1、Gas Processors Association Technical Publication TP-17 (1998 Revision) Table of Physical Properties of Hydrocarbons for Extended Analysis of Natural Gases Dr. Michael Frenkel and Dr. Ken Hall Thermodynamics Research Center Texas A and for the infringement of any patent or the violation of any federa
2、l, state or municipal law or regulation arising from the use of any information, apparatus, method or process disclosed in this report. IICopyright 1998 by Gas Processors Association. All rights reserved. No part of this Report may be reproduced without the written consent of the Gas Processors Asso
3、ciation. II Note:Numbers in this table donot have accuracies gr3tcr th3n 1 p3.rt in 1000: in some cases extra digits hal. been odded to calculated values to achic1! internal consistancy or to pennlt t!c.llculation of experimental value See Note No. - Compound t .D S i 1 Methane 2 Ethane 3 Propane 4
4、Isobutane 5 n-Butane 6 2,2-Dimethylpropane 7 Isopentane 8 lI-Pcntane 9 2.2-Dimethylbutane 10 2.3-Dimethylbutane 11 CycJopelltalle 12 2-Mcthylpentane 13 3-Methylpentane 14 II-Hexane 15 2.2-Dimethylpentalle 16 Mt!thyJcycJopelltalle 17 2,4-Dimethylpentane 18 2,2,3-Trimethylbutane 19 Benzene 20 3,3-Dime
5、thylpelltalle 21 CycJohexane 22 2-Methylhexane 23 2,3-Dimethylpentane 24 l,l-DimethylcycJopentane 25 3-Methylhexalle 26 1.t-3-DimethylcycJopelltane 27 l,c-3-DimthylcycJopentane 28 3-Ethylpcntane 29 l,t-2-DimethylcycJopentane 30 2,2,4-Trimethylpentane 31 II-Heptane 32 MethylcycJohexane 33 1.1.3-Trimc
6、thylcycJopentane 34 2,2-Dimcthylhexane 35 l.c-2-Dimethylcycopentane 36 2,5-Dimethylhexane 37 2,4-Dimdhylhexane 38 EthylcycJopentane 39 2,2,3-Trimethylpentalle 40 l,t-2,c4-Trimethylcyclopelltane 41 3,3-Dimethylhexalle 42 l,t-2,c-3-Trimethylc 43 2,3,4-Trimethylpcntane 44 2,3-Dimethylhexane 45 Toluene
7、46 1.1.2-TrimethylcycJopentane 47 1.c-2.t4-Trimethy1cycJopentane 48 2-Methylheptane 49 4-Methylheptane 50 3.4-Dimethylhexane 51 3-Methylheptane 52 3-Ethylhexane 53 l,c-3-DimethyJcycJohexane 54 l,c-2,t-3-TrimethyJcycJopelltane 55 1.t4-Dimethylcyclohexane 56 2,2,5-Trimethylhexane 57 1,1-Dimethylcycloh
8、exane 58 I-Methyl-t-3-ethylcyclopentane 59 I-Methyl-c-3-ethylcycJopentane ENGINEERING UNITS PHYSICAL CONSTANTS A B Z d 00 U-. 0 Ol .S “ gj l Z * * * 0.0984 1 * * * 0.0775 2 * * * 0.0727 3 * * * 0.0714 4 * * * 0.0703 5 36.349 463.5 321.17 0.0682 6 * * * 0.0679 7 * * * 0.0690 8 9.728 449.6 420.53 0.06
