1、Designation: C767 93 (Reapproved 2013)Standard Test Method forThermal Conductivity of Carbon Refractories1This standard is issued under the fixed designation C767; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last re
2、vision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method supplements Test Method C201, andshall be used in conjunction with that procedure to determinethe thermal co
3、nductivity of carbon or carbon-bearing refracto-ries. This test method is designed for refractories having aconductivity factor of not more than 200 Btuin./hft2F (28.8W/mK).1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconver
4、sions to SI units that are provided for information onlyand are not considered standard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices
5、 and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2C155 Classification of Insulating FirebrickC201 Test Method for Thermal Conductivity of RefractoriesE220 Test Method for Calibration of Thermocouples ByComparison Techniques3. Signific
6、ance and Use3.1 The thermal conductivity of carbon refractories is aproperty required for selecting their thermal transmissioncharacteristics. Users select carbon refractories to providespecified conditions of heat loss and cold face temperature,without exceeding the temperature limitation of the ca
7、rbonrefractory. This test method establishes placement of thermo-couples and positioning of test specimens in the calorimeter.3.2 This procedure must be used with Test Method C201and requires a large thermal gradient and steady state condi-tions. The results are based upon a mean temperature.3.3 The
8、 data from this test method is suitable for specifica-tion acceptance, estimating heat loss and surface temperature,and the design of multi-layer refractory construction.3.4 The use of these data requires consideration of the actualapplication environment and conditions.4. Apparatus4.1 The apparatus
9、 shall be in accordance with Test MethodC201 with the addition of thermocouples, back-up insulation,and refractory fiber paper as described in Section 5 of this testmethod.5. Test Specimen and Preparation5.1 Select the test specimen and prepare in accordance withTest Method C201.5.2 ThermocouplesEmb
10、ed calibrated thermocouples3inthe test specimen at two points for measuring temperature.Thermocouples4sheathed with material having low reactivitywith carbon must be used. Use the top thermocouple for onetest only.5.3 Installation of Thermocouples Place the hot junctionof the thermocouples in the ce
11、nter of each 9 by 412-in. (228 by114-mm) face and just below the surface of the test specimen.Cut grooves to receive the wire in each 9 by 412-in. face of thebrick to a depth necessary to embed the thermocouple justbeneath the surface by means of an abrasive wheel. The layoutfor the grooves allows a
12、ll of the cold-junction ends of the wiresto extend from one end of the brick. Cut a groove in the centerof each 9 by 412-in. face along the 9-in. dimension and end14in. (6 mm) beyond the center. Before cementing5the thermo-couples in place, take measurements to obtain, within 60.01in. (60.3 mm), the
13、 eventual distance between the center linesof the thermocouple junctions. Do this by measuring the212-in. (64-mm) dimension of the brick at the location for the1This test method is under the jurisdiction of ASTM Committee C08 onRefractories and is the direct responsibility of Subcommittee C08.02 on
14、ThermalProperties.Current edition approved Sept. 1, 2013. Published September 2013. Originallyapproved in 1973. Last previous edition approved in 2009 as C767 93 (2009).DOI: 10.1520/C0767-93R13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at s
15、erviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Method E220 specifies calibration procedures for thermocouples.4Claud S. Gordon Co., 5710 Kenosha St., Richmond, IL 60071,116 in. (2mm)sheathed Xactpak thermocouple,
16、Cat. No. 401-2104 or equivalent.5Alundum Cement RA 562 supplied by the Norton Co., One New Bond St.,Worcester, MA 01606, is satisfactory for this purpose.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1hot junctions and deducting the
17、distance between the centerline of each junction in its embedded position and the surfaceof the brick.5.4 Cover the calorimeter and inner and outer guards with a0.50-in. (12.7-mm) thick layer of Group 20 insulating firebrick(see Classification C155) for the purpose of obtaining a highermean temperat
18、ure in the test sample than would result byplacing the sample directly over the calorimeter area. Cut andgrind the back-up insulation so as to provide surfaces that areplane and do not vary from parallel by more than 60.01 in.(0.3 mm). Grind the sides of the pieces that are to be placed incontact pl
19、ane and at right angles to the horizontal faces. Makethe joints between the pieces tight without the use of anymortar.5.5 Place two strips of refractory fiber paper 1312 by12 by0.02 in. (342 by 13 by 0.5 mm) along the 1312-in. dimensionof the inner guard at the outside edges. Place twelve strips ofr
