1、AMSC N/A FSC 9150DISTRIBUTION STATEMENT A. Approved for public release; distribution isunlimited.Beneficial comments (recommendations, additions, deletions) and anypertinent data which may be of use in improving this document should beaddressed to: Commander, Naval Sea Systems Command, ATTN: SEA 05Q
2、, 1333Isaac Hull Avenue, SE, Stop 5160, Washington Navy Yard DC 20376-5160, byusing the self-addressed Standardization Document Improvement Proposal (DDForm 1426) appearing at the end of this document or by letter.MIL-PRF-18458C5 July 2002SUPERSEDINGMIL-G-18458B(SHIPS)19 March 1981(See 6.8)PERFORMAN
3、CE SPECIFICATIONGREASE, WIRE ROPE - EXPOSED GEARThis specification is approved for use by all Departments and Agenciesof the Department of Defense.1. SCOPE1.1 Scope. This specification covers corrosion resistant externallyapplied grease for use on wire ropes and exposed gears of hoists, winches,cran
4、es, shovels, dredges, and other similar equipment.1.2 Classification. Two types of grease are specified: a Type I forgeneral application and an environmentally preferable Type II for applicationswhere potential discharge to the environment is greater.2. APPLICABLE DOCUMENTS2.1 General. The documents
5、 listed in this section are specified insections 3 and 4 of this specification. This section does not includedocuments cited in other sections of this specification or recommended foradditional information or as examples. While every effort has been made toensure the completeness of this list, docum
6、ent users are cautioned that theymust meet all specified requirements documents cited in sections 3 and 4 ofthis specification, whether or not they are listed.INCH-POUNDProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-18458C22.2 Government doc
7、uments.2.2.1 Specifications, standards, and handbooks. The followingspecifications, standards, and handbooks form a part of this document to theextent specified herein. Unless otherwise specified, the issues of thesedocuments are those listed in the issue of the Department of Defense Index ofSpecifi
8、cations and Standards (DoDISS) and supplement thereto, cited in thesolicitation (see 6.2).STANDARDSFEDERALFED-STD-313 Material Safety Data, Transportation Data andDisposal Data for Hazardous Materials Furnished toGovernment ActivitiesFED-STD-791 - Lubricants, Liquid Fuels, and Related Products;Metho
9、ds of Testing(Unless otherwise indicated, copies of the above specifications,standards, and handbooks are available from the Standardization Document OrderDesk, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094.)2.2.2 Other Government documents, drawings and publications. Thefollowing oth
10、er Government documents, drawings, and publications form a partof this document to the extent specified herein. Unless otherwise specified,the issues are those cited in the solicitation.CODE OF FEDERAL REGULATIONS29 CFR 1910 Subpart Z Toxic and Hazardous Substances40 CFR 82 - Protection of Stratosph
11、eric Ozone40 CFR 261 - Hazardous Waste Criteria40 CFR 355 Appendices A and B The List of Extremely HazardousSubstances and Their ThresholdPlanning Quantities40 CFR 372.65 - Specific Toxic Chemical Listings40 CFR 761 - Polychlorinated Biphenyls(Application for copies should be addressed to the Superi
12、ntendent ofDocuments, Government Printing Office, Washington, DC 20402.)NATIONAL TOXICOLOGY PROGRAM (NTP)Latest Annual Report on Carcinogens, Summary, National ToxicologyProgram(Applications for copies should be addressed to the U.S. Department ofHealth and Human Services, National Institute of Envi
13、ronmental HealthSciences, Public Information Office, P.O. Box 12233, MD B2-04, ResearchTriangle Park, NC 27709.)OPNAVINST 5100.23E, Chapter 29 Occupational Reproductive Hazards(Copy available from internet website: http:/ by IHSNot for ResaleNo reproduction or networking permitted without license fr
14、om IHS-,-,-MIL-PRF-18458C3U.S. ENVIRONMENTAL PROTECTION AGENCYEPA/600/4-90/027F Methods for Measuring the Acute Toxicity ofEffluents and Receiving Waters to Freshwaterand Marine Organisms(Application for copies should be addressed to the National TechnicalInformation Service, U.S. Department of Comm
15、erce, Springfield, VA 22161.)2.3 Non-Government publications. The following documents form a partof this document to the extent specified herein. Unless otherwise specified,the issues of the documents that are DoD adopted are those listed in the issueof the DoDISS cited in the solicitation. Unless o
16、therwise specified, theissues of documents not listed in the DoDISS are the issues of the documentscited in the solicitation (see 6.2).AMERICAN NATIONAL STANDARDS INSTITUTE (ANSI)ANSI Z1.4 Sampling Procedures and Tables for Inspection byAttributes (DoD adopted)(Application for copies should be addre
