1、Designation: D5201 05a (Reapproved 2010)Standard Practice forCalculating Formulation Physical Constants of Paints andCoatings1This standard is issued under the fixed designation D5201; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision
2、, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This practice covers procedures commonly used in thepaint industry to formulate paints and coating mate
3、rials. Itdescribes procedures for calculating formulation values forweight solids, volume solids, solvent content, volatile organiccompound (VOC) content, hazardous air pollutant (HAP)content, and density of liquid paints and coatings. These valuesare calculated from basic formulation data. These ca
4、lculationsmay be related to either as-supplied (unreduced) or as-applied(reduced) coating materials, including multicomponent types.1.2 These calculated, formulation-based values may or maynot be acceptable for VOC regulatory purposes, depending onthe specific wording of the applicable regulation. S
5、ome regu-lations require analysis of the coating. Some rules allow the useof formulation data, however, some adjustments may beneeded to the values calculated in this practice before they areused for regulatory purposes (see 4.3).1.3 For purposes of this practice, it is assumed that volatilecomponen
6、ts evaporate and the materials that remain areidentified as coating solids. For example, solvents are normallyused to adjust viscosity for application and appearance of thecoating. Other liquid materials, such as plasticizers, reactivediluents, etc., that are expected to be retained in the dried fil
7、mto affect the final physical properties should be classified aspart of the coating solids. Standards such as Test MethodsD2369, D4758, D5403 and Guide D2832 may be used todetermine volatile or nonvolatile content of specific compo-nents. For purposes of this practice it is assumed that theblended f
8、ormulation behaves as an ideal solution with novolume change on mixing (see 6.2).1.4 Volatile by-products of cross-linking reactions (curevolatiles) are not considered in these calculations since theobject of this practice is to define paint physical constantsbased on formulation information. Variat
9、ions in raw materials,variations in the production processes, test methods, and testmethod accuracy are not taken into account in these calcula-tions.1.5 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that
10、are provided for information onlyand are not considered standard. However, they may be readilyconverted into SI units, if required by the user (for example,see Note 4).2. Referenced Documents2.1 ASTM Standards:2D153 Test Methods for Specific Gravity of PigmentsD1475 Test Method For Density of Liquid
11、 Coatings, Inks,and Related ProductsD2369 Test Method for Volatile Content of CoatingsD2832 Guide for Determining Volatile and NonvolatileContent of Paint and Related CoatingsD3960 Practice for Determining Volatile Organic Com-pound (VOC) Content of Paints and Related CoatingsD4758 Test Method for N
12、onvolatile Content of Latexes3D5403 Test Methods for Volatile Content of RadiationCurable MaterialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with Specifications2.2 U. S. Environmental Protection Agency Documents:Code of Federal Regulations Title 40 Part 51.100 (s
13、)Definition of VOC Clean Air Act, Section 1124,5Code of Federal Regulations Title 40 Part 63, SubpartNNNN, Table 3 (Default Organic HAP Mass Fraction forSolvents and Solvent Blends) and Subpart RRRR Table 4(Default Organic HAP Mass Fraction for Petroleum Sol-vent Groups)4EPAFederal Reference Method
14、24 Determination of Vola-tile Matter Content, Water Content, Density Volume1This practice is under the jurisdiction of ASTM Committee D01 on Paint andRelated Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.24 on Physical Properties of Liquid Paints formulati
15、on; HAP; hazardous air pollutant;physical constants; solids content; VOC; volatile organiccompoundD5201 05a (2010)5SUMMARY OF CHANGESCommittee D01 has identified the location of selected changes to this standard since the last issue,(D5201 05), that may impact the use of this standard. (Approved Dec
16、ember 1, 2005.)(1) Revised Eq. 11 and 12.Committee D01 has identified the location of selected changes to this standard since the last issue(D5201 03a) that may impact the use of this standard. (Approved May 15, 2005.)(1) Added reference to HAP in 1.1.(2) Added reference to Test Methods D5403 in 1.3
17、 and 2.1.(3) Added reference to various documents that refer to HAP in2.2.(4) Added definition of formula HAP content in 3.1.2.(5) Added additional information to footnote 3.(6) Added footnote 4.(7) Added the word solvent to 5.5.(8) Added 5.7 on calculating Formula HAP Content.(9) Added 5.8.2.3 on c
18、alculating VOC Content of reducedpaints.(10) Added 5.8.2.4 on calculating HAP Content of reducedpaints.ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that d
19、etermination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved
20、 or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel
21、that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprin
22、ts (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D5201 05a (2010)6