9、65 9 7.298 456.9 440.33 0.0671 10 9.781 654.1 461.39 0.0592 11 6.665 440.9 436.19 0.0684 12 5.963 452.5 448.61 0.0684 13 * * * 0.0684 14 3.431 401.8 477.23 0.0665 15 4.414 549.7 499.19 0.0605 16 3.234 397.4 475.97 0.0668 17 3.317 427.9 496.31 0.0636 18 3.160 710.0 552.02 0.0525 19 2.724 427.9 505.85
10、 0.0662 20 3.207 591.8 537.17 0.0586 21 2.227 397.4 495.05 0.0673 22 2.307 422.1 507.47 0.0628 23 2.514 493.1 524.93 0.0609 24 2.089 407.6 503.69 0.0646 25 2.249 493.1 535.73 0.0609 26 2.167 493.1 532.13 0.0609 27 1.966 419.2 513.41 0.0665 28 2.150 493.1 535.73 0.0609 29 1.674 372.7 519.17 0.0656 30
11、 * * * 0.0684 31 1.576 504.7 570.11 0.0602 32 1.364 420.6 553.73 0.0602 33 1.194 366.9 529.97 0.0670 34 1.616 477.2 561.47 0.0600 35 1.076 361.1 530.33 0.0676 36 1.073 371.3 536.63 0.0662 37 1.380 493.1 565.43 0.0612 38 1.118 396.0 554.63 0.0611 39 1.137 438.0 556.97 0.0610 40 1.008 384.4 551.93 0.0
12、621 41 1.114 438.0 559.31 0.0610 42 0.9553 396.0 559.85 0.0645 43 0.8406 381.4 554.63 0.0656 44 1.008 595.8 605.48 0.0549 45 0.9773 450.6 592.79 0.0602 46 0.8621 438.0 576.77 0.0610 47 0.7522 362.6 547.79 0.0684 48 0.7463 368.4 551.39 0.0667 49 0.7789 390.2 564.17 0.0653 50 0.7124 369.8 554.81 0.065
13、1 51 0.7299 378.5 558.23 0.0638 52 0.6355 459.8 596.21 0.0595 53 0.8327 459.8 594.23 0.0595 54 0.8022 459.8 598.19 0.0595 55 0.6080 343.4 565.97 0.0653 56 0.8022 459.8 594.23 0.0595 57 0.7210 438.0 587.57 0.0610 58 0.6972 438.0 589.19 0.0610 59 Note:Numbers in this table donot h:le accuracies greate
14、r than 1 part in 1000: in some cases exira digits have heen added to calculated values to achieve internal consistancy or to pennit recalculation of experimental value See Note No. - . Compound :s .D E :I z 60 I-Methyl-t-2-ethylcyclopentane 61 2,2,4-Trimethylhexane 62 I-Methyl-l-ethylcyclopentane 63
15、 Cycloheptane 64 n-Octane 65 2,2,4,4-Tetramethylpentane 66 l,t-3-Dimethylcyclohexane 67 l,c-4-Dimethylcyclohexane 68 l,c-2,c-3-Trimethylcyclopentane 69 2,4,4-Trimethylhexane 70 Isopropylcyclopentane 71 2,3,5-Trimethylhexane 72 2,2-Dimethylheptane 73 2,4-Dimethylheptane 74 l-Ethyl-c-2-methylcyclopent
16、ane 75 2,2,3-Trimethylhexane 76 l,c-2-DimethYlcyclohexane 77 2,6-Dimethylheptane 78 n-PropylcycJopentane 79 l,c-3,c-5-TrimethylcycJohexane 80 Ethylcyclohexane 81 2,5-Dimethylheptane 82 3,5-Dimethylheptane 83 1,I,3-TrimethylcycJohexane 84 2,3,3-Trimethylhexane 85 3,3-Dimethylheptane 86 1,1,4-Trimethy
17、lcyc10hexane 87 2,2,3,3-Tetramethylpentane 88 Ethylbenzene 89 2,3,4-Trimethylhexane 90 l,t-2,t-4-Trimethylcyclohexane 91 l,c-3,t-5-Trimethylcyclohexane 92 Xylene 93 p-Xylene 94 3,4-Dimethylheptane 95 2-Methyloctane 96 4-Methyloctane 97 3-Methyloctane 98 l,t-2,c-3-TrimethylcycJohexane 99 l,t-2,c-4-Tr