17、ssed to the American NationalStandards Institute, Inc., 11 West 42ndStreet, 13thFloor, New York, NY10036.)AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM)A 1008/A1008M Steel, Sheet, Cold-Rolled, Carbon, Structural,High-Strength Low-Alloy and High-Strength Low-Alloy withImproved Formability, Standar
18、d Specification D 217 Cone Penetration of Lubricating Grease, Standard TestMethods for (DoD adopted)D 770 - Isopropyl alcohol, Standard Specification forD 1748 Rust Protection by Metal Preservatives in the HumidityCabinet, Standard Test Method for (DoD adopted)D 2596 Measurement of Extreme-Pressure
19、Properties of LubricatingGrease (Four-Ball Method), Standard Test Method for (DoDadopted)D 4057 - Manual Sampling of Petroleum and Petroleum Products,Standard Practice for (DoD adopted)D 4177 - Automatic Sampling of Petroleum and Petroleum Products,Standard Practice for (DoD adopted)D 5864 Determini
20、ng Aerobic Aquatic Biodegradation of Lubricantsor Their Components, Standard Test Method forD 6081 Aquatic Toxicity Testing of Lubricants: SamplePreparation and Results Interpretation, Standard PracticeforD 6139 Determining the Aerobic Aquatic Biodegradation ofLubricants or Their Components Using th
21、e Gledhill ShakeFlaskG 152 - Operating Open Flame Carbon Arc Light Apparatus forExposure of Nonmetallic Materials, Standard Practice for(Application for copies should be addressed to the American Society forTesting and Materials, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959.)Provided by I
22、HSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-18458C4COORDINATING EUROPEAN COUNCILCEC L-33-A-93 Biodegradability of Two-Stroke Cycle OutboardEngine Oils in Water(Application for copies should be addressed to: CEC, Madou Plaza, PlaceMadou 1, B-1030 Bruss
23、els, Belgium.)ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENTOECD 301D OECD Guideline for Testing of Chemicals: ReadyBiodegradability: Closed Bottle Test(Application for copies should be addressed to OECD PublicationsService, 2 rue Andr-Pascal, 75775 Paris Cedex 16, France)INTERNATIONAL AGENC
24、Y FOR RESEARCH ON CANCER (IARC)International Agency for Research on Cancer (IARC) Monographs(Applications for copies should be addressed to the WHO PublicationsCenter, 49 Sheridan Avenue, Albany, NY 12210.)2.4 Order of precedence. In the event of a conflict between the textof this document and the r
25、eferences cited herein, the text of this documenttakes precedence. Nothing in this document, however, supersedes applicablelaws and regulations unless a specific exemption has been obtained.3. REQUIREMENTS3.1 Qualification. The grease furnished under this specification shallbe products that are auth
26、orized by the qualifying activity for listing on theapplicable qualified products list before contract award (see 4.2 and 6.3).3.2 Material. The grease shall be a smooth, homogeneous, nontoxicmixture formulated to provide a lubricant suitable for the intended use (see6.1). Both types shall be of suc
27、h material as to not require additionalcontainer labeling in accordance with CFR, Title 29, Part 1910, Subpart Z.3.2.1 Environmental, safety, and health requirements. Greasesconforming to the specification shall not contain nor have the followingmaterials purposely added to the product formulation.3
28、.2.1.1 Toxins and carcinogens. The materials used in the grease andfor testing (see 4.3), and defined as known or suspected carcinogens in thefollowing documents shall not exceed concentrations of 0.1% (by weight):Occupational Safety and Health Administration (OSHA) in 29 CFR 1910 Subpart Z(regulate
29、d carcinogens); International Agency for Research on Cancer (IARC)Groups 1, 2A, and 2B; and the latest annual report of the National ToxicologyProgram (NTP). The materials shall have no extremely hazardous substances(EHS) or toxic chemicals identified in 40 CFR 355, and 372, respectively. Thegrease
30、shall have no adverse effect on the health of personnel when used forits intended purpose.3.2.1.2 Reproductive hazards. The product shall not contain anyreproductive hazards listed in OPNAVINST 5100.23E, Chapter 29 Appendix29-B in concentrations equal to or greater than 0.1% (by weight). The mostcur
31、rent version of the instruction can be obtained from the internet website:http:/.Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-18458C53.2.1.3 Prohibited materials. The product shall not contain any 2,6-di-t-butylphenol, chlorinated compound
32、s, or hydrolyzable chlorine derivatives.All derivatives or salts of barium, strontium, lead, and chromium, includingchromates or dichromates, are also prohibited.3.2.1.4 Other chemicals targeted by EPA. The grease shall not containpolychlorinated biphenyls (PCBs) in concentrations equal to or exceed
33、ing 50parts per million (40 CFR 761); and other materials in concentrations thatexceed 1.0% by weight including cyanide, and cyanide compounds, methyl ethylketone, methyl isobutyl ketone, and xylene (all isomers).3.2.1.5 Hazardous waste. The greases shall not meet the definition ofa hazardous waste
