1、BRITISH STANDARD BS 6200-3.0:2002 Including Corrigendum No. 1 Sampling and analysis of iron, steel and other ferrous metals Part 3.0: Reference methods of analysis Summary of methods ICS 77.040; 77.100 BS 6200-3.0:2002 This British Standard, having been prepared under the direction of the Engineerin
2、g Sector Policy and Strategy Committee, was published under the authority of the Standards Policy and Strategy Committee on 11 October 2002 BSI 21 November 2002 The following BSI references relate to the work on this British Standard: Committee reference ISE/18 Draft for comment 00/708702 DC ISBN 0
3、580 37264 2 Committees responsible for this British Standard The preparation of this British Standard was entrusted to Technical Committee ISE/18, Sampling and analysis of iron and steel, upon which the following bodies were represented: UK Steel Association Welding Institute Amendments issued since
4、 publication Amd. No. Date Comments 14235 Corrigendum No. 1 21 November 2002 Correction to standard identifierBS 6200-3.0:2002 BSI 21 November 2002 i Contents Page Committees responsible Inside front cover Foreword ii 1S c o p e 1 2 Methods for the chemical analysis of iron, steel and other ferrous
5、metals 1 Annex A (informative) European standards and corresponding subsections of BS 6200 9 Annex B (informative) International standards and corresponding subsections of BS 6200 10 Bibliography 11 Table 1 Methods of analysis 2 Table A.1 European standards and corresponding British Standards 9 Tabl
6、e B.1 International standards and corresponding British Standards 10BS 6200-3.0:2002 ii BSI 21 November 2002 Foreword This section of BS 6200-3 has been prepared by Technical Committee ISE/18. It supersedes BS 6200-3.0:1991, which is withdrawn. BS 6200 is a multipart British Standard covering all as
7、pects of the sampling and analysis of ferrous materials and consists of the following parts: Part 1: Introduction and contents; Part 2: Sampling and sample preparation; Part 3: Reference methods of analysis; Part 4: Recommendations for the order of listing elements in the chemical analysis of steel;
8、 Part 5: Guidelines on statistical procedures; Part 6: Guidelines on atomic absorption techniques; Part 7: Routine methods of analysis. 1) A general introduction to BS 6200 is given in Part 1, which lists the contents of all the existing parts, sections and subsections. Part 3 consists of a summary
9、of the available referee methods of analysis. It is divided into separate sections for each element being determined and each section is further divided into subsections for different techniques and/or different ranges of application. Section 3.0 summarizes briefly the scope and origin of all the su
10、bsections currently available. This new edition has been prepared to bring Section 3.0 up to date. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer
11、immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, pages 1 to 11 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. 1) At the time of print BS 6200-7 was in pr
12、eparation.BS 6200-3.0:2002 BSI 21 November 2002 1 1 Scope This section of BS 6200-3 provides a summary of all the methods of analysis which have been published as subsections of BS 6200-3 and also includes details of European standards which have been published separately as BS ENs. 2 Methods for th
13、e chemical analysis of iron, steel and other ferrous metals The methods currently available as British Standards are listed in Table 1 in alphabetical order of the element being determined. Multi-element methods are presented at the end of the table after the alphabetical listing for individual elem