20、efractory fiber paper 2 by12 by 0.02 in. (51 by 13 by 0.5 mm)on the outer guards at intervals in the pattern shown in Fig. 1.These strips serve as spaces to prevent contact between theback-up insulation or the test material and the calorimeterassembly. Then place the back-up insulation on the calori
21、meterassembly so as to provide a level and plane surface. Placeadditional strips of refractory fiber paper of the same dimen-sions in the same pattern upon the back-up insulation. Thesestrips serve as spacers to prevent contact between the carbonbrick and the back-up insulation. Place the test speci
22、mencentrally over the center of the calorimeter section on its 9 by412-in. (228 by 114-mm) face, place the guard brick at the sidesof the test specimen so as to cover completely the calorimeterand inner guard area, and place the soap brick along the edgesof the three brick so as to cover completely
23、the calorimeterassembly. Fill the small space between the furnace walls andthe test brick assembly with granulated insulating firebrick.5.6 Place the silicon carbide slab over the 9 by 1312-in. (228by 342-mm) area of the three 9-in. (228-mm) brick specimen,and space it 1 in. nominal above the specim
24、en by placing undereach corner of the slab rectangular pieces of Group 28insulating firebrick (see Classification C155) cut to measure38-in. (10-mm) square and 1-in. nominal length.6. Conditions of Test6.1 Make a special effort to seal the furnace tightly so thatthe atmosphere can be maintained nono
25、xidizing through intro-duction of argon under slight positive pressure as measured bya draft gage. In addition, place several pieces of carbonrefractory around the edges of the furnace on top of the outerguard brick to react with any oxygen that may enter the furnacechamber. The argon should not imp
26、inge on the test samples,but should impinge on these additional pieces of carbon.Maintain the atmosphere void of oxygen throughout the test.7. Procedure7.1 Place the heating chamber in position, start waterflowing through the calorimeter assembly, and supply currentto the heating unit. Maintain the
27、rate of water flow through thecalorimeter between 120 and 200 g/min. Determine the flow byweighing the quantity of water collected during a measuredtime period. The weight of water collected shall not be lessthan 200 g and shall be weighed to an accuracy of 60.5 g. Therate of flow shall be constant
28、within 61 % during the testperiod.7.2 Allow the furnace to reach a condition of steady state ofheat flow at various mean temperatures successively increased.A steady state shall be that condition when the measured flowof heat into the calorimeter varies less than 2 % over a 2-hperiod, during which t
29、ime the temperature difference betweenthe calorimeter and the inner guard has not been more than0.05F (0.03C), the hot face of the test specimen has notvaried more than 5F (3C), and the temperature of the waterentering the calorimeter has not varied at a rate of more than1F (0.5C)/h (Note 1). Usuall
30、y, 12 h or more are needed toobtain a balance with the apparatus after a definite change ismade in the hot-face temperature.NOTE 1Significant errors will result if the tolerances specified areexceeded.7.3 After the steady state of heat flow has been reached,measure the temperature of the test specim
31、en, the rate of waterflow through the calorimeter, and the temperature rise of thewater flowing through the calorimeter. Take at least four sets ofreadings at approximately 30-min intervals during the 2-hholding period, and these shall be averaged for the final valuesfor that particular heating cham
32、ber temperature.NOTE 2From these data a preliminary thermal conductivity calcula-tion may be made, using estimated distances between thermocouplejunctions in the test specimen.7.4 At the conclusion of the test, examine the specimens forchanges which may have taken place as a result of the heattreatm
33、ent. Then remove the thermocouple wires, cut the brickin half through the 412 by 212-in. (114 by 64-mm) dimension,and examine for voids and cracks.FIG. 1 Arrangement of Refractory-Fiber Paper Strips in Calorim-eter AssemblageC767 93 (2013)28. Calculation8.1 Make the record of test data, the calculat
34、ions, and thereport in accordance with Test Method C201.9. Precision and Bias9.1 Refer to Test Method C201 for a statement of precisionand bias.10. Keywords10.1 calorimeter; carbon refractories; refractories; thermalconductivityASTM International takes no position respecting the validity of any pate
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36、at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comme
37、nts will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted
38、 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).C767 93 (2013)3
