NAVY MIL-PRF-32177 A-2012 CLEANING COMPOUND NONSKID.pdf

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1、Comments, suggestions, or questions on this document should be addressed to: Commander, Naval Sea Systems Command, ATTN: SEA 05S, 1333 Isaac Hull Avenue, SE, Stop 5160, Washington Navy Yard DC 20376-5160 or emailed to CommandStandardsnavy.mil, with the subject line “Document Comment”. Since contact

2、information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.dla.mil. AMSC N/A FSC 7930 METRIC MIL-PRF-32177A 21 August 2012 SUPERSEDING MIL-PRF-32177 27 September 2004 PERFORMANCE SPECIFICATION CLEANING COMPOUND, NONSKID T

3、his specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification establishes the requirements for a compound for cleaning nonskid surfaces on aircraft carriers and other air-capable ships. 1.2 Classification. The cleaning comp

4、ound will conform to the following types, as specified (see 6.2). a. Type I - For use with fresh (potable) water. b. Type II - For use with seawater. 1.3 Part or identifying number (PIN). PINs to be used for cleaning compounds acquired to this specification are created as follows: M 32177 - X Prefix

5、 for Military Specification Specification number 1 for Type I or 2 for Type II (see 1.2) 2. APPLICABLE DOCUMENTS 2.1 General. The documents listed in this section are specified in sections 3, 4, or 5 of this specification. This section does not include documents cited in other sections of this speci

6、fication or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified requirements of documents cited in sections 3, 4, or 5 of this specification, whether or not the

7、y are listed. 2.2 Government documents. 2.2.1 Specifications, standards, and handbooks. The following specifications, standards, and handbooks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or

8、 contract. COMMERCIAL ITEM DESCRIPTIONS A-A-2294 - Eductor (By-Pass Low Temperature, Synthetic Hydrocarbon Base, Aircraft and Missile (Copies of these documents are available online at https:/assist.dla.mil/quicksearch/ or https:/assist.dla.mil.) 2.2.2 Other Government documents, drawings, and publi

9、cations. The following other Government documents, drawings, and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. CODE OF FEDERAL REGULATIONS (CFR) 29 CFR 1910.1003 - 1

10、3 Carcinogens (4-Nitrobiphenyl, etc.) 40 CFR 59, Subpart C - National Volatile Organic Compound Emission Standards for Consumer Products 40 CFR 82 - Protection of Stratospheric Ozone 40 CFR 131.36 - Toxics criteria for those states not complying with Clean Water Act section 303(c)(2)(B) 40 CFR 141 -

11、 National Primary Drinking Water Regulations 40 CFR 261 - Identification and Listing of Hazardous Waste 40 CFR 355, Appendices A and B - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (Alphabetical Order and CAS Number Order) 40 CFR 372.65 - Chemicals and chemical

12、 categories to which this part applies 40 CFR 797, Subpart B - Aquatic Guidelines (Copies of these documents are available from the Superintendent of Documents, U.S. Government Printing Office, Washington DC 20401 or online at www.gpoaccess.gov/index.html.) Provided by IHSNot for ResaleNo reproducti

13、on or networking permitted without license from IHS-,-,-MIL-PRF-32177A 3 U.S. ENVIRONMENTAL PROTECTION AGENCY (EPA) EPA OPPTS 835.3110 - Ready Biodegradability EPA OPPTS 835.3120 - Sealed-Vessel Carbon Dioxide Production Test EPA SW-846, Method 5021 - Volatile Organic Compounds in Soils and Other So

14、lid Matrices Using Equilibrium Headspace Analysis EPA SW-846, Method 8260 - Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) (Copies of these documents are available from the Environmental Protection Agency, Ariel Rios Building, 1200 Pennsylvania Avenue, N.W., Washington DC

15、 20460 or online at www.epa.gov.) NATIONAL INSTITUTE OF ENVIRONMENTAL HEALTH SCIENCES (NIEHS) National Toxicology Program (NTP) latest annual Report on Carcinogens (Copies of this document are available from the National Toxicology Program, P.O. Box 12233, Mail Drop K2-02, Research Triangle Park, NC

16、 27709 or online at www.niehs.nih.gov.) NAVAL SEA SYSTEMS COMMAND (NAVSEA) PUBLICATIONS T9074-BD-GIB-010/0300 - Base Materials for Critical Applications: Requirements for Low Alloy Steel Plate, Forgings, Castings, Shapes, Bars, and Heads of HY-80/100/130 and HSLA-80/100 (Copies of this document are

17、available online at https:/nll1.ahf.nmci.navy.mil. This publication can be located by searching the Navy Publications Index for the TMIN without the suffix.) 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specifi

18、ed, the issues of these documents are those cited in the solicitation or contract. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) Documentation of the Threshold Limit Values for Physical Agents (Copies of this document are available from the American Conference of Governmental Hyg