18、imethylcycJohexane 100 a-Xylene 101 1,1,2-Trimethylcyclohexane 102 n-Nonane 103 l,c-2,t-3-TrimethylcycJohexane 104 l,c-2,c-3-TrimethylcycJohexane 105 Isopropylbenzene 106 IsopropyJcyclohexane 107 Cyclooctane 108 n-ButylcycJopentane 109 PropylcycJohexane 110 n-PropyJbenzene 111 m-Ethyltoluene 112 p-E
19、thyltoluene 113 4-Methylnonane 114 5-Methylnonane 115 1,3,5-Trimethylbenzene 116 2-Methylnonane 117 3-Ethyloctane 118 3-Methvlnonane ENGINEERING UNITS PHYSICAL CONSTANTS A B Z d ell u 0 0 . “ .S ta o . “ E3 o;s. 3 . S U “ ., 01 =s :2;,-, :! CSHI6 112.215 250.15 C9Hzo 128.258 262.25 C,H16 112.215 250
20、.70 C7HI4 98.188 245.81 C,H!, 114.231 * C9Hzo 128.258 252.12 CSHI6 112.215 250.46 C,HI6 112.215 255.80 C,HI6 112.215 253.39 C9Hzo 128.258 267.19 C.H!6 112.215 259.51 C9Hzo 128.258 268.46 C9Hzo 128.258 271.08 C.Hzo 128.258 271.75 C,H!6 112.215 262.45 C9Hzo 128.258 272.44 C,HI6 112.215 265.54 C9Hzo 12
21、8.258 275.41 CSHI6 112.215 267.67 C9H18 126.242 281.12 C,HI6 112.215 269.28 C.Hzo 128.258 276.75 C.Hzo 128.258 276.26 CsH 126.242 277.92 C.Hzo 128.258 279.84 C9Hzo 128.258 278.65 C9HI 126.242 274.93 C9Hzo 128.258 284.53 C,Hlo 106.167 277.09 C9Hzo 128.258 282.10 C9HI, 126.242 286.22 C.HI, 126.242 284
22、.91 C,Hlo 106.167 282.35 C,Hlo 106.167 280.99 C9Hzo 128.258 284.72 C9Hzo 128.258 289.93 C.Hzo 128.258 288.39 C9Hzo 128.258 291.60 C9HI, 126.242 294.08 C.HI, 126.242 293.05 C.Hlo 106.167 291.96 C9H18 126.242 294.85 C9Hzo 128.258 * C9H18 126.242 303.75 C.HI, 126.242 304.53 C.Hlz 120.194 306.27 C.H18 1
23、26.242 310.19 C,HI6 112.215 304.Q1 C.HI, 126.242 314.Q1 C9HI, 126.242 314.09 C9HIZ 120.194 318.56 C9HIZ 120.194 322.41 C9HIZ 120.194 323.56 CloHzz 142.285 330.21 CloHzz 142.285 329.27 C9HIZ 120.194 328.54 CloHzz 142.285 332.59 CloHzz 142.285 331.71 CIOHzz 142.285 334.05 2 *See Table of notes for Ref
24、erences Critical Constants . “ 0 Q) u E . r :I .;S Q.) .D “ “ . : “ 0-.a 2 Q.) “ 0 . :s S ., u :I S o 0 Vl :I g z 0.7053 438.0 588.65 0.0610 60 0.5790 343.4 577.67 0.0653 61 0.7087 438.0 594.41 0.0610 62 0.7794 554.0 627.89 0.0576 63 * * * 0.0690 64 0.7139 361.1 574.61 0.0646 65 0.7578 459.8 608.09
25、0.0595 66 0.6452 440.8 616.55 0.0595 67 0.6754 438.0 593.33 0.0610 68 0.4923 343.4 588.29 0.0653 69 0.5873 523.6 621.23 0.0544 70 0.4567 345.2 589.01 0.0645 71 0.4248 340.8 578.39 0.0654 72 0.3979 333.6 586.13 0.0656 73 0.5376 438.0 589.19 0.0610 74 0.4260 438.0 594.41 0.0533 75 0.5270 459.8 638.33
