3.4.1 Filler Content 8 - 12 % (ISO 3451-
15、1, Method A) 3.4.2 Density 0.94 0.98 g/cm3 (ISO 1183, Method A) 3.4.3 Tensile Strength at Yield 17 MPa min (ISO 527-1 Flow 82 E-5 mm/mm/ C 3.5.4 Coefficient of Linear Thermal Expansion; Across Flow 101 E-5 mm/mm/ C 3.5.5.1 Impact Strength Izod, Notched at 23 +/- 2 C 35 kJ/m2 3.5.5.2 Impact Strength
16、Izod, Notched at -40 +/- 2 C 5.0 kJ/m2 3.5.6.1 Impact Strength, Multiaxial; Max Load Energy at 23 +/- 2 C 20 J 3.5.6.2 Impact Strength, Multiaxial; Max Load Energy at 0 +/- 2 C 21 J 3.5.7 Poissons Ratio 0.44 N/A 4.2 MATERIAL IDENTIFICATION FOR RECYCLING PURPOSES TPO-(PP+EPM)-MD10) (ISO 1043) ENGINEE
17、RING MATERIAL SPECIFICATION WSS-M4D1039-A1 Copyright 2013, Ford Global Technologies, LLC Page 6 of 7 Table 1: Number of Specimens Required Initial Approval New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per lot Total Test Specimens Lots Specimens per lo
18、t Total Test Specimens 3.1 WSS-M99P1111-A 3.1.4 WSS-M99P2222-D1 Total Carbon, Hazardous Substances, Formaldehyde, Acraldehyde, Acetaldehyde (See below for odor and fogging) 1 1 1 per test 3.1.5 Parts Performance Reference Performance Specification 3.3.1 Weathering Resistance 1 1 1 3.3.2 Resistance t
19、o Scratch and Mar 1 3 3 3.4.1 Filler Content* 3 1 3 1 1 1 3.4.2 Density 1 3 3 3.4.3 Tensile Strength at Yield* 3 5 15 1 5 5 3.4.4 Tensile Modulus 1 10 10 3.4.5 Flexural Modulus* 3 10 30 1 10 10 3.4.6 Impact Strength, Notched Charpy, (per condition)* 3 10 30 1 10 10 3.4.7 Heat Deflection Temperature*
20、 3 2 6 1 2 2 3.4.8 Heat Aged Properties 3.4.8.1 Tensile Strength at Yield Change 1 5 5 3.4.8.2 Impact Strength, Notched Charpy, Change 1 10 10 3.4.9 Odor 1 9 9 3.4.10 Fogging 1 3 3 3.4.11 Flammability 1 5 5 3.5.1 Melt Flow Rate 3 1 3 1 1 1 3.5.2 Elongation at Yield 3 5 15 1 5 5 3.5.3 Mold Shrinkage
21、1 5 5 3.5.4 Coefficient of Linear Thermal Expansion (per condition) 1 3 3 3.5.5 Impact Strength, Notched Izod (per condition) 1 10 10 3.5.6 Impact Strength, Multiaxial 3 10 30 1 10 10 3.5.7 Poissons Ratio 1 2 2 3.5.8 Curves -IR -TGA -DSC -CLTE -Stress/Strain Curves 1 1 1 per test * For these require
22、ments the 3 sigma value from the raw data is used to meet the requirements. ENGINEERING MATERIAL SPECIFICATION WSS-M4D1039-A1 Copyright 2013, Ford Global Technologies, LLC Page 7 of 7 Table 2: Minimum Color Property Testing Contact Materials Engineering for Color Test Work Plan Para. Test Lots Speci
23、mens per Lot Total Test Specimens Color Test Direction 3.3.1 Weathering Resistance 1 1 1 Every Color 3.3.2 Resistance to Scratch and Mar 1 3 3 As directed by Materials Engineering 3.4.3 Tensile Strength at Yield 1 5 5 As directed by Materials Engineering 3.4.5 Flexural Modulus 1 10 10 As directed by Materials Engineering 3.4.6 Impact Strength, Notched Charpy at 23 +/- 2 C 1 10 10 As directed by Materials Engineering 3.4.9 Odor 1 9 9 As directed by Materials Engineering 3.4.11 Flammability 1 5 5 Every Color
