1、 545032011 ISO 6468:1996(NEQ) 27 2002 . 184- , 1.02004 . 1 - 2 343 3 22 2011 . 568-4 6468:1996 . , . - (ISO 6468:1996 Water quality Determination of certainorganochlorine insecticides, polychlorinated biphenyls and chlorobenzenes Gas chromatographic methodafter liquid-liquid extraction, NEQ)5 , - .
2、) . - , , 2013 , - - II 5450320111 .12 13 24 .35 - ( ) .36 ( ).13 () , , 19 () - 20 () 22 () 23 () - 24 () 6 - 25 () 26 () . . 2728III 545032011 ( ) . -, (), , 1 10 , - , C12HnCln, n =1c184 10. - IUPAC (International Union of Pure and Applied Chemistry ) 1 209 -., , - , , - , , , , , , , . . , - ,
3、 , - . . , , . -, -, - - ( 0,6 ) - 17 210 , . -, -, . 0,00076/3() 4 /3(). , , -, , . ,0,5/320/3. , , , ( 4 9) , - - . - . - - , , , . 60, 77, 81, 126, 169, 105, 114, 118, 123, 156,157,167,189, .- () 2,3,7,8-. , , .IV 545032011 Water. Method for determination of polychlorinated biphenyls 201301011 ,
4、 , - ( ) - ( ):2,4,4c162 ( 28);2,2c162,5,5c162 ( 52);2,2c162,4,5,5c162 ( 101);2,3c162,4,4c162,5 ( 118);2,2c162,3,4,4c162,5c162 ( 138);2,2c162,4,4c162,5,5c162 ( 153);2,2c162,3,4,4c162,5,5c162 ( 180);2,2c162,3,3c162,4,4c162,5,5c162 ( 194) :- - - () - ( 28, 52, 101, 118, 138, 153, 180) , 2 /3 100000 /3
5、 2/3 3,5c215106/3;- - ( ) - ( 28, 52, 101, 118, 138, 153, 180, 194) 10 /3 50000 /3. .2 : 5725-62002 ( ) . 6. / 170252006 - * 515922000 . 515932000 . 524062005 . 523612005 . 532282008 . 1. . * . 01.01.2012 / 170252009.1 545032011 7452003 . 127775 . . 177074 . , , , . 260379 . . 416676 . . 446177 . .
6、670972 . 699577 . -. 914780 . 929374 ( 243573) . 996886 . 1426278 . 2124189 . 2436380 . . 2533682 . , 2831189 . - - - , 1 , , . (), ()., ,- , .3 :3.1 (analyte): , . 52361, 173.2 (reference material): , -, , - . 52361, 303.3 (blank experiment): . 52361, 313.4 blank (sample): , - , . 52361, 322 5450320113.5 (internal standard): , , - , .3.6 (surrogate standard): , - , - .3.7 (recovery standard): , - .4 4.1 51592 51593. - . - , . 0,5 3, - . . - .4.2 8, 58 - . c - .4.3 2 5 . :4.3.1 :- 50 3 (. 5.3.12.1) 1 .4.3.2 :- (. 6.2) 24 2 . , , .5 - ( )5.1 , , - - (selected ion monitoring SIM) - . .1 , - ,