34、as defined by the Resource Conservation and Recovery Act (40CFR 261).3.2.2 Recycled, recovered, or environmentally preferable materials.Recycled, recovered, or environmentally preferable materials should be used tothe maximum extent possible, provided that the material meets or exceeds theoperationa
35、l and maintenance requirements and promotes economicallyadvantageous life cycle costs.3.3 Chemical and physical properties. Type I grease shall have thechemical and physical properties shown in Table I. Type II grease shall meetall the requirements of Type I grease and also the environmental require
36、mentsof Table II.3.4 Toxicity. The grease shall have no adverse effect on the health ofpersonnel when used for its intended purpose. (See 6.1 and 6.5).TABLE I. Chemical and physical requirements and test methods for Type I andType II.Characteristics RequirementFED-STD-791method no.Non-governmentmeth
37、od no.See section4-paragraphnumberWorked penetration 200-350 range ASTM D 217Oil separation (%)10 maximum321 1/Load wear index 30 minimum ASTM D 2596Salt spray Pass 4001 4.4.2Accelerated weathering PassASTM G 152,1534.4.3Low temperatureflexibilityPass 4.4.4Volatile matter (%) 2.0 maximum 4.4.5Adhesi
38、veness (%) 95 minimum 4.4.61/ Test shall be conducted at 65.5C (150F) for 50 hours duration.Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-18458C6TABLE II. Additional requirements and test methods for Type II.Characteristics RequirementFED-S
39、TD-791method no.Non-governmentmethod no.See section4-paragraphnumberAquaticbiodegradability (%)80 minimum CEC L-33-A-931/4.4.72/Acute toxicity, mysidshrimp, LL50 (ppm)1000 minimum EPA-600/4-90-0274.4.81/ Coordinating European Council test, “Biodegradability of Two Stroke CycleOutboard Engine Oils in
40、 Water”2/ Acceptable alternatives to the test method and limit are 60% in 28 days byASTM D 5864, ASTM D 6139, or OECD 301D test methods.4. VERIFICATION4.1 Classification of inspections. The inspection requirementsspecified herein are classified as follows:(a) Qualification inspection (see 4.2)(b) Co
41、nformance inspection (see 4.3)4.2 Qualification inspection. Type I grease qualification inspectionshall consist of all of the tests specified in table I, and section 4.4(except 4.4.7 and 4.4.8). Type II grease qualification inspection testsinclude all Type I grease tests plus those of Table II and p
42、aragraphs 4.4.7and 4.4.8. A minimum sample size of 15.9 kg (35 lb) is required forqualification testing. (See 6.3)4.3 Conformance inspection. Each sample selected as specified in 4.3.1shall be tested as specified in Table I, except the salt spray and acceleratedweathering need not be run. Failure of
43、 the samples in any of these tests shall because for rejection of the lot. Inspection shall be in accordance with method9601 of FED-STD-791.4.3.1 Sampling for conformance inspection. Samples for conformanceinspections shall be taken in accordance with ASTM D 4057 and ASTM D 4177.4.3.2 Sampling for e
44、xamination of filled containers. A random sampleof filled containers shall be drawn from each lot in accordance with ANSI Z1.4to verify compliance with this specification regarding fill, closure, marking,and other requirements not involving tests.4.3.3 Examination of filled containers. Samples shall
45、 be examined fordefects of the container and the closure, for evidence of leakage, and forunsatisfactory markings; each sample-filled container shall also be weighed todetermine the amount of the contents.4.4 Test methods. Testing shall be in accordance with applicable testmethods given in tables I
46、and II and in 4.4.1 through 4.4.8.4.4.1 Preparation of specimens for protection tests. Three specimenpanels shall be prepared for each protection test.4.4.1.1 Panel composition and size. Steel panels shall be fabricatedfrom open hearth, cold finished, dead soft temper, low carbon steel conformingto
47、ASTM A 1008/1008M. The panels shall be 5.08 by 10.16 by 0.32 cm (2 by 4 by1/8 inch) conforming to those panels specified in ASTM D 1748.Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-18458C74.4.1.2 Panel finishing and cleaning. The panel tes
48、t surfaces shall befinished and cleaned as follows:(a) After rounding the edges of the panel and reaming out the holesused for suspension, wipe the surfaces as clean as possibleusing solvent-soaked rags.(b) Scrub the panel with clean cotton or surgical gauze swab in abeaker of hot non-aromatic petro
49、leum solvent such as heptane.(c) Rinse in warm (21-27C) 70-80F isopropyl alcohol, for atleast 10 seconds and air-dry the panel. If required, use avacuum desiccator and set it aside for later usage.(d) Buff the panel test surface with 240 grit aluminum oxideabrasive with plain or paper backing so as to produce a surfacefinish of 0.254-0.508 micrometers (10-20 micro inches) rootmean square. The fin