26、0.0595 76 0.3674 339.8 585.23 0.0659 77 0.4593 438.0 613.49 0.0610 78 0.4000 411.9 620.33 0.0599 79 0.4708 459.8 624.65 0.0595 80 0.3567 333.6 586.13 0.0656 81 0.3606 346.6 593.33 0.0642 82 0.4103 417.0 642.11 0.0596 83 0.3758 343.4 606.65 0.0653 84 0.3608 355.3 604.13 0.0652 85 0.4740 411.9 611.33
27、0.0599 86 0.3524 397.4 633.83 0.0646 87 0.3576 523.4 651.20 0.0564 SS 0.3395 342.4 602.15 0.0651 S9 0.4423 384.2 641.75 0.0597 90 0.4534 384.2 624.29 0.0597 91 0.3196 513.6 650.93 0.0566 92 0.3322 509.2 649.49 0.0570 93 0.2995 364.0 612.77 0.0639 94 0.2484 335.0 589.37 0.0678 95 0.2571 337.2 596.39
28、0.0666 96 0.2392 339.4 602.15 0.0664 97 0.3808 384.2 653.27 0.0597 98 0.3884 384.2 651.83 0.0597 99 0.2569 541.3 674.87 0.0558 100 0.3160 411.9 638.33 0.0599 101 * * * 0.0693 102 0.3166 384.2 667.67 0.0597 1113 0.3120 384.2 668.75 0.0597 104 0.1827 465.4 676.13 0.0574 1115 0.1854 415.2 679.55 0.0592
29、 106 0.2097 516.3 705.29 0.0585 107 0.1564 400.9 664.43 0.0610 lOS 0.1639 390.6 676.49 0.0600 109 0.1368 464.1 689.36 0.0586 110 0.1206 456.9 687.29 0.0569 111 0.1200 468.5 692.69 0.0569 112 0.09180 308.1 636.71 0.0664 113 0.09454 308.1 635.45 0.0664 114 0.09786 453.5 687.47 0.0569 115 0.08230 297.3
30、 637.07 0.0677 116 0.09141 308.1 638.69 0.0664 117 0.08211 310.4 644.99 0.0665 118 NOle:Numbers in this table donot have accuracies greater than 1 part in 1000: in some cases extra digits have been added to calculated values to achieve internal consistancy or to permit recalculation of experimental
31、value See Note No. - Compound 119 o-Ethyltoluene 120 1,2,4-Trimethylbenzene 121 tert-Butylbenzene 122 Methylcyclooctane 123 tert-Butylcyclohexane 124 Isobutylcyclohexane 125 n-Decane 126 Isobutylbenzene 127 sec-Butylbenzene 128 I-Methy 1,3-isopropylbenzene 129 1,2,3-Trimethylbenzene 130 I-Methyl-4-i
32、sopropylbenzene 131 I-Methyl-2-isopropylbenzene 132 n-Butylcyclohexane 133 1,3-Diethylbenzene 134 1-Methyl-3-propylbenzene 135 1,2-Diethylbenzene 136 n-Butylbenzene 137 I-Methyl-4-propylbenzene 138 1,4-Diethylbenzene 139 I-Methyl-2-propylbenzene 140 n-Undecane 141 1,2,4,5-Tetramethylbenzene 142 1,2,
33、3,5-Tetramethylbenzene 143 1,2,3,4-Tetramethylbenzene 144 Cyclodecane 145 Naphthalene 146 n-Dodecane 147 2,3-Dimethylheptane 148 l,c-2,t-4-Trimethylcyclohexane 149 l,c-2,c-4-Trimethylcyclohexane 150 Isobutylcyclopentane 151 2,2-Dimethyloctane 152 3,3-Dimethyloctane 153 3,6-Dimethyloctane 154 2,3-Dim
