1、b MIL-C-22230B 68 m 4777706 0117878 7 m INCH - POUND NIL-C-22230B (SH) 19 October 1987 SUPERSEDING MIL-C-22230A(SHIPS) 24 February 1969 (See 6.5) MILITARY SPECIFICATION CLEANING COMPOUND, FUEL TANK AND BILGE This specification is approved for use within the Naval Sea Systems .Command, Department of
2、the Navy, and is available for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers cleaning compound for use in cleaning fuel oil tanks and machinery space bilges. 2. APPLICABLE DOCUPlENTS 2.1 Government documents. 2.1.1 Specifications apd
3、tandards. Th following specifi ations and. standards form a part of this specification to the extent specified herein, Unless otherwise specified, the issues of these documents shall be those listed in the issue of the Department of Defense Index of Specifications and Standards (DoDISS) and suppleme
4、nt thereto, cited in the solicitation. SPECIFICATIONS FEDERAL QQ-B-639 - Brass, Naval: Flat Products (Plate, Bar, Sheet QQ-S-766 - Steel Plates, Sheets, and Strip - Corrosion and Strip). Res ist ing . MILITARY MIL-C-15726 - Copper-Nickel Alloy, Rod, Flat Products (Flat Wire, MIL-S-22698 - Steel Plat
5、e and Shapes, Weldable Ordinary Strength Strip, Sheet, Bar, and Plate) and Forgings. and Higher Strength: Hull Structural. Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be addressed to: Commander, Naval Sea Sy
6、stems Command, SEA 5523, Gopartment of the Navy, Washington, DC 20362-5101 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. /- -% THIS DOCUMENT CONTAINS /l PAGES. AMSC N/A FSC 6850 DISTRIBUTION STATEMENT A Ap
7、proved for public release; distribution unlimited Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-c STANDARDS FEDERAL FED-STD-313 - Material Safety Data Sheets Preparation and the FED-STD-791 - Lubricants, Liquid Fuels, and Related Products; Submissi
8、on of. hletiods of Testing. MILITARY NIL-STD-105 - Sampling Procedures and Tables for Inspection by NIL-STD-290 - Packaging of Petroleum and Related Products. Attributes. 2.1.2 Other Government publications. The following other Government publications form a part of this specification to the extent
9、specified herein, Unless otherwise specified, the issues shall be those in effect on the date of the solicitation. DEPARTMENT OF LABOR (OSHA) Code of Federal Regulations (CFR) 29 CFR, Part 1910.1200 (Application for copies should be addressed to the Superintendent of Documents, U.S. Government Print
10、ing Office, Washington, DC 20402.) (Copies of specifications, standards, publications and other Government documents required by contractors in connection with specific acquisition functions should be obtained from the contracting activity or as directed by the contracting activity.) 2.2 Other Publi
11、cations. The-following documents form a part of this speci- fication to the extent specified herein. Unless otherwise specified, the issues of the documents which are DoD adopted shall be those listed in the issue of the DoDISS specified in the solicitation. Unless otherwise specified, the issues of
12、 documents not listed in the DoDISS shall be the issue of the nongovernment docu- ments which is current on the date of the solicitation. AMERICAN SOCIETY FOR TESTING AND FlATERIALS (ASTM) B 209 - Standard Specification for Aluminum and Aluminum-Alloy D 93 - Standard Test Methods for Flash Point by
13、Pensky-Martens D 396 - Standard Specification for Fuel Oils. (DoD adopted) D 445 - Standard Test Method for Kinematic Viscosity of Trans- Sheet and Plate. (Metric) (DoD adopted) Closed Tester. (DoD adopted) parent and Opaque Liquids (and the Calculation of Dynamic Viscosity). (DoD adopted) (Applicat
14、ion for copies should be addressed to the American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103.) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-. , MIL-C-22230B 68 W 9999906 OLL7900 L W NIL-C - 22 230B (SH) (Nongovern
15、ment standards and other publications are normally available from the organizations which prepare or which distribute the documents. ments also may be available in or through libraries or other informational services.) These docu- 2.3 Order of precedence. In the event of a conflict between the text
16、of this specification and the references cited herein (except for associated detail . specifications, specification sheets or PIS standards), the text of this specifi- cation shall take precedence. Nothing in this specification, however, shall supersede applicable laws and regulations unless a speci
17、fic exemption has been obtained. 3. REQUIREMENTS 3.1 Material. The ingredient materials used in the manufacture of the cleaning compound shall be of a high quality, in solution as a single phase liquid, free from insoluble suspended or precipitated solids, and shall showno evidence of separation, ge
