1、Designation: D1582 98 (Reapproved 2017)Standard Test Method forNonvolatile Content of Liquid Phenol, Resorcinol, andMelamine Adhesives1This standard is issued under the fixed designation D1582; the number immediately following the designation indicates the year oforiginal adoption or, in the case of
2、 revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers the determination of nonvolatilecontent or total solids of liquid pheno
3、l, resorcinol, andmelamine adhesives with or without hardener (Note 1) addedand containing high-boiling and low-boiling volatile organicsolvents or water, or both.NOTE 1Some low molecular weight materials in the adhesive may belost if hardener is not used. When a hardener is used, it must be mixed i
4、naccordance with the manufacturers instructions.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibilit
5、y of the user of this standard to establish appro-priate safety, health and environmental practices and deter-mine the applicability of regulatory limitations prior to use.For specific precautions, see 5.2.1.4 This international standard was developed in accor-dance with internationally recognized p
6、rinciples on standard-ization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2D907 Terminology of Adhesive
7、s3. Terminology3.1 DefinitionsMany of the terms in this test method aredefined in Terminology D907.4. Summary of Test Method4.1 Without HardenerA weighed amount of adhesive andquartz sand are oven-dried, cooled in a desiccator, andweighed. The percent nonvolatile content is calculated basedon the am
8、ount remaining.4.2 With HardenerA weighed amount of mixed adhesiveis oven dried, cooled in a desiccator, and weighed. The percentnonvolatile content is calculated based on the amount remain-ing.5. Apparatus5.1 Petri Dish, 00 by 22 mm or its equivalent.5.2 Circulating-Air Oven, capable of maintaining
9、 tempera-tures of 70 6 1C, 105 6 1C, and 150 6 1C. (Warning Asafety (explosion-proof) oven should be used when volatilematerials are likely to burn or explode.)5.3 Desiccator, with drying agent and tray.5.4 Analytical Balance, accurate to 1 mg.6. Sampling6.1 Except in special cases, take a composite
10、 sample fromthree or more separate containers chosen at random. Also, takesamples from containers which appear to be nonrepresentativeand test such samples separately. Place the samples immedi-ately in airtight containers, filled to prevent excessive air spaceabove the adhesive, and take precautions
11、 to reduce evaporationor drying to a minimum. Mix the adhesive in the containerthoroughly if there is a tendency for the materials to separate.6.2 Test three specimens of each sample.7. Procedure7.1 70C Drying Temperature Without Hardener:7.1.1 Place approximately 20 g of the adhesive in a coveredwe
12、ighing bottle.7.1.2 Place approximately 10 g of fine, oven-dried quartzsand in an open Petri dish, together with a small glass stirringrod, and weigh the dish, rod, and contents to the nearest 1 mgon the analytical balance. Weigh out to the nearest 1 mgapproximately2goftheadhesive by difference from
13、 theweighing bottle, keeping the bottle covered as much as1This test method is under the jurisdiction of ASTM Committee D14 onAdhesives and is the direct responsibility of Subcommittee D14.30 on WoodAdhesives.Current edition approved Aug. 1, 2017. Published August 2017. Originallyapproved in 1958. L
14、ast previous edition approved in 2011 as D1582 98 (2011).DOI: 10.1520/D1582-98R17.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary pag
15、e onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for th
16、eDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.1possible. Mix the adhesive and quartz sand intimately bymeans of the stirring rod and distribute uniformly over thebottom of the dish in as thin a l
17、ayer as possible. Condition thespecimen at 23 6 1C for at least 16 h.7.1.3 Place the dish with the rod and contents in the oven at70 6 1C until a constant weight is reached.7.1.4 Place the warm dish immediately in the desiccator andallow to cool to room temperature before weighing to thenearest 1 mg
18、.7.2 70C Drying Temperature With Hardener:7.2.1 Mix approximately 100 g of the adhesive in accor-dance with the manufacturers directions, weighing compo-nents to the nearest 0.01 g.7.2.2 Proceed as in 7.1.2, 7.1.3, and 7.1.4.7.3 105C Drying Temperature Without HardenerProceedas in 7.1 except to plac
19、e the sample in the oven at 105 6 1C.7.4 105C Drying Temperature With HardenerProceed asin 7.2 except to place the sample in the oven at 105 6 1C.7.5 150C Drying Temperature Without HardenerProceedas in 7.1 except to place the sample in the oven at 150 6 1C.7.6 150C Drying Temperature With HardenerP
20、roceed asin 7.2 except to place the sample in the oven at 150 6 1C.8. Calculation8.1 Calculate the percent nonvolatile content or total solidsas follows:Nonvolatile content, % 5 wt of residue/wt of specimen! 3100 (1)The weight of the residue is the difference in the weight ofthe dish, rod, and conte
21、nts before and after heating.8.2 Repeat the test if the results for the three specimens ofa sample do not agree with 60.5 percentage units of oneanother.9. Report9.1 Report the following information:9.1.1 Complete identification of the adhesive tested, includ-ing type, lot number, and source,9.1.2 P
22、rocedure used,9.1.3 Catalyst or hardener, mixing proportions, and condi-tions used, where applicable,9.1.4 Total drying time to reach constant weight,9.1.5 Number of specimens tested, and9.1.6 Individual nonvolatile content of the three specimensand the average nonvolatile content of the sample.10.
23、Precision and Bias10.1 A precision and bias statement does not exist for thistest method because resources necessary for round-robin test-ing have not been forthcoming.11. Keywords11.1 adhesives; melamine; nonvolatile content; phenol; re-sorcinolASTM International takes no position respecting the va
24、lidity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is su
25、bject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headqu
26、arters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This stand
27、ard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 98 (2017)2
