1、ASD Technical Report Rapport Technique ASD ASD Fachbericht TR 9536 Edition 1 March 2008 PUBLISHED BY THE AEROSPACE AND DEFENCE INDUSTRIES ASSOCIATION OF EUROPE - STANDARDIZATIONAvenue de Tervuren, 270 - B-1150 Brussels - Tel. + 32 2 775 8126 - Fax. + 32 2 775 8131 - www.asd-stan.orgICS: Descriptors:
2、 ENGLISH VERSION Aerospace series Declarable Substances Recommended Practice Srie arospatiale Procdures pour la dclaration des substances Luft- und Raumfahrt Deklarationspflichtige Substanzen Empfohlene Vorgehensweise Edition approved for publication 31 March 2008 Quality Domain Copyright 2008 by AS
3、D-STAN Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 2 TR 9536:08-03 Contents Page 0 Scope 5 1 Purpose.5 2 Applicable documents 5 2.1 ASD-STAN Publications5 2.2 SAE Publications .5 3 Disclaimer.5 4
4、Declarable substances list6 4.1 Glossary of Chemical Family Identifier Abbreviations used in Declarable Substances List .6 4.2 Glossary of Chemical Family Identifier Abbreviations used in Declarable Substances List .7 4.3 Declarable Substances List8 5 Notes.52 Copyright ASD-STAN Provided by IHS unde
5、r license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 3 TR 9536:08-03 Foreword This Declarable Substances List is intended to be used in conjunction with TR 9535 to address, in a consistent way, the collection of information on chemicals through
6、out the supply chain. This information is key for compliance with numerous regulatory requirements as well as to meet customer and other stakeholders expectations and obligations. The aerospace and defence sectors manufacture long life cycle products. They consider it essential to know whether any o
7、f the substances inscripted in the Declarable Substances List are incorporated within the products they manufacture or in the manufacturing processes in order: to anticipate, at the earliest design stage, any potential regulatory or business risks that might occur, associated to these substances, to
8、 ease compliance with appropriate applicable regulatory frameworks, to facilitate end of life management, to implement an efficient tracking process and anticipate any possible supply chain or business disruption. This is not necessarily a list of substances that should be removed from the aerospace
9、 and defence industries. Despite the fact that some of the substances contained on this list are not currently used within the aerospace and defence industries, they may be used at some point in the future. This use will be of interest to customers or the sector to be tracked for appropriate managem
10、ent. Some of the substances within this list are either currently regulated or may be regulated when the assessments on the substances are completed. ASD-STAN, in partnership with the Aerospace and Defence Industries Association of Europe (ASD) and Aerospace Industries Association (AIA) compiled the
11、 list of all the substances that are known as being officially classified as: Carcinogens, Mutagens or Reproductive Toxins CMRs category 1 and 2, according to Annex 1 of Directive 67/548/EEC (as amended) Carcinogens, class 1 and 2A, according to IARC (International Agency for Research on Cancer) Per
12、sistent, Bioaccumulative and Toxic PBT, per the Convention for the Protection of the Marine Environment of the North-East Atlantic (known as the “OSPAR Convention“) - Chemicals for Priority Action (Marine Pollutants of the North-East Atlantic) (as amended through HSC(1) 2007) Substances defined as P
13、ersistent, Bioaccumulative and Toxic PBT or very Persistent, very bioaccumulative vPvB according to REACH regulation No. 1907/2006 Annex XIII; List obtained from ESIS (European chemical Substances Information System) Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reprod
14、uction or networking permitted without license from IHS-,-,-Page 4 TR 9536:08-03 Substances called out in REACH Annex XVII “Other” chemicals of concern to the aviation sector (Ozone Depleting Substances ODS as defined by Montreal Protocol and Persistent Organic Pollutants POP as defined by the Stock
15、holm Convention. Many of the substances called out in the reference regulations are actually families of substances, rather than discreet chemicals. The list included in this standard is directly derived from the above sources. However, to facilitate the identification of those substances which fall
16、 into these families being used in the suppply chain, the list has been further populated with the detailed EU index numbers of the substances belonging to these referenced families.This detailed list appears in TR 9535 Substance Declaration Microsoft Excel form. This compilation represents a good f
