1、Designation: C1606 04 (Reapproved 2009)Standard Test Method forSampling Protocol for TCLP Testing of ContainerGlassware1This standard is issued under the fixed designation C1606; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the
2、year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method defines the way in which containerglassware should be prepared before performing the Toxicity
3、Characteristic Leaching Procedure (TCLP). The method coversthe homogenization of the sample, and the selection of arepresentative portion of the sample to test and get reproduc-ible results.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in
4、 thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and to determine theapplicability of regulatory limitations prior to use.
5、2. Referenced Documents2.1 ASTM Standards:2E691 Practice for Conducting an Interlaboratory Study toDetermine the Precision of a Test Method3. Summary of Test Method3.1 Container glass articles decorated with ceramic glassdecorations are broken to fit the requirements of the TCLPprotocol by using a d
6、isc mill or roll mill apparatus, and then thesamples are homogenized using a riffle box. A representativesample of the glass articles can then be put through the TCLPtest with reproducible results.4. Significance and Use4.1 Sampling of decorated glass containers for the TCLPcan vary greatly, resulti
7、ng from the size and shape of the articlerelative to the amount of ceramic decoration on the ware.Breaking the glass can cause some of the pieces to have nodecoration on them, and others to be heavily decorated andmore likely to leach lead and cadmium under the TCLP test.This method provides an effe
8、ctive tool to homogenize the glasscontainers so that reproducible results can be attained from theTCLP test.5. Apparatus5.1 Pre-breaking apparatus, consisting of:5.1.1 Two L (or larger) polythene bucket with a tightlysealed lid,5.1.2 One or two clean 35 to 40 mm diameter aluminagrinding balls,5.2 Di
9、sc mill or roll mill,5.3 Sieves, as needed,5.4 Riffle box, and,5.5 Roller or tumbler apparatus.6. Reagents and Materials6.1 Glassware to be tested, in two sets of 10 units each.7. Hazards7.1 When working with glassware, always be aware andcareful of the potential of getting cut by the glass. Persona
10、lprotective equipment, such as a face shield or goggles, leathergloves, and a protective apron should be worn when workingwith glass.Take precautions when working with the samples andapparatus to avoid the possibilities of getting hurt.8. Sampling, Test Specimens, and Test Units8.1 Since the amount
11、of lead and cadmium that leaches froma decoration can be affected by the relative size of thedecoration, it is important to start with two sets of ten unitseach.9. Procedure9.1 To minimize the variation of sampling, this testing shallbe done in duplicate, and therefore, take two sets of 10 units oft
12、he glassware to be tested.1This test method is under the jurisdiction ofASTM Committee C21 on CeramicWhitewares and Related Products and is the direct responsibility of SubcommitteeC21.03 on Methods for Whitewares and Environmental Concerns.Current edition approved Oct. 1, 2009. Published February 2
13、010. Originallyapproved in 2004. Last previous edition approved in 2004 as C160604. DOI:10.1520/C1606-04R09.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the stan
14、dards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.9.2 Pre-break the glass prior to milling, using the followingprocedure:9.2.1 Place the first set of glassware into the 2 L bucket,along wi
15、th one or two clean 35 to 40 mm diameter aluminagrinding balls.9.2.2 After tightly sealing the lid, shake the vessel hardenough to smash the glass to create pieces that can be fed intothe roll or disc mill.9.3 Clean both the mill and riffle box, prior to use.9.4 Feed the pre-broken glass into the di
16、sc mill or roll millas feedstock.9.4.1 Grind the glass as two separate lots, with the selectedmill apertures set between 2.5 mm and 3.5 mm. Theseaperature settings tend to produce crushed glass with a maxi-mum particle size of 5 mm.9.5 Any oversized material must be removed by sieving orhand picking
17、, and be broken up prior to blending back into theoriginal sample.9.6 Homogenize the sample using a roller or tumblerapparatus.9.7 Immediately pass sample through the riffle box collect-ing two sub-samples of 100g each.9.8 Perform TCLP extraction according to EPA specifica-tions.10. Precision and Bi
18、as10.1 The number of laboratories, materials, and determina-tions in this study DOES NOT meet the minimum require-ments for determining precision prescribed in PracticeE691.10.1.1 This precision statement is provisional. Within fiveyears, additional data will be obtained and processed whichdoes meet
19、 the requirements of E691.11. Keywords11.1 TCLP; ceramic glass enamels; ceramic glassdecorationsASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determin
20、ation of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or wit
21、hdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that yo
22、ur comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (sin
23、gle or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM websit
24、e (www.astm.org/COPYRIGHT/).TABLE 1 Precision Statement for Test Method Sampling Protocolfor TCLP Testing of Container GlasswareNOTEPrecision, characterized by repeatability , Sr, r, and reproduc-ibility, SR, R has been determined for the materials to be:Material Average Sr r SR Rppm Pb 0.192000 0.076158 0.213242 0.086429 0.242002C1606 04 (2009)2
