1、raising standards worldwide NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW BSI Standards Publication PD CEN/TR 15990:2010 Data Sheets Footwear Tests Materials and Test Adhesives Incorporating corrigendum November 2010National foreword This Published Document is the UK impleme
2、ntation of CEN/TR 15990:2010, incorporating corrigendum November 2010. The start and finish of text introduced or altered by CEN corrigendum November 2010 is indicated in the text by tags . The UK participation in its preparation was entrusted to Technical Committee PRI/52, Adhesives. A list of orga
3、nizations represented on this committee can be obtained on request to its secretary. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. BSI 2011 ISBN 978 0 580 73895 1 ICS 61.060; 83.180 This Published Document
4、was published under the authority of the Standards Policy and Strategy Committee on 31 July 2010. Amendments issued since publication Date Text affected 31 March 2011 I mplementation of CEN corrigendum November 2010 PD CEN/TR 15990:2010 PUBLISHED DOCUMENTTECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHE
5、R BERICHT CEN/TR 15990 July 2010 ICS 61.060; 83.180 English Version Data Sheets - Footwear Tests Materials and Test Adhesives Fiches techniques - Matriaux et colles pour essais des articles chaussants Datenbltter - Schuh-Testwerkstoffe und Schuh- Testklebstoffe This Technical Report was approved by
6、CEN on 28 December 2009. It has been drawn up by the Technical Committee CEN/TC 193. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
7、Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All
8、 rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 15990:2010: E Incorporating corrigendum November 2010PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 6 2 Normative references 6 3 Test mater
9、ials .7 3.1 Test material L17 3.2 Test material L27 3.3 Test material SBR 8 3.4 Test material NBR 9 3.5 Test material SBS . 10 3.6 Test material PVC . 11 3.7 Test material EVA . 11 4 Test adhesives 12 4.1 Test adhesive CR1 12 4.2 Test adhesive CR2 13 4.3 Test adhesive PU1 14 4.4 Test adhesive PU2 14
10、 4.5 Test adhesive PUD1 . 15 4.6 Test adhesive PUD2 . 15 PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 3 Foreword This document (CEN/TR 15990:2010) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. Attention is drawn to the possibility that some
11、 of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 4 Introduction For testing adhesive bonds some important European Standards have been deve
12、loped by CEN/TC 193/Working Group 5 “Adhesives for Leather and Footwear“ in close cooperation with European Shoe Institutes and the “Association of European Adhesive and Sealant Manufacturers (FEICA)“: EN 1392:2006, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives
13、Testing of bond strength under specified conditions EN 15062:2006, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing ageing of bonds under specified conditions EN 15307:2007, Adhesives for leather and footwear materials Sole-upper bonds Minimum strength requ
14、irement These European Standards intend to serve: the manufactures of shoe materials for testing the bondability of their products; the adhesive manufactures to determine the bond properties of their adhesives; the shoe industry to test the suitability of the materials and/or adhesives before applyi
15、ng in their production line and for quality control. In the footwear industry a large number of different solvent or dispersion adhesives are applied for sole-upper bonding offering a broad range of technical effects. The most important and most often adhesives used are based on polyurethane and pol
16、ychloroprene. For research, development and quality certification purposes some simply formulated 1- and 2-part “reference test adhesives“ have been developed which can be considered as typical adhesives of these types. In footwear manufacture also a great number of the different sole and upper mate
17、rials are used. From the most important and most often applied some materials have been selected as “reference test materials“. The annexed data sheets offer for each of these reference test adhesives and reference test materials some information and specify some properties. CEN/TC193 Working Group
18、5 takes care for a continuous updating of these data sheets. For further information on a reference test adhesive or a reference test material (e.g. on availability and supply) please contact the European Shoe Institute mentioned in its data sheet: INSTITUTO TECNOLGICO DEL CALZADO Y CONEXAS (INESCOP
19、) Polig. Ind. Campo Alto - Aptdo. 253 03600 Elda- Alicante Espaa Phone: +34 965 39 52 13; Fax: +34 965 38 10 45 E-Mail: inescopinescop.es or respectively PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 5 PRF- UND FORSCHUNGSINSTITUT e.V. (PFI) Marie-Curie-Strae 19 D-66953 Pirmasens Phone: +49 6331 24900;
20、Fax: +49 6331 249060 E-Mail: infopfi-pirmasens.de or respectively Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 45493 SAFETY STATEMENT Persons using this document should be familiar with the normal laboratory practice, if applicable.