14、ents. Attention is drawn to the fact that further information relating to the range or field of application can be found in the scope clause of individual standards. A list of the European standards with corresponding British Standards is presented in Annex A. International standards which have been
15、 implemented as subsections of BS 6200-3 are listed in Annex B.BS 6200-3.0:2002 2 BSI 21 November 2002 Table 1 Methods of analysis Element Subsection number of BS 6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook
16、 No. 19 method or other method superseded or updated Aluminium 3.1.1:1991 (Aluminium content normally found in the materials in the field of application) Steel, cast iron, low carbon ferro-chromium and chromium metal Volumetric method Aluminium 1 3.1.2:1991 0.001 to 0.10 Steel and cast iron NOTE It
17、is unsuitable for steels containing beryllium Spectrophotometric method Aluminium 3 3.1.4:1990 0.005 to 0.2 Non-alloyed steel FAAS method a EN 29658:1991 (identical to ISO 9658:1990) 3.1.5:1985 0.05 to 5 Ferrosilicon FAAS method a ISO 4139:1979 3.1.6:1991 5 to 15 Permanent magnet alloys containing 7
18、%t o3 5% n i c k e l , 10 % to 30 % cobalt, 0 . 5%t o8% c o p p e r , up to 3 % titanium, up to 6 % niobium, all percentage by mass and the remainder iron Volumetric method Aluminium 2 Arsenic BS EN 10212:1996 0.001 to 0.08 Steel and iron Spectrophotometric method EN 10212:1995 Boron BS EN 10200:199
19、2 0.000 4 to 0.012 0 Steel Spectrophotometric method EN 10200:1991 3.5.2:1991 (Boron content normally found in ferroboron) Ferroboron Volumetric method Boron 2 3.5.3:1998 0.000 05 to 0.001 0 Steel Curcumin spectrophotometric method ISO 13900:1997 a The abbreviation FAAS indicates “Flame atomic absor
20、ption spectrometric”.BS 6200-3.0:2002 BSI 21 November 2002 3 Table 1 Methods of analysis (continued) Element Subsection number of BS 6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method or other method
21、 superseded or updated Calcium 3.7.1:1987 0.000 2 Steel FAAS method c EN 10177:1989 (identical to Euronorm 177:1985) Carbon BS EN 10036:1991 0.1 Steel and iron Gravimetric method after combustion EN 10036:1989 BS 6200-3.8.1:1985 3.8.2:1991 (Carbon content found in all types of steel, pig and cast ir
22、on and commercially pure iron) Steel and cast iron Non-aqueous titrimetric method after combustion C a r b o n 4 3.8.3:1990 0.003 to 4.5 Steel and iron Infra-red absorption method after combustion ISO 9556:1989 3.8.5:1991 b 0.1 Non-combined carbon in cast iron and pig iron Gravimetric method Chromiu
23、m BS EN 24937:1991 0.25 to 35 Steel and iron Potentiometric or visual titration method EN 24937:1990 (identical to ISO 4937:1986) BS 3.10.1:1985 3.10.2:1989 0.002 to 2.0 Steel and iron FAAS method c EN 10188:1989 3.10.4:1985 Ferrochromium and ferrosilicochromium Potentiometric method ISO 4140:1979 3
24、.10.5:1992 High and low carbon grades of ferrochromium Volumetric method Chromium 3 Cobalt 3.11.1:1991 0.04 to 12 Steel and cast iron Spectrophotometric method Cobalt 1 3.11.2:1991 0.002 to 0.04 Steel, irons and steelmaking materials Spectrophotometric method Cobalt 2 3.11.3:1997 0.003 to 5.0 Steel
25、and iron FAAS method c ISO 11652:1997 b To be used in conjunction with BS EN 10036 c The abbreviation FAAS indicates “Flame atomic absorption spectrometric”.BS 6200-3.0:2002 4 BSI 21 November 2002 Table 1 Methods of analysis (continued) Element Subsection number of BS 6200 or BS EN and year of publi
