1、Designation: D1153 06D1153 12Standard Specification forMethyl Isobutyl Ketone1,2This standard is issued under the fixed designation D1153; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in paren
2、theses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers methyl isobutyl ketone (99.0 % grade).1.2
3、For specific hazard information and guidance, see the suppliers Material Safety Data Sheet for materials listed in thisspecification.1.3 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard,an observed value or a calculated value
4、shall be rounded off “to the nearest unit” in the last right-hand digit used in expressingthe specification limit, in accordance with the rounding-off method of Practice E29.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
5、1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatorylimitations prior to use.2. Referenced Doc
6、uments2.1 ASTM Standards:3D268 Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings andMaterialD1078 Test Method for Distillation Range of Volatile Organic LiquidsD1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)D1296 Te
7、st Method for Odor of Volatile Solvents and DiluentsD1353 Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related ProductsD1364 Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)D1476 Test Method for Heptane Miscibility
8、of Lacquer SolventsD1613 Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and RelatedProductsD3329 Test Method for Purity of Methyl Isobutyl Ketone by Gas ChromatographyD4052 Test Method for Density, Relative Density, and API Gravity of Liquids
9、 by Digital Density MeterD5386 Test Method for Color of Liquids Using Tristimulus ColorimetryE1 Specification for ASTM Liquid-in-Glass ThermometersE29 Practice for Using Significant Digits in Test Data to Determine Conformance with SpecificationsE300 Practice for Sampling Industrial Chemicals2.2 U.S
10、. Federal Specification:PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging of 41 This specification is under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.35 on Solvents, Plasticizers, and Ch
11、emical Intermediates.Current edition approved June 1, 2006Nov. 1, 2012. Published June 2006January 2013. Originally approved in 1951. Last previous edition approved in 20012006 asD1153 94 (2001).D1153 06. DOI: 10.1520/D1153-06.10.1520/D1153-12.2 This compound is also known under the name of 2-methyl
12、 -4-pentanone.3 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the ASTM website.4 Available from Standardization Documents Orde
13、r Desk, DODSSP, Bldg. 4, Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098, http:/dodssp.daps.dla.mil.This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be t
14、echnically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current versionof the standard as published by ASTM is to be considered the official document.*A Summary of Changes section appears at the end of t
15、his standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States13. Properties3.1 Methyl isobutyl ketone (99.0 % grade) shall conform to the following requirements:D1153 122Methyl isobutyl ketone wt %, min 99.0Apparent specific gravity:20/
16、20C 0.800 to 0.803or25/25C 0.796 to 0.799Color, Pt-Co units, maxA 15Distillation, CInitial boiling point, min 114.0Dry point, max 117.0Nonvolatile matter, mg/100 mL, max 5OdorB nonresidualWater, wt %, maxC 0.1Acidity (free acid as acetic acid), wt % , max 0.01Methyl isobutyl carbinol, wt %, max 0.3A
17、 Instrumental Pt-Co color determined by Test Method D5386 have been shown to have no statistically significant difference from PT-Co color determined by Test MethodD1209. However, it is not known whether methyl isobutyl ketone was part of the sample set included in the interlaboratory study.B Option
18、al: Test for odor only when agreed upon as necessary by the purchaser and the supplier.C This quantitative water limit ensures that the material is miscible without turbidity with 19 volumes of 99 % heptane at 20C.4. Sampling4.1 The material shall be sampled in accordance with Practice E300.5. Test
19、Methods5.1 The properties enumerated in this application shall be determined in accordance with the following ASTM Test Methods:5.1.1 Apparent Specific GravityDetermine the apparent specific gravity by any convenient method that is accurate to the thirddecimal place, the temperature of both specimen
20、 and water being 20 or 25C. See Guide D268 or Test Method D4052.5.1.2 ColorTest Method D1209.5.1.3 Distillation RangeTest Method D1078 using an ASTM Solvents Distillation Thermometer having a range from 98 to152C and conforming to the requirements for Thermometer 41C as prescribed in Specification E
21、1. Thermometric devices suchas RTDs, thermistors and liquid-in-glass thermometers of equal or better accuracy in the specified temperature range, may be used.5.1.4 Nonvolatile MatterTest Method D1353.5.1.5 OdorTest Method D1296.5.1.6 WaterTest Method D1364 or D1476.5.1.7 AcidityTest Method D1613.5.1
22、.8 Alcohol and PurityTest Method D3329.6. Packaging and Package Marking6.1 Package site shall be agreed upon by the purchaser and the supplier.6.2 Packaging shall conform to applicable carrier rules and regulations or when specified shall conform to Fed. Spec.PPP-C-2020.7. Keywords7.1 ketones; methy
23、l isobutyl ketone (MIBK); solvents; 2-methyl-4-pentanoneSUMMARY OF CHANGESCommittee D01.35 has identified the location of selected changes to this standard since the last issue(D1153 - 94 (2001)D1153) - 06) that may impact the use of this standard. (Approved JuneNovember 1,2006.)2012.)(1) Added refe
24、rence to Practice language E29in Scope section.5.1.3 that allows for the use of non-mercury thermometers.(2) Added Practice E29 to list of Referenced Documents.(3) Changed specs limits for apparent specific gravity in 3.1.(4) Added new footnote A in 3.1.(5) Added Test Method D5386 to list of Referen
25、ced Documents.D1153 123ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringem
26、ent of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn.Your comments are invited either for revision of this standard or
27、for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views kno
28、wn to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D1153 124