17、aith effort by the industry to accurately and completely compile a substance list based on regulations or stakeholders concerns.This list will be subject to change as new information becomes available, and we encourage users to refer to the latest version of this technical report. Copyright ASD-STAN
18、 Provided by IHS under license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 5 TR 9536:08-03 0 Scope This technical report applies to the aerospace and defence industries and their supply chain. 1 Purpose This list of substances was developed for
19、use by members of the aerospace and defence industries in order to assist in making product and process decisions to support compliance with regulatory requirements, as well as to meet customers and other third party obligations. In addition, this list will assist aerospace industry member companies
20、 with managing business risks, such as supply chain disruption. 2 Applicable documents This Technical Report will consist of a list of substances which are of interest to the sector to know whether any of these substances are used within aerospace products or manufacturing processes used to make the
21、se products. It is intended to be used in conjunction with TR 9535. ASD-STAN thanks the Aerospace and Defence Industries Association of Europe (ASD) and Aerospace Industries Association (AIA) for their cooperation in the planning of this document.This technical report is being published simultaneous
22、ly in Europe and in the U.S. The American version carries the same number and is published by SAE. 2.1 ASD-STAN Publications Available from ASD-STAN, 270, Avenue de Tervuren 2ndfloor, B-1150 Brussels, Belgium, Tel: +32 2 775 81 26 - Fax: +32 2 775 81 31, www.asd-stan.org. TR 9535: Substance Declarat
23、ion 2.2 SAE Publications Available from SAE International, 400 Commonwealth Drive, Warrendale, PA 15096-0001, Tel: 877-606-7323 (inside USA and Canada) or 724-776-4970 (outside USA), www.sae.org. ARP 9535: Substance Declaration Standard 3 Disclaimer While due diligence is being exercised in creating
24、 the Declarable Substances list, this list should not be considered to be exhaustive and will be periodically reviewed and updated. Application of this document is the sole responsibility of its users. Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reproduction or netwo
25、rking permitted without license from IHS-,-,-Page 6 TR 9536:08-03 4 Declarable substances list 4.1 Glossary of Chemical Family Identifier Abbreviations used in Declarable Substances List CMRs: Carcinogens, Mutagens or Reproductive Toxins CAS Number: A CAS registry number is a unique numeric identifi
26、er that can contain up to 10 digits, divided by hyphens into three parts, to designate only one chemical substance. The CAS number is assigned by the Chemical Abstract Service. EINECS: European Inventory of Existing Chemical Substances) is a registry number given to each chemical substance commercia
27、lly available in the European Union between 1 January 1971 and 18 September 1981. The inventory was created by Directive 67/548/EEC concerning the labelling of dangerous substances. ELINCS: European List of Notified Chemical Substances. HSC: Hazardous Substances Committee. Intended Release: A substa
28、nce is intended to be released, if under normal or reasonably foreseeable conditions of use, the release is essential for the end use function of the article. In other words, without the release of the substances, the article would not work sufficiently or as intended by the supplier of the article.
29、 Additionally, if the release contributes to a quality or minor function of the article, which is not directly connected to the end use function (e.g. perfumed eraser), then it is an intended release. Normal wear during use is not an intended release. MSDS: Material Safety Data Sheet is a form conta
30、ining data regarding the properties of a particular substance. An important component of product stewardship and workplace safety, it is intended to provide workers and emergency personnel with procedures for handling or working with that substance in a safe manner, and includes information such as
31、physical data (melting point, boiling point, flash point, etc.), toxicity, health effects, first aid, reactivity, storage, disposal, protective equipment, and spill handling procedures. The exact format of an MSDS can vary from source to source from source to source and shall be provided in complian
32、ce with the applicable regulatory framework and in the language of the country where the item is delivered. ODS: Ozone Depleting Substances. PBT: Persistent, Bioaccumulative and Toxic. POP: Persistent Organic Pollutants. SAP: Enterprise resource planning software produced by SAP AG, headquartered in
33、 Walldorf, Germany. vPvB: very Persistent and very Bioaccumulative. Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 7 TR 9536:08-03 4.2 Glossary of Chemical Family Identifier Abbreviations used in Dec