21、 This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory conditions. ENVIRONMENTAL STATEMENT It is understood that som
22、e of the material permitted in this standard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials, they will be eliminated from this standard to the extent possible. At the end of the test, the user of the standard shall take care to
23、 carry out an appropriate disposal of the wastes, according to local regulation. PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 6 1 Scope For research, development and quality certification purposes, some simply formulated 1- and 2-part “reference test adhesives“ have been developed and, from the most i
24、mportant and most often applied, some materials have been selected as “reference test materials“. This technical report offers for each of these reference test adhesives and reference test materials some information and specify some properties. CEN/TC 193/WG 5 takes care for a continuous updating of
25、 these data sheets. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 139
26、2, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing of bond strength under specified conditions EN 12092, Adhesives Determination of viscosity EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (I
27、SO 868:2003) EN ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 2420, Leather Physical and mechanical tests Determination of apparent density (ISO 2420:2002) EN ISO 3376
28、, Leather Physical and mechanical tests Determination of tensile strength and percentage extension (ISO 3376:2002) EN ISO 4045, Leather Chemical tests Determination of pH (ISO 4045:2008) EN ISO 4047, Leather Determination of sulphated total ash and sulphated water-insoluble ash (ISO 4047:1977) EN IS
29、O 4048, Leather Chemical tests Determination of matter soluble in dichloromethane and free fatty acid content (ISO 4048:2008) EN ISO 5398-3, Leather Chemical determination of chromic oxide content Part 3: Quantification by atomic absorption spectrometry (ISO 5398-3:2007) ISO 34 (all parts), Rubber,
30、vulcanized or thermoplastic Determination of tear strength ISO 37, Rubber, vulcanized or thermoplastic Determination of tensile stress-strain properties ISO 247, Rubber Determination of ash ISO 1407, Rubber Determination of solvent extract ISO 2781, Rubber, vulcanized or thermoplastic Determination
31、of density ISO 4649, Rubber, vulcanized or thermoplastic Determination of abrasion resistance using a rotating cylindrical drum device ISO 7619, Rubber, vulcanized or thermoplastic Determination of indentation hardness PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 7 3 Test materials 3.1 Test material L
32、1 Description Chrome tanned cowhide upper leather, full grain Information Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 162311 Designation Test upper leather L 1 Thickness: 1,5 mm to 1,8 mm Colour: green brown Formulation Raw materia
33、l: Cowhides of South Germany, weight class 25 kg to 29,5 kg Manufacturing method: specified by Lederinstitut Gerberschule Reutlingen Table 1 Technical Data of Test Material L1 Technical Data Unit Nominal Tolerance Standard Apparent density g/m 30,7 0,1 EN ISO 2420 Tensile strength N/mm 2 21 - EN ISO
34、 3376 Elongation at break % Max. 80 - EN ISO 3376 Ashes at 800 C % 6,0 1,0 EN ISO 4047 Chrome oxide % - EN ISO 5398-3 pH-value - 3,5 - EN ISO 4045 Dichloro methane extract % 8,0 2,0 EN ISO 4048 Bonding properties: Test Adhesives PU 1, PU 2, CR 1, CR 2, PUD 1 and PUD 2 (according to EN 1392) 3.2 Test
35、 material L2 Description Vegetably tanned soling leather, butt Information Lederinstitut Gerberschule Reutlingen Erwin-Seiz-Str. 9, D-72764 Reutlingen Phone: +49 7121 16230; Fax: +49 7121 162311 Designation Test upper leather L 2 PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 8 Thickness: 3,8 mm to 4,5
36、mm Colour: brown Formulation Raw material: Manufacturing method: specified by Lederinstitut Gerberschule Reutlingen Table 2 Technical Data of Test Material L2 Technical Data Unit Nominal Tolerance Standard Apparent density g/m 3Max. 1,15 - EN ISO 2420 Tensile strength N/mm 2 19 - EN ISO 3376 Elongat