19、ienists, 1330 Kemper Meadow Drive, Cincinnati, OH 45240 or online at www.acgih.org.) ASTM INTERNATIONAL ASTM B6 - Standard Specification for Zinc ASTM B96/B96M - Standard Specification for Copper-Silicon Alloy Plate, Sheet, Strip, and Rolled Bar for General Purposes and Pressure Vessels ASTM B148 -

20、Standard Specification for Aluminum-Bronze Sand Castings ASTM B209 - Standard Specification for Aluminum and Aluminum-Alloy Sheet and Plate ASTM D93 - Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester ASTM D329 - Standard Specification for Acetone ASTM D1141 - Standard Practi

21、ce for the Preparation of Substitute Ocean Water ASTM D1193 - Standard Specification for Reagent Water Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32177A 4 ASTM D2834 - Standard Test Method for Nonvolatile Matter (Total Solids) in Water-E

22、mulsion Floor Polishes, Solvent-Based Floor Polishes, and Polymer-Emulsion Floor Polishes ASTM D3363 - Standard Test Method for Film Hardness by Pencil Test ASTM D6361/D6361M - Standard Guide for Selecting Cleaning Agents and Processes ASTM D6450 - Standard Test Method for Flash Point by Continuousl

23、y Closed Cup (CCCFP) Tester ASTM E70 - Standard Test Method for pH of Aqueous Solutions With the Glass Electrode ASTM E168 - Standard Practices for General Techniques of Infrared Quantitative Analysis ASTM F483 - Standard Practice for Total Immersion Corrosion Test for Aircraft Maintenance Chemicals

24、 ASTM F502 - Standard Test Method for Effects of Cleaning and Chemical Maintenance Materials on Painted Aircraft Surfaces ASTM F519 - Standard Test Method for Mechanical Hydrogen Embrittlement Evaluation of Plating/Coating Processes and Service Environments ASTM F718 - Standard Specification for Shi

25、pbuilders and Marine Paints and Coatings Product/Procedure Data Sheet (Copies of these documents are available from ASTM International, 100 Barr Harbor Dr., P.O. Box C700, West Conshohocken, PA 19428-2959 or online at www.astm.org.) INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) International Ag

26、ency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks to Humans (Copies of this document are available from WHO Press, World Health Organization, CH-1211 Geneva 27, Switzerland or online at www.who.int/bookorders.) SAE INTERNATIONAL SAE-AMS-QQ-A-250/9 - Aluminum Alloy

27、 5456, Plate and Sheet SAE-AMS-5046 - Carbon Steel, Sheet, Strip, and Plate, (SAE 1020 and 1025), Annealed (Copies of these documents are available from SAE World Headquarters, 400 Commonwealth Drive, Warrendale, PA 15096-0001 or online at www.sae.org.) 2.4 Order of precedence. Unless otherwise note

28、d herein or in the contract, in the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUI

29、REMENTS 3.1 Qualification. The cleaning compounds furnished under this specification shall be products that are authorized by the qualifying activity for listing on the applicable qualified products list before contract award (see 4.2 and 6.3). 3.2 Material. Cleaning compounds supplied under this sp

30、ecification shall comply with all Navy occupational health and safety regulations, and meet the following characteristics: Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32177A 5 3.2.1 Volatile organic content (VOC). The VOC of the undiluted

31、 cleaning compound shall not exceed 10 weight percent (see 4.4.1). 3.2.2 Hazardous air pollutants (HAPs). The content of HAPs solvents in the cleaning compound diluted in accordance with 3.2.5.1 or 3.2.5.2 shall be not greater than the weight percent (%WT) values listed in table I (see 4.4.2). TABLE

32、 I. Hazardous solvent content. Hazardous solvent in total cleaning compound Maximum, %WT Benzene 0.05 Chlorine or Fluorine containing solvents, total 0.05 Class I or Class II ozone depleting chemicals as defined in 40 CFR 82 0.01 Ethyl Benzene 0.05 Methyl, Ethyl, and Butyl Mono-Ethers of Ethylene Gl

33、ycol or the Acetates thereof, total (Methyl, Ethyl, and Butyl Cellosolves and Methyl, Ethyl, and Butyl Cellosolve Acetates) 0.05 Methyl Ethyl Ketone (MEK) 0.05 Methyl Isobutyl Ketone (MIBK) 0.05 Toluene 0.05 Xylene (all forms), total 0.01 3.2.3 Toxicity. When evaluated in accordance with 4.4.3 (the

34、HHA), the cleaning compound shall have no adverse effect on the health of personnel when used for its intended purpose (see 4.4.3 and 6.5). 3.2.3.1 Prohibited materials. Unless specific maximum levels are cited herein (see 3.2), the addition of any of the following prohibited materials shall be not

