1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions REV 02 2013 05 13 Revised Editorial See Summary of Revisions G. Eaton, NA 2012 11 21 Revised See Summary of Revisions G. Eaton, NA 2012 03 15 Activated Georgette Eaton, NA Controlled document at www.MATS Copyright 2013, Ford Global Technologi
2、es, LLC Page 1 of 6 POLYPROPYLENE (PP) WSS-M4D865-B7 20% LONG GLASS FIBER REINFORCED, STRUCTURAL, NON UV-STABLE, INTERIOR 1. SCOPE The material defined by this specification is an injection molding compound composed of a polypropylene matrix, with 20% by weight long glass fiber reinforcement with ty
3、pical fiber length between 9-16 mm. 2. APPLICATION This specification was released originally for material used for instrument panel structures. 2.1 LIMITATIONS This material does not contain UV stabilizers, long term exposure to direct sunlight will cause chalking and loss of gloss. Use WSS-M4D865-
4、B5/latest for visible, color matched applications. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). Note: Many 4D resin specifications prior to 2011,
5、identified certain requirements with the symbol (s), which indicated that the mean and +/- 3 sigma values were to be reported. The specification minimum, maximum or range was established using 3 sigma data. For 2011 and beyond, refer to Table 1 for number of samples required for each test to establi
6、sh specification limits. 3.1.1 This specification is based on virgin materials, however materials with recycled content as defined by WRS-M99P42-A1 (post-consumer and/or post industrial recyclates and repolymerised recycled materials) should be used whenever technically feasible and following all ma
7、terials and PV testing required by Ford Materials Engineering. The use of regrind is permitted, for economic / environmental reasons, with compliance as indicated in WSS-M99P1111-A. 3.1.2 Materials used in interior applications must meet the requirements outlined in WSS-M99P2222-C1/Latest, Performan
8、ce, Vehicle Interior Environment Quality Material/Component Requirements. Data must be included in material submission package. 3.1.3 Components made with this material must also meet the performance specification WSS-M15P45-B/latest or WSS-M15P4-F/latest requirements. 3.1.4 Processing Criteria: Pro
9、per processing parameters and equipment should be used to preserve maximum fiber length in molded parts as specified and measured by the raw material supplier. ENGINEERING MATERIAL SPECIFICATION WSS-M4D865-B7 Copyright 2013, Ford Global Technologies, LLC Page 2 of 6 Raw material supplier must be inv
10、olved upfront for mold flow, CAE, and tooling design and should be present at all molding trials. WSS-M99D514-A1 is to be used for thermoplastic compounds using long glass fiber masterbatch pellets. WSS-M99D514-A2 is to be used for thermplastic compounds using Direct Long glass Fiber Technology (DLF
11、T) or Injection Molding Compounding (IMC). 3.2 SAMPLE PREPERATION Unless otherwise specified all tests shall be carried out on injection molded, one-end gated test specimens. The test specimens A and D shall be molded using molding conditions defined in ISO 1873-2. No annealing is allowed. See Table
12、 1 for the number of samples required. Specimens shall be as follows: Specimen A 150 minimum x 10 x 4.0 +/- 0.2 mm (ISO 527-2, Specimen Type 1A) Specimen B 355 x 100 x 1.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A. 80 x 10 x 4.0 +/- 0.2 mm Specimen E
13、100 mm diameter x 3.2 mm Specimen F 80 mm diameter x 3.2 mm Specimen G 90 mm x 200 mm Specimen H 50 +/- 1 mm diameter x 3.2 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.3 MATERIAL PROPERTIES 3.3.1 Glass Fiber Content 18% - 22% (ISO 3451-1, Method A, 1h at 650 +/- 25C, test portion, 2 2.5 g) 3.3.2 De
14、nsity 1.01 1.05 g/cm3 (ISO 1183, Method A) 3.3.3 Tensile Strength at Break 64 MPa min (ISO 527-1 and ISO 527-2, Specimen A, 5 mm/minute test speed) 3.3.4 Tensile Modulus 4.1 GPa min (ISO 527-1 & ISO 527-2, Specimen A, 1 mm/minute test speed) 3.3.5 Flexural Modulus 4.1 GPa min (ISO 178, Specimen D, 6
15、4 mm support span, 2 mm/minute test speed) 3.3.6 Impact Strength Notched Charpy (ISO 179/1/2, Specimen D) 3.3.6.1 At 23 +/- 2 C 14 kJ/m2 min Report Break Type 3.3.6.2 At -40 +/- 2 C 15 kJ/m2 min Report Break Type The test specimens must be conditioned for min of 6 hours ENGINEERING MATERIAL SPECIFIC
16、ATION WSS-M4D865-B7 Copyright 2013, Ford Global Technologies, LLC Page 3 of 6 at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box, if not possible, test can be conducted outside, but within 5 seconds. 3.3.7 Heat Deflection Temperature 15