34、larable Substances List Chemical Family Full Name FAMAs Arsenic Compounds, including arsenic acid and its salts FAMAzoOther Other Azo compounds FAMBe Beryllium Compounds FAMBenzene Compounds based on a single benzene ring FAMBenziAzo Benzidine based azo dyes FAMCd Cadmium Compounds FAMCoWCarbide Cob
35、alt metal with tungsten carbide FAMCr Chrome compounds, other than CrVI FAMCrVI Chromium (VI) compounds arsenic trioxide FAMAs 1303-28-2 033-004-00-6 diarsenic pentaoxide; arsenic pentoxide; arsenic FAMAs NOCAS0019 033-005-00-1 arsenic acid and its salts FAMAs 7784-40-9 082-011-00-0 lead hydrogen ar
36、senate; Arsenic acid, lead(2+) salt (1:1) FAMAs 23593-75-1 clotrimazole FAMAzoOther 592-62-1 611-004-00-2 methyl-ONN-azoxymethyl acetate; methyl azoxy meth FAMAzoOther 7440-41-7 004-001-00-7 beryllium FAMBe NOCAS0015 004-002-00-2 beryllium compounds FAMBe 1304-56-9 004-003-00-8 beryllium oxide FAMBe
37、 108-70-3 1,3,5-trichlorobenzene FAMBenzene 108-88-3 TOLUENE FAMBenzene120-82-1 1,2,4trichlorobenzene; TRICHLOROBENZENE FAMBenzene 133-49-3 Pentachlorobenzenethiol FAMBenzene31472-83-0 Tetrachloro(tetrachlorophenyl)benzene FAMBenzene 50-00-0 FORMALDEHYDE FAMBenzene552-89-6 O-NITROBENZALDEHYDE FAMBen
38、zene 85-22-3 pentabromoethylbenzene* FAMBenzene87-61-6 1,2,3-trichlorobenzene FAMBenzene 75-28-5 601-004-01-8 isobutane (containing 0.1 % butadiene FAMBenzene 71-43-2 601-020-00-8 benzene FAMBenzene 118-74-1 602-065-00-6 hexachlorobenzene (HCB) FAMBenzene 96-09-3 603-084-00-2 styrene oxide; (epoxyet
39、hyl)benzene; phenyloxiran FAMBenzene Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 9 TR 9536:08-03 CAS Number EU Index Number Chemical Name Chemical Family 84777-06-0 607-426-00-1 1,2-benzenedicarbo
40、xylic acid, dipentylester, branched and linear FAMBenzene 68515-42-4 607-480-00-6 1,2-benzenedicarboxylic acid; di-C7-11-branched a FAMBenzene 79-46-9 609-002-00-1 2-nitropropane FAMBenzene121-14-2 609-007-00-9 2,4-dinitrotoluene dinitrotoluene, technical grade FAMBenzene 25321-14-6 609-007-00-9 2,4
41、-dinitrotoluene FAMBenzene92-93-3 609-039-00-3 4-nitrobiphenyl FAMBenzene 602-01-7 609-050-00-3 2,3-dinitrotoluene FAMBenzene 618-85-9 609-052-00-4 3,5-dinitrotoluene FAMBenzene 81-15-2 609-068-00-1 musk xylene FAMBenzene 25376-45-8 612-151-00-5 methyl-phenylenediamine diaminotoluene, technical prod
42、uct - mixture of 2 and 3 FAMBenzene 122-66-7 007-021-00-4 hydrazobenzene; 1,2-diphenylhydrazine FAMBenziAzo 60-09-3 611-008-00-4 4-aminoazobenzene; 4-phenylazoaniline FAMBenziAzo NOCAS0023 611-024-00-1 Benzidine based azo dyes; 4,4; -diarylazobiphen FAMBenziAzo 1937-37-7 611-025-00-7 disodium 4-amin
43、o-3- 4-(2,4-diaminophenyl)azo1 FAMBenziAzo 2602-46-2 611-026-00-2 tetrasodium 3,3-1,1-biphenyl- 4,4- diylbis(azo FAMBenziAzo 573-58-0 611-027-00-8 disodium 3,3-1,1-biphenyl- 4,4-diylbis(azo)b FAMBenziAzo 108225-03-2 611-058-00-7 (6-(4-hydroxy-3-(2-methoxyphenylazo)- 2-sulfonato-7 FAMBenziAzo NOCAS00
44、32 CADMIUM AND ITS COMPOUNDS FAMCd 1306-19-0 048-002-00-0 cadmium oxide (non-pyrophoric) FAMCd 7440-43-9 048-002-00-0 cadmium (non-pyrophoric) FAMCd 7790-79-6 048-006-00-2 cadmium fluoride FAMCd 10108-64-2 048-008-00-3 cadmium chloride FAMCd 10124-36-4 048-009-00-9 cadmium sulphate FAMCd 1306-23-6 0
45、48-010-00-4 cadmium sulphide FAMCd 7646-79-9 027-004-00-5 cobalt dichloride FAMCo 10124-43-3 027-005-00-0 cobalt sulphate FAMCo 74559-36-7 Tungsten carbide (WC), alloy, Kennametal K6; C W . Co; Cobalt metal with tungsten carbide FAMCoWCarbide NOCAS0026 Cobalt metal with tungsten carbide FAMCoWCarbid
46、e Copyright ASD-STAN Provided by IHS under license with AECMA Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 10 TR 9536:08-03 CAS Number EU Index Number Chemical Name Chemical Family 7789-09-5 024-003-00-1 ammonium dichromate FAMCr 24613-89-6 024-010-00-X dic
47、hromium tris(chromate); chromium III chromate; FAMCr 1333-82-0 024-001-00-0 chromium (VI) trioxide FAMCrVI 7778-50-9 024-002-00-6 potassium dichromate FAMCrVI 10588-01-9 024-004-00-7 sodium dichromate anhydrate FAMCrVI 7789-12-0 024-004-01-4 sodium dichromate, dihydrate FAMCrVI 14977-61-8 024-005-00
48、-2 chromyl dichloride; chromic oxychloride FAMCrVI 7789-00-6 024-006-00-8 potassium chromate FAMCrVI 13765-19-0 024-008-00-9 calcium chromate FAMCrVI 7789-06-2 024-009-00-4 strontium chromate FAMCrVI NOCAS0018 024-017-00-8 Chromium (VI) compounds FAMCrVI 7775-11-3 024-018-00-3 sodium chromate FAMCrVI NOCAS0024 611-029-00-9 o-dianisidine based azo dyes; 4,4-diarylazo-3,3 FAMDianisAzo 88-85-7 609-025-00-7 dinoseb; 6-sec-butyl-2,4-dinitrophenol FAMDinoseb NOCAS0021 609-026-00-2 salts and esters of dinoseb FAMDinoseb 1420-07-1 609-030-00-4 dinoterb (ISO); 2-tert-butyl-4,6