35、allowed: carcinogens defined by 29 CFR 1910.1003; Group 1, 2A, and 2B compounds from the latest IARC Monographs on the Evaluation of Carcinogenic Risks to Humans; compounds listed in the National Toxicology Program (NTP) latest annual Report on Carcinogens; Group A1, A2, and A3 compounds from the Am

36、erican Conference Of Governmental Industrial Hygienists (ACGIH document), Documentation of the Threshold Limit Values for Physical Agents; and extremely hazardous substances (EHS) and toxic chemicals identified in 40 CFR 355, Appendices A and B, and 40 CFR 372.65, respectively. When any of these pro

37、hibited materials are present, as a result of a trace or impurity in another ingredient(s), the concentration shall not equal or exceed 0.1 percent by weight of the cleaning compound. 3.2.3.2 Certification of material hazards. The cleaning compound shall not contain any hazardous material or exhibit

38、 any hazardous characteristic as defined by 40 CFR 261. Formulation changes shall require a reevaluation of the material. 3.2.4 Non-volatile content. When the cleaning compound is diluted in accordance with 3.2.5.1 or 3.2.5.2, as required by classification type (see 1.2), the non-volatile content sh

39、all be less than 20 percent by weight (see 4.4.4). 3.2.5 Cleaning compound dilution. When diluted cleaning compound is specified herein, the cleaning compound shall be diluted in accordance with the following: 3.2.5.1 Type I dilution. Type I cleaning compounds shall be diluted with 18 parts potable

40、water to 1 part cleaning compound (see 4.4.15). 3.2.5.2 Type II dilution. Type II cleaning compounds shall be diluted with 18 parts seawater to 1 part cleaning compound (see 4.4.16). 3.2.6 Undiluted cleaning compound. When undiluted cleaning compound is specified herein, the cleaning compound shall

41、be in as-received condition. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32177A 6 3.3 Flash point. The flash point of the undiluted cleaning compound shall be greater than or equal to 60 C (140 F) (see 4.4.5). 3.4 pH. The pH of the cleani

42、ng compound diluted in accordance with 3.2.5.1 or 3.2.5.2, as required by classification type (see 1.2), shall be greater than or equal to 6.5 and less than or equal to 12.4 (see 4.4.6). 3.5 Cleaning efficiency. The average Coefficient of Friction (CoF), FC, reading after cleaning with the cleaning

43、compound when diluted in accordance with 3.2.5.1 or 3.2.5.2, as required by classification type (see 1.2) , shall be greater than or equal to FR, the minimum restored CoF (see 4.4.7). 3.6 Total immersion corrosion. When tested, the cleaning compound, undiluted and diluted in accordance with 3.2.5.1

44、or 3.2.5.2, as required by classification type (see 1.2), shall not cause a weight change greater than that caused by immersion in ASTM D1141 seawater alone (see 4.4.8 ). 3.7 Effect on organic coatings. When tested, the cleaning compound, undiluted and diluted in accordance with 3.2.5.1 or 3.2.5.2,

45、as required by classification type (see 1.2), shall not (see 4.4.9): a. Soften epoxy polyamide paint conforming to MIL-DTL-24441/21 by more than 2 pencil hardness values. b. Soften nonskid coatings conforming to MIL-PRF-24667 Type I to allow insertion of a dull putty knife. c. Soften aircraft polyur

46、ethane topcoats conforming to MIL-PRF-85285 Type I, Class H by more than 1 pencil hardness value. d. Soften silicone-alkyd topside coatings conforming to MIL-PRF-24635 Type II or III and polysiloxane topside coatings conforming to MIL-PRF-24635 Type V by more than 2 pencil hardness values. e. Cause

47、loss of adhesion. f. Cause discoloration or other sign of deterioration. g. Soften color toppings conforming to MIL-PRF-24667 by more than 2 pencil hardness values. 3.8 Effect on polyimide insulated wire. When tested, the undiluted cleaning compound shall not cause dissolution, cracking, or dielectr

48、ic breakdown (leakage) of the polyimide insulated wire in excess of that produced by distilled water (see 4.4.10). 3.9 Biodegradability. The biodegradability of the cleaning compound, diluted in accordance with 3.2.5.1 or 3.2.5.2, as required by classification type (see 1.2), shall be a minimum of 5

49、0 percent in 23 days (see 4.4.11). 3.10 Aquatic toxicity. The product shall be not toxic to aquatic life as determined by 40 CFR 797, Subpart B for the following three criteria: acute (Daphnia or fish), acute (algae), and chronic (Daphnia) effects (see 4.4.12). 3.11 Service evaluation. When tested, the cleaning compound diluted in accordance with 3.2.5.1 or 3.2.5.2, as required by classification type (see 1.2), shall satisfy the following (see 4.4.13): a. Not discolor the

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