37、ion at break % Max. 30 - EN ISO 3376 Ashes at 800 C % Max. 1,3 - EN ISO 4047 pH-value - 3,5 - EN ISO 4045 Dichloro methane extract % Max. 2,0 - EN ISO 4048 Bonding properties: Test Adhesives PU 1, PU 2, CR 1, CR 2, PUD 1 and PUD 2 (according to EN 1392) 3.3 Test material SBR Description Synthetic ru
38、bber vulcanizate, transparent Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation Durotrans 1Formulation SBR: silica zinc oxide colour pigments 1Durotrans is the tradename of a product supplied by ContiTech Formteile/Schuhbedarf, D-Han
39、nover. This information is given for the convenience of users of this CEN Report and does not constitute an endorsement by CEN. Equivalent products may be used if they can be shown to lead to the same results. PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 9 Table 3 Technical Data of Test Material SBR T
40、echnical Data Unit Nominal Tolerance Standard Raw density g/m 31,17 0,02 ISO 2781 Tensile strength N/mm 2 13 - ISO 37 Elongation at break % 500 - ISO 37 Hardness ShoreA 70 3 EN ISO 868 Abrasion mm 3 210 30 ISO 4649 Ashes at 950 C % 31,0 2,0 ISO 247 Acetone extract % 6,0 0,5 ISO 1407 Bonding properti
41、es: Test Adhesives PU 2 and CR 2 (according to EN 1392 with halogenation) 3.4 Test material NBR Description Oil-resistant, vulcanised nitrile-butadiene soling material Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation CMKX Thickness:
42、 4,0 mm Surface: ripped pattern Colour: dark brown Formulation NBR, 33 % ACN silica plasticizer, reinforcing resin, zinc oxide colour pigments PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 10 Table 4 Technical Data of Test Material NBR Technical Data Unit Nominal Tolerance Standard Raw density g/m 31,2
43、5 0,02 ISO 2781 Tensile strength N/mm 222,0 3,0 ISO 37 Elongation at break % 400 80 ISO 37 Hardness ShoreA 80 3 EN ISO 868 Abrasion mm 3150 30 ISO 4649 Ashes at 950 C % 32,0 2,2 ISO 247 Acetone extract % 14,0 1,0 ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (according to EN 1392) 3.5 Te
44、st material SBS Description Thermoplastic styrene-butadiene-styrene soling material Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens Designation SBS R 6 Neu - granules SBS R 6 Neu - test sheet Formulation styrene-butadiene-styrene block copolym
45、er polystyrene, silica, plasticizer, Table 5 Technical Data of Test Material SBS Technical Data Unit Nominal Tolerance Standard Raw density g/m 30,95 0,03 ISO 2781 Tensile strength N/mm 24,0 0,5 ISO 37 Elongation at break % 500 50 ISO 37 Hardness ShoreA 60 2 EN ISO 868 Abrasion mm 3150 10 ISO 4649 A
46、shes at 950 C % 7,6 0,3 ISO 247 Acetone extract % 9,5 0,3 ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (according to EN 1392 with halogenation) PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 11 3.6 Test material PVC Description Plasticized polyvinyl chloride soling material Information INST
47、ITUTO TECNOLGICO DEL CALZADO Y CONEXAS (INESCOP) Polig. Ind. Campo Alto - Aptdo. 253 03600 Elda- Alicante Espaa Designation Black PVC Thickness: 5,0 mm Surface: smooth Colour: black Formulation PVC plastiziser dop (36 %), stabilizer, carbon black Table 6 Technical Data of Test Material PVC Technical
48、 Data Unit Nominal Tolerance Standard Raw density g/m 31,23 0,03 ISO 2781 Tensile strength N/mm 212,9 1,0 ISO 37 Elongation at break % 300 20 ISO 37 Tear strength N/mm 24,1 1,0 ISO 34 Hardness ShoreA 78 3 EN ISO 868 Abrasion mm 3123 10 ISO 4649 Ashes at 950 C % 2,6 0,1 ISO 247 Acetone extract % 53 1
49、,0 ISO 1407 Bonding properties: Test Adhesives PU 1 and PU 2 (according to EN 1392) 3.7 Test material EVA Description Vulcanizate of ethylene-vinylacetate-copolymer and polyisoprene Information Prf- und Forschungsinstitut fr die Schuhherstellung, Marie-Curie-Str. 19, D- 66953 Pirmasens PD CEN/TR 15990:2010 CEN/TR 15990:2010 (E) 12 Designation Lunalight 2Formulation ethylene-vinylacetate-
