1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions Rev. 6 2015 08 21 Revised Editorial, removed high in title to align with scope L. Soreide, NA 2013 04 25 Revised Editorial, updated recycling code Y. Bankowski, NA 2000 05 18 Activated M. Masserant, NA Controlled document at www.MATS Copyrigh
2、t 2015, Ford Global Technologies, LLC Page 1 of 8 THERMOPLASTIC POLYOLEFIN ELASTOMER (TPO), WSS-M4D550-A10 20% TALC FILLED, MEDIUM IMPACT, MOLDING COMPOUND, MOLDED IN COLOR, INTERIOR 1. SCOPE The material defined by this specification is a low gloss, medium impact, rigid thermoplastic polyolefin ela
3、stomer (TPO) injection molding compound, mineral (talc) filled, UV stabilized and high scratch resistant for interior use. 2. APPLICATION This specification was released originally for material used for an unpainted instrument panel with a non-seamless passenger airbag. 2.1 LIMITATIONS This material
4、 should not be used as an instrument panel substrate with a seamless passenger airbag. This material is not to be used in applications requiring painting because it contains internal anti-scratch additive. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part
5、 producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.1.1 Many 4D resin specifications prior to 2011, identified certain requirements with the symbol (s), which indicated that the mean and +/- 3 sigma values were to be reported. The specification
6、minimum, maximum or range was established using 3 sigma data. For 2011 and beyond, refer to Table 1 for number of samples required for each test to meet specification limits. 3.1.2 This specification is based on virgin materials. Materials with post-consumer, post industrial, or repolymerised recycl
7、ed materials as defined by WRS-M99P42-A1 are preferred and should be used whenever feasible. 3.1.3 The use of regrind is permitted, for economic / environmental reasons, with compliance as indicated in Ford Engineering CAD and Drafting Standard E-4. 3.1.4 Materials used in interior applications must
8、 meet the requirements outlined in WSS-M99P2222-C1/Latest, Performance, Vehicle Interior Environment Quality Material/Component Requirements. Data must be included in material submission package. ENGINEERING MATERIAL SPECIFICATION WSS-M4D550-A10 Copyright 2015, Ford Global Technologies, LLC Page 2 o
9、f 8 3.1.5 Performance Criteria: Parts using this specification shall meet the appropriate performance specification, WSS-M15P4-F/Latest for Hard, Interior, Molded-in-Color component performance or WSS-M15P45-B/Latest. 3.2 SAMPLE PREPARATION Unless otherwise specified all tests shall be carried out o
10、n injection molded, one-end gated test specimens. The test specimens A and D shall be molded using molding conditions defined in ISO 1873-2. No annealing is allowed. See Table 1 for the number of specimens required. Specimens shall be as follows: Specimen A 150 minimum x 10 x 4.0 +/- 0.2 mm (ISO 527
11、-2, Specimen Type 1A) Specimen B 355 x 100 x 1.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A. 80 x 10 x 4.0 +/- 0.2 mm Specimen E 100 mm diameter x 3.2 mm Specimen F 80 mm diameter x 3.2 mm Specimen G 90 mm x 200 mm Specimen H 50 +/- 1 mm diameter x 3.2
12、 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.3 APPEARANCE 3.3.1 Weathering Resistance Rating 4 min (FLTM BO 116-01, 3609.6 kJ/m2 exposure Specimen C from smooth polished mold, ISO 105-A02 / AATCC Evaluation Procedure 1) Every 526.4kJ/m2 remove the samples from the weatherometer and allow them to co
13、ol for one hour. Conduct a tactile evaluation and report any tackiness. Visually evaluate and report any spewing or other exudation. After exposure the material shall show no fading or color change in excess of specified AATCC rating. In addition, there shall be no cracking, crazing or other deterio
14、ration. Use regional choice colors for initial approval and report color house used. See Table 2 for additional color durability submission requirements. 3.3.2 Resistance to Scratch and Mar (FLTM BO 162-01, Specimen I) Scratch Rating 2 at 2N, max Whitening/Color Change Rating 1 at 15N, max Marring R