34、ethyloctalle 155 1,4-Dimethyl-2-ethylbenzene 156 l,2-Dimethyl-4-ethylbenzene 157 l,3-Dimethyl-2-ethylbenzene 158 l,2-Dimethyl-3-ethylbenzene 159 (2-Methylbutyl)benzene 160 1-tert-Butyl-2-methylbenzene 161 ll-Pentylbenzene 162 I-Methyl-t-2-(4-methylpentyl) cyclopentane 163 1-terl-B utyl-3 ,5-dimethyl
35、benzene 164 1,2,4-Triethylbenzene 165 1,3,5-Triethylbenzene 166 n-Hexylbenzene 167 n-Tridecalle 168 n-Tetradecane 169 n-Pentadecane i! ENGINEERING UNITS PHYSICAL CONSTANTS A B 0 o:J 0 ., oS (OJ gj lit 8: gjlO ._ C o If Pou i 8 S !; CgH12 120.194 329.26 0.10308 CgH12 120.194 336.82 0.08527 C1oH14 134
36、.221 336.40 0.08992 C9H18 126.242 323.59 0.1004 C1oH20 140.269 340.85 0.09397 C1oHzo 140.269 340.36 0.08788 C10Hzz 142.285 * * C1oH14 134.221 342.95 0.07860 ClOH14 134.221 343.93 0.07868 ClOH14 134.221 346.90 0.06648 C9H1Z 120.194 348.94 0.06379 ClOH14 134.221 350.79 0.06249 C1oH14 134.221 352.98 0.
37、06312 C1oHzo 140.269 357.70 0.05429 ClOH14 134.221 357.97 0.04769 ClOH14 134.221 362.09 0.06225 C1oH14 134.221 362.15 0.04396 ClOH14 134.221 361.87 0.04880 C1oH14 134.221 362.09 0.06225 ClOH14 134.221 362.74 0.04421 C1oH14 134.221 364.87 0.05855 CllHz4 156.312 384.60 0.01912 C1oH14 134.221 386.34 0.
38、02306 C1oH14 134.221 388.51 0.01297 C1oH14 134.221 400.73 0.01194 C1oHzo 140.269 396.18 0.02509 CloHs 128.174 424.31 0.01035 C1zHz6 170.338 421.32 0.00774 C9Hzo 128.258 284.92 0.29822 C9H18 126.242 298.40 0.35068 C9H18 126.242 294.77 0.37577 C9H18 126.242 298.40 0.26766 C1oH22 142.285 314.48 0.13864
39、 C1oH22 142.285 322.09 0.12446 ClOH22 142.285 321.50 0.11766 COH22 142.285 315.80 0.12343 C1oH14 134.221 368.13 0.05972 ClOH14 134.221 373.06 0.05366 C1oH14 134.221 374.oI 0.05256 C1oH14 134.221 381.03 0.04512 CllH16 148.248 384.99 0.03253 CllH16 148.248 392.73 0.03463 CllH16 148.248 401.89 0.01523
40、C12H24 168.323 417.20 0.01850 C12H18 162.274 402.98 0.01340 C12H8 162.274 426.20 0.00020 C12H18 162.274 420.40 0.00734 C1zH18 162.274 438.82 0.00588 C13H28 184.365 455.81 0.00263 C14H30 198.392 488.17 0.00093 ClsHn 212.419 519.23 0.00040 3 *See Table of notes for References Critical Constants 8 . .0
41、 0: c. 1 1: z 477.2 705.29 0.0569 119 468.8 708.71 0.0569 120 406.1 701.33 0.0574 121 434.5 713.39 0.0579 122 384.6 713.21 0.0581 123 432.2 701.51 0.0549 124 * * 0.0703 125 442.4 710.33 0.0573 126 419.2 708.53 0.0567 127 414.8 708.53 0.0573 127 501.0 736.43 0.0569 129 406.1 713.93 0.0573 130 414.8 7