18、lling, or solidifying during handling or storage. 3.1.1 Toxic formulations. The compound, or a water solution of the compound, shall be free from toxicity and health hazards as defined in appendix A of 29 CFR 1910.1200. The material shall have no adverse effect on the health of personnel when used f
19、or its intended purpose. Questions pertinent to this effect shall be referred by the contracting activity to the Naval Medical Command (NAVMEDCOM) who will act as an advisor to the contracting activity (see 4.6). 3.2 Composition. The liquid shall be an emulsifier or a mixture of emulsifiers and solv
20、ents. It shall be free from caustic soda, benzol, chlori- nated compounds, 2-butoxyelhanol, 2-methoxyethanol, 2-ethoxyethanol and their acetates. 3.3 Cleaning efficiency. The cleaning compound shall emulsify fuel oil in salt water and shall leave not more than 8 milligrams (mg) of oil, based on the
21、average of 10 determinations (see 4.5.1). 3.4 Resistance to de-emulsification. Oil emulsified by the compound shall resist de-emulsification when diluted with salt water and shall produce, not more than 8 mg of de-emulsified oil, based on the average of 10 determinations (see 4.5.2). 3.5 Corrosivity
22、. Aqueous solutions of the compound shall be less corro- sive to mild steel, aluminum, brass, and copper-nickel than 3-1/2 percent salt water alone (see 4.5.3). 3.6 Flash-point. The closed-cup flash point of the compound shall be not less than 150 degrees Fahrenheit (OF) (see 4.5.4). 3.6.1 Labeling.
23、 Unless otherwise specified (see 6.2), each container of bilge cleaner shall be labeled with the actual flash point of the compound. 3.7 Miscibility with sea water. a 3-1/2 percent salt solution (see 4.5.5). The compound shall be readily miscible in 3 Provided by IHSNot for ResaleNo reproduction or
24、networking permitted without license from IHS-,-,-b 3.8 Fluidity at 50F. The compound shall be a fluid at 50F, and shall have a viscosity at this temperature not in excess of 800 centipoises. 3.9 Material safety data sheet (MSDS). The contracting activity shall be provided a material safety data she
25、et (NSDS) at the time of contract award. The ilSDS shall be provided in- accordance with the requirements of FED-STD-313 and 29 CFR 1910.1200. When FED-STD-313 is at variance wth the CFR, 29 CFR 1910.1200 shall take precedence, modify and supplement FED-STD-313. included with each shipment of the ma
26、terial covered by this specification (see 6.3). The NSDS shall be 4, QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the contractor is responsible for the performance of all inspectcon requirements as specified herein. - E
27、xcept as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by the Government. The Government reserves the right to perform any of the inspectio
28、ns set forth in the specification where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. 4,l.l Responsibility for compliance. All items must meet all requirements of sections 3 and 5. a part of the contractors overall inspection system or qual
29、ity program. The absence of any inspection requirements in the specification shall not relieve the contractor of the responsibility of assuring that all products or supplies submitted to the Government for acceptance comply with all requirements of the contract. known defectve material, either indic
30、ated or actual, nor does it commit the Government to acceptance of defective material. The inspection set forth in this Specification shall become Sampling in quality conformance does not authorize submission of 4.2 Quality conformance inspection. 4.2.1 Sampling. 4.2.1.1 w. For purposes of sampling,
31、 a lot shall consist of all material formulated under the same conditions of production and offered for delivery at one time. 4.2.1.2 Sampling for examination of filled containers. A random sample of filled containers shall be selected from each lot in accordance wth inspec- tion level I of MIL-STD-
32、105 with an acceptable quality level (AQL) of 2.5 per- cent defective, to verify compliance with all stipulations of this specification regarding fill, closure, marking and other requirements not involving tests. 4.2.1.3 Sampling for quality conformance inspection. Two samples of each lot shall be t
33、aken at random from the remaining containers selected in 4.2.1.2. Each sample shall contain approximately 1 quart (32 ounces) and shall be placed immediately in tightly stoppered bottles. The sample bottles shall be marked with name of manufacturer, contract number, and date on vhich the sample was