17、2 C min (ISO 75-1 & ISO 75-2 Specimen D, flatwise, 0.34 +/- 0.1 mm deflection. At 1.80 MPa) 3.3.8 Heat Aging Performance (ISO 188, 150 +/- 50 air changes/h, 1000 h at 140 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.3.8.1 Tensile Strength at
18、 Break, Change +/- 25% max (Test Method per para 3.3.3) 3.3.8.2 Impact Strength, Notched Charpy Change +/- 25% max (Test Method per para 3.3.6.1, specimens to be notched before Heat Aging) 3.3.9 Odor Rating 3 max (FLTM BO 131-03, Specimen G) 3.3.10 Fogging Photometric (SAE J1756, 3 h at 100 C heatin
19、g, 21 C cooling plate, post test conditioning 16 h) Fog Number 70 min Formation of clear film, droplets or crystals is cause for rejection. 3.3.11 Fogging Gravimetric 2.5 mg max (SAE J1756, Specimen F, 16h at 100 C heating, 21 C cooling plate, post test conditioning 4 h) 3.3.12 Flammability (ISO 379
20、5/SAE J369, Specimen B smooth surface) Burn Rate 100 mm/minute max 3.4 MATERIAL PROPERTIES REPORT ONLY Values are retained in Ford Materials Database 3.4.1 Molding Shrinkage Report method used, sample size and value. After 48 h at 23 +/- 2 C, Flow Report Value, % Cross Flow Report Value, % ENGINEER
21、ING MATERIAL SPECIFICATION WSS-M4D865-B7 Copyright 2013, Ford Global Technologies, LLC Page 4 of 6 3.4.2 Coefficient of Linear Thermal Expansion (ISO 11359-2 TMA, temperature range -30 to +30 C) Flow Report Value, E-5 mm/mm/ C Cross Flow Report Value, E-5 mm/mm/ C 3.4.3 Impact Strength Notched Izod,
22、 (ISO 180/1A, Specimen D) 3.4.3.1 At 23 +/- 2 C Report Value, kJ/m2 Report Break Type 3.4.3.2 At -40 +/- 2 C Report Value, kJ/m2 Report Break Type The test specimen must be conditioned for minimum of 6 hours at the above specified temperature prior to impact test. Low temperature testing shall be do
23、ne within the cold chamber, if not possible, test may be conducted outside, but within 5 seconds. 3.4.4 Poissons Ratio Report Ratio (ISO 527-1/2, Specimen A, 1 mm/minute test speed) 3.4.5 Supplemental Information The following curves are to be submitted with the data packages: FTIR TGA DSC CLTE Engi
24、neering Stress/Strain at 23 C 4. GENERAL INFORMATION The information given below is provided for clarification and assistance in meeting the requirements of this specification. Contact for questions concerning Engineering Material Specifications. ENGINEERING MATERIAL SPECIFICATION WSS-M4D865-B7 Cop
25、yright 2013, Ford Global Technologies, LLC Page 5 of 6 4.1 TYPICAL PROPERTIES USING METHODS IN SECTION 3.4 Para. Test Typical Value Units 3.4.1 Molding Shrinkage After 48 h at 23 +/- 2 C (For specific method and sample size, contact Materials Engineering) Flow Cross Flow 0.35-0.45 0.61-0.79 % % 3.4.
26、2 Coefficient of Linear Thermal Expansion Flow Cross Flow 5.3 7.7 E-5 mm/mm/ C E-5 mm/mm/ C 3.4.3 Impact Strength, Notched Izod, At 23 +/- 2 C At -40 +/- 2 C 19 19 kJ/m2 kJ/m2 3.4.4 Poissons Ratio 0.34 N/A 4.2 MATERIAL IDENTIFICATION FOR RECYCLING PURPOSES PP-GLF20 (ISO 1043/ISO 11469) ENGINEERING M
27、ATERIAL SPECIFICATION WSS-M4D865-B7 Copyright 2013, Ford Global Technologies, LLC Page 6 of 6 Table 1: Minimum Sample Size Initial Approval New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per Lot Total Test Specimens Lots Specimens per lot Total Test Spe
28、cimens 3.1 WSS-M99P1111-A 3.1.1 WSS-M99P2222-C1/Latest Total Carbon, Hazardous Substances, Formaldehyde, Acraldehyde, Acetaldehyde (See below for Odor and Fogging) 1 1 1 per test 3.3.1 Glass Fiber Content* 3 1 3 1 1 1 3.3.2 Density 1 3 3 3.3.3 Tensile Strength at Break* 3 5 15 1 5 5 3.3.4 Tensile Mo
29、dulus 1 10 10 3.3.5 Flexural Modulus* 3 10 30 1 10 10 3.3.6 Impact Strength Notched Charpy (per condition)* 3 10 30 1 10 10 3.3.7 Heat Deflection Temperature* 3 2 6 1 2 2 3.3.8 Heat Aging Performance 3.3.8.1 Tensile Strength at Break, Change 1 5 5 3.3.8.2 Impact Strength, Notched Charpy, Change 1 10
30、 10 3.3.9 Odor 1 9 9 3.3.10 Fogging Photometric 1 3 3 3.3.11 Fogging Gravimetric 1 3 3 3.3.12 Flammability 1 5 5 3.4.1 Molding Shrinkage 1 5 5 1 5 5 3.4.2 Coefficient of Linear Thermal Expansion (per condition) 1 3 3 3.4.3 Impact Strength, Notched Izod (per condition) 1 10 10 3.4.4 Poissons Ratio 1
31、2 2 3.4.5 Curves - FTIR - TGA - DSC - CLTE - Stress/Strain Curves 1 1 1 per test * For these requirements, the 3 Sigma value from the raw data is used to set the requirement max or min. 5. SUMMARY OF REVISIONS 5/13/2013 Editorial Change Removed fiber length from title and changed the length in the scope from 9-13 mm to 9-16 mm. 11/21/12 3.3.5 Modified Flexural Modulus value from 4.2 to 4.1 min.