26、cation Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method or other method superseded or updated Copper 3.12.1:1986 0.1 Steel and iron Volumetric method Copper 1 3.12.2:1985 0.02 to 5 Steel and iron Spectrophotometric method EN 24946:1990
27、 (identical to ISO 4946:1984) Copper 3 3.12.3:1986 0.004 to 0.5 Steel and iron FAAS method d EN 24943:1990 (identical to ISO 4943:1985) 3.12.4:1986 0.1 Cast iron Volumetric method Copper 5 3.12.5:1986 0.5 to 8 Permanent magnet alloys Volumetric method Copper 4 Lead 3.16.1:1986 0.5 Carbon and low all
28、oy steel Gravimetric method Lead 1 3.16.2:1986 0.05 to 0.5 Steel Spectrophotometric method L e a d 2 3.16.3:1991 0.000 5 to 0.05 Steel Spectrometric method L e a d 3 3.16.4:1987 0.003 to 0.5 Steel FAAS method d EN 10181:1989 (identical to Euronorm 181:1985) Magnesium 3.17.1:1992 Magnesium content no
29、rmally found in nodular graphite cast iron containing up to 2 % (m/m) nickel Cast iron Volumetric method Method 1 d The abbreviation FAAS indicates “Flame atomic absorption spectrometric”.BS 6200-3.0:2002 BSI 21 November 2002 5 Table 1 Methods of analysis (continued) Element Subsection number of BS
30、6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method or other method superseded or updated Manganese BS EN 10071:1991 0.5 Steel Steel and iron Electrometric titration method EN 10071:1989 BS EN ISO 107
31、00:1995 0.002 to 2.00 Steel and iron FAAS method e EN ISO 10700:1995 3.18.2:1985 0.01 to 4 Steel Spectrophotometric method ISO 629:1982 Manganese 2 3.18.3:1985 55 to 95 Ferro-manganese and ferrosilico-manganese Potentiometric method EN 24159:1989 (identical to ISO 4159:1978) Manganese 3 3.18.4:1991
32、0.02 to 14 Steel and cast iron Volumetric method Manganese 1 Molybdenum 3.19.1:1985 0.03 to 9 Steel and iron Spectrophotometric method ISO 4941:1978 Molybdenum 1 3.19.2:1992 (Range of molybdenum contents normally found in ferromolybdenum) Ferromolybdenum Gravimetric method Molybdenum 2 3.19.3:1992 (
33、Range of molybdenum contents normally found in molybdenum oxide and molybdenite ores) Molybdenum oxide and molybdenite ores Gravimetric method Molybdenum 3 Nickel 3.20.1:1989 0.5 to 30 Steel and iron Gravimetric or titrimetric method EN 24938:1990 (identical to ISO 4938:1988) 3.20.3:1985 0.1 to 4 St
34、eel and iron Spectrophotometric method ISO 4939:1984 Nickel 3 BS EN 10136:1991 0.003 to 2.0 Steel and iron FAAS method e EN 10136:1989 BS 6200-3.20.4 Niobium 3.21.1:1986 0.002 to 1.3 Steel Spectrophotometric method EN 10178:1989 (identical to Euronorm 178:1985) e The abbreviation FAAS indicates “Fla
35、me atomic absorption spectrometric”.BS 6200-3.0:2002 6 BSI 21 November 2002 Table 1 Methods of analysis (continued)Element Subsection number of BS 6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method o
36、r other method superseded or updated Nitrogen 3.22.1:1992 0.005 to 0.25 Steel (except those steels containing silicon nitride) Volumetric method Nitrogen 1 3.22.2:1985 0.002 to 0.050 Steel Spectrophotometric method ISO 4945:1977 3.22.3:1986 0.000 5 to 0.005 Steel Spectrophotometric method EN 10179:1
37、989 (identical to Euronorm 179:1985) Nitrogen 2 3.22.4:1997 0.000 8 to 0.5 Steel and iron Thermal conductimetric method ISO 10720:1997 Phosphorus BS EN 10184:1992 0.005 to 1.5 Steel and iron Spectrophotometric method EN 10184:1989 BS 6200-3.24.1 3.24.2:1992 (Phosphorus contents normally found in fer