34、taken. Each sample shall be kept separate and tested as specified in 4.4. 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-. -% MIL-C-22230B 68 777770b OLL7902 5 m MIL-C-22230B (SH) 4.3 Examination of filled containers. Each sample filled container
35、selected in accordance with 4.2.1.2 shall be examined for defects of the. container and closure, for evidence of leakage, and for unsatisfactory markings. Each sample filled container shall be weighed to determine the amount of the contents. Any c-ontainer in the sample having one or more defects, o
36、r under required fill, shall be rejected. If the number of defective containers in any sample exceeds the acceptance number for the appropriate sampling plan in accordance with MIL-STD-105, the lot represented by the sample shall be rejected. Rejected lots may be resubmitted for examination provided
37、 that the contractor has removed or repaired all nonconforming containers. 4.4 Quality conformance tests. Tests for acceptance of individual lots shall be made and shall consist of all the tests as specified in 4.5. 4.5 Test methods. 4.5.1 Cleaning efficiency test. Test panels of corrosion-resisting
38、 steel, in accordance with QQ-S-766 (class 304 stainless steel, number 2 finish), 22- gauge sheet or strip stock, shall be prepared, each 1 by 3 inches. shall be smoothed with no. 1 emery cloth then cleaned in hot alkaline solution until free from water-break. The panels shall be rinsed in water, th
39、en dipped in 95 percent ethyl alcohol, and wiped dry with paper toweling. Sharp edges 4.5.1.1 Standard soil. The soiling material shall be Navy special grade fuel oil in accordance with ASTM D 396, grade 5, light and shall have a viscosity of 200 to 225 Standard Saybolt Universal (sSu) at 122F. Two
40、hundred f 1 mg of this fuel oil shall be applied to one side of the panel, taking care to keepthe oil away from the edges, as shown on figure 1. The oil shall be applied to the panel with a small brush. SH 13202659 FIGURE 1. Soiled test pinel. 5 Provided by IHSNot for ResaleNo reproduction or networ
41、king permitted without license from IHS-,-,-MIL-C-Z2-Z3B b9p7997jOb Oj,J7703 7-m- MI L - C - 2 2 2 3 OB ( Sli ) 4.5.1.2 Preparation of cleaning solution and apparatus. A solution of 3-1/2 percent salt water shall be prepared by dissolving 108 grams of c.p. sodium chloride in 3000 milliliters (mL) of
42、 distilled water. Nine mL of the compound being tested shall be added and mixed to the salt water solution. mL of the mixed solution shall be transferred to each of the 10 test jars. test jars shall be placed in a water bath on a Fisher oscillating hot-plate heater-agitator or equal, assembly.) each
43、 solution reaches 160F. Three hundred The (Figures 2 and 3 show the test jar and water bath The test jars shall be heated and agitated until the temperature of 6 _. J Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-C-222308 68 W 7777706 0337704 7
44、 W a -. - Ff I L - C - 2 2 2 3 OB ( S H ) Thermometer - - Copper n. Tubing Pa ne 1 SH 13202660 FIGURE 2. Test jar and panel. 7 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Air Condenser - Copper Tubing - 1/4 in. x 8 in. Thermometer - _ kiater Bath
45、 - - Test Panel O xb: I I SII 13202661 FIGURE 3. Cleaning efficiency test assembly. 8 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-C-22230B 68 = 7777706 OLL7706 2 -% I 4.5.1.3 Procedure for test. When the solutions have reached 160F,-a soiled
46、panel shall be inserted in each test jar, with the soiled side up, as shown on . figures 2 and 3. The test jars shall be agitated for 60 minutes; the temperature of each solution shall be maintained at 160F. One test jar shall be removed and its liquid contents poured into a 2 liter (L) Erlenmeyer f
47、lask or-equal. The jar shall be rinsed with 200 mL of 3-1/2 percent salt solution (1100F) by inverting the jar 10 times, and rinse water shall be emptied into the 2 L flask. The rinsing operation shall be repeated. 3-1/2 percent sodium chloride solution until the liquid rises to within 50 mL of the
48、top of the flask. Each test jar and flask shall be treated similarly, leaving the test panel in each jar. The flasks and their contents shall be reserved for the “resistance to de-emulsification“ test. and in the jar shall be extracted with a solvent and measured photometrically as described below.
49、Ten tests shall be made simultaneously and the results averaged. The 2 L flask shall be filled with The residual oil on the test strip 4.5.1.4 Residual oil determination. The residual oil shall be extracted from the pint jar surfaces and the test strip using 25 mL of carbon tetra- chloride. amount of oil present shall be determined by measuring the oil content photo- metrically at a wave length of 700 n