42、16.63 0.0573 131 355.3 707.45 0.0602 132 418.3 724.oI 0.0582 133 414.8 721.85 0.0575 134 418.3 730.13 0.0582 135 419.2 729.23 0.0593 136 414.8 725.63 0.0575 137 406.5 724.73 0.0582 138 414.8 729.59 0.0575 139 287.2 690.53 0.0706 140 420.6 757.13 0.0575 141 405.2 765.05 0.0582 142 405.2 782.69 0.0582
43、 143 428.4 816.71 0.0568 144 587.4 887.45 0.0509 145 264.0 724.73 0.0709 146 349.5 604.85 0.0653 147 411.9 629.33 0.0599 148 411.9 640.13 0.0599 149 462.7 654.71 0.0553 150 306.0 624.65 0.0664 151 327.8 647.15 0.0653 152 319.1 637.25 0.0645 153 322.0 647.87 0.0655 154 414.8 734.45 0.0575 155 414.8 7
44、41.29 0.0575 156 414.8 742.73 0.0575 157 414.8 752.81 0.0575 158 377.1 740.93 0.0573 159 375.6 764.33 0.0579 160 375.6 762.17 0.0580 161 359.7 766.13 0.0563 162 326.3 748.13 0.05S3 163 343.7 775.13 0.0584 164 353.2 762.53 0.0584 165 337.9 793.67 0.0584 166 243.7 757.13 0.0715 167 227.7 787.73 0.0722
45、 168 214.7 814.73 0.0728 169 Numbers in this table do not have accuracies greater !han 1 part In 1000 : in some cases exlm digits haye been added to calculated values to achieve internal consistency or to permit recalculation of experimental value C D I. 0 oW I:l 0 s 0 td 0. “ b.Oo. z 0 . S a 0 “0 I
46、. c:II. .g 6h l , -I:l . a u 0 oJ OJ a ZI. b.O .0 0.!J: CI.) 0 l s s 8 I a b.O uO * * (6.4) -* * 10.066 -* * 10.408 -0.00156 * * 12.369 -0.00120 * * 11.923 -0.00108 0.59687 4.9762 14.499 -0.00104 * * 13.843 -0.00089 * * 13.700 -0.00086 0.65421 5.4543 15.800 -0.00077 0.66652 5.5569 15.508 -0.00073 0.
47、75040 6.2562 11.210 -0.00073 0.65845 5.4896 15.698 -0.00078 0.66952 5.5819 15.439 -0.00075 * * 15.554 -0.00075 0.67876 5.6590 17.707 -0.00070 0.75405 6.2867 13.387 -0.00069 0.67781 5.6510 17.732 -0.00072 0.69480 5.7927 17.298 -0.00068 0.88517 7.3799 10.585 -0.00067 0.69761 5.8161 17.229 -0.00058 0.7
48、8401 6.5365 12.876 -0.00066 0.68375 5.7006 17.578 -0.00070 0.69993 5.8354 17.172 -0.00066 0.75923 6.3298 15.512 -0.00064 0.69217 5.7708 17.364 -0.00069 0.75355 6.2825 15.629 -0.00064 0.75064 6.2582 15.689 -0.00070 0.70339 5.8643 17.087 -0.00069 0.75648 6.3069 15.568 -0.00065 0.69674 5.8088 19.665 -0
49、.00065 * * 17.453 -0.00068 0.77442 6.4565 15.208 -0.00062 0.75334 6.2807 17.867 -0.00064 0.70019 5.8376 19.568 -0.00066 0.77780 6.4846 15.142 -0.00064 0.69852 5.8237 19.615 -0.00066 0.70518 5.8792 19.430 -0.00063 0.77164 6.4333 15.263 -0.00062 0.72055 6.0073 19.015 -0.00060 0.75226 6.2718 17.892 -0.00063 0.71464 5.9581 19.173 -0.00062 0.75870 6.3254 17.740 -0.00063 0.72361 6.0329 18.935 -0.00060 0.71685 5.9765 19.113 -0.00061 0.87234 7.2729