38、rochromium, ferromaganese and ferromolybdenum) Ferrochromium, ferromaganese and ferromolybdenum Spectrophotometric method Phosphorus 3 Silicon 3.26.1:1995 0.10 to 5.0 Steel and iron Gravimetric method ISO 439:1994 3.26.2:1991 10 to 20 Acid-resisting high silicon iron Gravimetric method Silicon 2 3.2
39、6.3:1987 0.05 to 1.0 Steel Spectrophotometric method EN 24829-1:1990 (identical to ISO 4829-1:1986) Silicon 4 3.26.4:1989 0.01 to 0.05 Steel Spectrophotometric method EN 24829-2:1990 (identical to ISO 4829-2:1988) 3.26.5:1985 8 to 95 Ferrosilicomanganese and ferrosilicochromium Gravimetric method IS
40、O 4158:1978 BS 6200-3.0:2002 BSI 21 November 2002 7 Table 1 Methods of analysis (continued) Element Subsection number of BS 6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method or other method supersed
41、ed or updated Sulfur 3.28.1:1985 0.003 Steel and iron Gravimetric method EN 24934:1989 (identical to ISO 4934:1980) Sulfur 1 3.28.2:1990 0.002 to 0.10 Steel and iron Infra-red absorption method after combustion EN 24935:1991 (identical to ISO 4935:1989) 3.28.3:1995 0.000 3 to 0.010 Steel and iron Sp
42、ectrophotometric method ISO 10701:1994 Tantalum 3.29.1:1986 0 Steel Spectrophotometric method T a n t a l u m 1 Tin 3.31.1:1992 0.005 to 0.25 Steel and cast iron Volumetric method Tin 1 3.31.2:1992 (Tin contents normally found in ferrotungsten and tungsten metal) Ferrotungsten and tungsten metal Vol
43、umetric method Tin 2 3.31.3:2002 0.001 to 0.10 Steel and iron Flame atomic absorption spectrometric method Titanium BS EN 10211:1996 0.01 to 1 Alloyed and non-alloyed steel and iron FAAS method f EN 10211:1995 BS EN ISO 10280:1995 (Formerly 3.32.1:1991) 0.004 to 0.80 Steel and iron Spectrophotometri
44、c method EN ISO 10280:1995 (identical to ISO 10280:1991) 3.32.4:1985 20 to 80 Ferrotitanium Volumetric method ISO 7692:1983 f The abbreviation FAAS indicates “Flame atomic absorption spectrometric”.BS 6200-3.0:2002 8 BSI 21 November 2002 Table 1 Methods of analysis (continued)Element Subsection numb
45、er of BS 6200 or BS EN and year of publication Range % (m/m) Field of application Method principle Identical ISO or European standard BSI Handbook No. 19 method or other method superseded or updated Tungsten 3.33.1:1992 3 to 30 Steel (other than those containing niobium and/or tantalum) Gravimetric
46、method Tungsten 1 3.33.2:1992 0.02 to 3.0 Steel (not recommended for steels with molybdenum content exceeding 1.5 %. If vanadium is present, a correction is necessary) Spectrophotometric method Tungsten 2 3.33.3:1985 70 to 90 Ferrotungsten Gravimetric ISO 7693:1984 Vanadium 3.34.1:1989 0.04 to 2 Ste
47、el and iron Potentiometric method EN 24947:1990 (identical to ISO 4947:1986) 3.34.2:1989 0.005 to 0.5 Steel and iron Spectrophotometric method ISO 4942:1988 3.34.3:1990 0.005 to 1.0 Steel and iron FAAS method g ISO 9647:1989 3.34.4:1985 0.03 Steel Gravimetric method Zirconium 1 Multi-element methods
48、 3.40.1:1997 Nickel (0.001 to 0.30), copper (0.001 to 0.40), cobalt (0.001 to 0.10) Unalloyed steel and unalloyed iron Inductively coupled plasma atomic emission spectrometric method ISO 13898-1:1997 3.40.2:1997 Nickel (0.001 to 0.30) ISO 13898-2:1997 3.40.3:1997 Copper (0.001 to 0.40) ISO 13898-3:1
49、997 3.40.4:1997 Cobalt (0.001 to 0.10) ISO 13898-4:1997 g The abbreviation FAAS indicates “Flame atomic absorption spectrometric”.BS 6200-3.0:2002 BSI 21 November 2002 9 Annex A (informative) European standards and corresponding subsections of BS 6200 Older European standards were originally published as dual-numbered standards. T