15、ating 2 at 2N, max These values are derived from colored and grained samples in agreement with Materials Engineering. Details regarding color house, let down ratio, colors, grain, etc can be found in the approval package. 3.4 MATERIAL PROPERTIES 3.4.1 Filler Content 16 - 22 % (ISO 3451-1, Method A,
16、1h at 850 +/- 50C, test portion 2 2.5g) ENGINEERING MATERIAL SPECIFICATION WSS-M4D550-A10 Copyright 2015, Ford Global Technologies, LLC Page 3 of 8 3.4.2 Density 1.01 1.07 g/cm3 (ISO 1183, Method A) 3.4.3 Tensile Strength at Yield 18 MPa min (ISO 527-1 Flow 7.7 E-5 mm/mm/ C 3.5.4 Coefficient of Line
17、ar Thermal Expansion; Cross Flow 8.5 E-5 mm/mm/ C 3.5.5.1 Impact Strength, Notched Izod at 23 +/- 2 C 30 kJ/m2 3.5.5.2 Impact Strength ,Notched Izod at -40 +/- 2 C 5 kJ/m2 3.5.6.1 Impact Strength, Multiaxial; Max Load Energy at 23 +/- 2 C 21 J 3.5.6.2 Impact Strength, Multiaxial; Max Load Energy at
18、0 +/- 2 C 22 J 3.5.7 Poissons Ratio 0.4 N/A 4.2 MATERIAL IDENTIFICATION FOR RECYCLING PURPOSES TPO-(PP+EPM)-TD20 (ISO 1043/11469) ENGINEERING MATERIAL SPECIFICATION WSS-M4D550-A10 Copyright 2015, Ford Global Technologies, LLC Page 6 of 8 5. SUMMARY OF REVISIONS 2015 08 21 Removed high from title to
19、align with the scope where it is listed as medium impact 2013 04 25 Updated recycling code 2012 10 02 Change Tensile Strength at yield from 20 MPa to 18 MPa. 2012 06 26 Updated title, added Limitations section, revised format to global resin template. Melt Flow, Impact Strength, Multiaxial Impact, I
20、zod Impact moved to report only Revised Weathering Resistance . Density, Filler Content, Resistance to Scratch, Flexural Modulus, Heat Deflection Temperature, Heat Aging Performance, Fogging, Added Mar resistance, Tensile Modulus, Notched Charpy Impact, Odor, Fogging Gravimetric Removed Shear Modulu
21、s, Table 1. ENGINEERING MATERIAL SPECIFICATION WSS-M4D550-A10 Copyright 2015, Ford Global Technologies, LLC Page 7 of 8 Table 1: Number of Specimens Required Initial Approval New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per lot Total Test Specimens Lo
22、ts Specimens per lot Total Test Specimens 3.1 WSS-M99P1111-A 3.1.3 WSS-M99P2222-C1 Total Carbon, Hazardous Substances, Formaldehyde, Acraldehyde, Acetaldehyde (See below for odor and fogging) 1 1 1 per test 3.1.4 Parts Performance Reference Performance Specification 3.3.1 Weathering Resistance 1 1 1
23、 3.3.2 Resistance to Scratch and Mar 1 1 1 3.4.1 Filler Content* 3 1 3 3 1 3 3.4.2 Density 1 3 3 3.4.3 Tensile Strength at Yield* 3 5 15 1 5 5 3.4.4 Tensile Modulus 1 10 10 3.4.5 Flexural Modulus* 3 10 30 1 10 10 3.4.6 Impact Strength, Notched Charpy, (per condition)* 3 10 30 1 10 10 3.4.7 Heat Defl
24、ection Temperature* 3 2 6 1 2 2 3.4.8 Heat Aged Properties 3.4.8.1 Tensile Strength at Yield Change 1 5 5 3.4.8.2 Impact Strength, Notched Charpy, Change 1 10 10 3.4.9 Odor 1 9 9 3.4.10 Fogging 1 3 3 3.4.11 Fogging Gravimetric 1 3 3 3.4.12 Flammability 1 5 5 3.5.1 Melt Flow Rate 3 1 3 1 1 1 3.5.2 El
25、ongation at Yield 3 5 15 1 5 5 3.5.3 Mold Shrinkage 1 5 5 3.5.4 Coefficient of Linear Thermal Expansion (per condition) 1 3 3 3.5.5 Impact Strength, Notched Izod (per condition) 1 10 10 3.5.6 Impact Strength, Multiaxial 3 10 30 1 10 10 3.5.7 Poissons Ratio 1 1 1 * For these requirements the 3 sigma
26、value from the raw data is used to meet the requirements. ENGINEERING MATERIAL SPECIFICATION WSS-M4D550-A10 Copyright 2015, Ford Global Technologies, LLC Page 8 of 8 Table 2: Minimum Color Property Testing Contact Materials Engineering for Color Test Work Plan Para. Test Lots Specimens per Lot Total
27、 Test Specimens Color Test Direction 3.3.1 Weathering Resistance 1 1 1 Every Color 3.3.2 Resistance to Scratch and Mar 1 3 3 As directed by Materials Engineering 3.4.3 Tensile Strength at Yield 1 5 5 As directed by Materials Engineering 3.4.5 Flexural Modulus 1 10 10 As directed by Materials Engineering 3.4.6 Impact Strength, Notched Charpy at 23 +/- 2 C 1 10 10 As directed by Materials Engineering 3.4.9 Odor 1 9 9 As directed by Materials Engineering 3.4.11 Fogging Gravimetric 1 3 3 As directed by Materials Engineering 3.4.12 Flammability 1 5 5 Every Color