1、BRITISH STANDARD BS EN ISO 4610:2001 Incorporating Corrigendum No. 1 Plastics Vinyl chloride homopolymer and copolymer resins Sieve analysis using air-jet sieve apparatus The European Standard EN ISO 4610:2001 has the status of a British Standard ICS 83.080.20; 19.120 NO COPYING WITHOUT BSI PERMISSI
2、ON EXCEPT AS PERMITTED BY COPYRIGHT LAWBS EN ISO 4610:2001 This British Standard, having been prepared under the direction of the Sector Policy and Strategy Committee for Materials and Chemicals, was published under the authority of the Standards Policy and Strategy Committee on 29 November 2001 BSI
3、 15 March 2002 ISBN 0 580 38730 5 National foreword This British Standard is the official English language version of EN ISO 4610:2001. It is identical with ISO 4610:2001. It supersedes BS EN ISO 4610:1997 which is withdrawn. The UK participation in its preparation was entrusted to Technical Committ
4、ee PRI/82, Thermoplastic Materials, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be fo
5、und in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standar
6、ds are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for chan
7、ge, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii to iv, pages 1 t
8、o 4, an inside back cover and a back cover. The BSI copyright date displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date Comments 13756 Corr. No. 1 15 March 2002 Incorporation of corrected EN ForewordEUROPEANSTANDARD NORMEEUROPENNE
9、EUROPISCHENORM ENISO4610 October2001 ICS83.080.20 SupersedesENISO4610:1997 Englishversion PlasticsVinylchloridehomopolymerandcopolymerresins Sieveanalysisusingairjetsieveapparatus(ISO4610:2001) PlastiquesRsinesdhomopolymresetcopolymresde chloruredevinyleAnalysegranulomtriquesurtamiseuse dpressiondai
10、r(ISO4610:2001) KunststoffeVinylchloridHomoundCopolymerisate SiebanalysemitderLuftstrahlSiebmaschine(ISO 4610:2001) ThisEuropeanStandardwasapprovedbyCENon4October2001. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusof
11、anationalstandardwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheManagementCentreortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation under
12、theresponsibilityofaCENmemberintoitsownlanguageandnotifiedtotheManagementCentrehasthesamestatusasthe official versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,CzechRepublic,Denmark,Finland,France,Germany,Greece, Iceland,Ireland,Italy,Luxembourg,Netherlands,Norway,Portugal,Spain,Swe
13、den,SwitzerlandandUnitedKingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:ruedeStassart,36B1050Brussels 2001CEN Allrightsofexploitationinanyformandbyanymeansreserved worldwideforCENnationalMembers. Ref.No.ENISO4610:2001EINESO64:0102
14、(10E) 2 CORRECTED20020206 Foreword ThetextoftheInternationalStandardfromTechnicalCommitteeISO/TC61“Plastics“ofthe InternationalOrganizationforStandardization(ISO)hasbeentakenoverasaEuropeanStandard byTechnicalCommitteeCEN/TC249“Plastics“,thesecretariatofwhichisheldbyIBN. ThisdocumentsupersedesENISO4
15、610:1997. ThisEuropeanStandardshallbegiventhestatusofanationalstandard,eitherbypublicationofan identicaltextorbyendorsement,atthelatestbyApril2002,andconflictingnationalstandardsshall bewithdrawnatthelatestbyApril2002. AccordingtotheCEN/CENELECInternalRegulations,thenationalstandardsorganizationsoft
16、he followingcountriesareboundtoimplementthisEuropeanStandard:Austria,Belgium,Czech Republic,Denmark,Finland,France,Germany,Greece,Iceland,Ireland,Italy,Luxembourg, Netherlands,Norway,Portugal,Spain,Sweden,SwitzerlandandtheUnitedKingdom. Endorsementnotice ThetextoftheInternationalStandardISO4610:2001
17、hasbeenapprovedbyCENasaEuropean Standardwithoutanymodifications. ENISO4610:20012INTERNATIONAL STANDARD ISO 4610 Second edition 2001-10-15 Reference number ISO 4610:2001(E) Plastics Vinyl chloride homopolymer and copolymer resins Sieve analysis using air-jet sieve apparatus Plastiques Rsines dhomopol
18、ymres et copolymres de chlorure de vinyle Analyse granulomtrique sur tamiseuse dpression dair ENISO4610:2001ii DPF discliamer This FDP feli amy ctnonia ededdebm tyfep.seca In aroccecnad tiwh Asebod gnisnecil ycilop, thsi feli may be pritnde ro eivwde but sllah ton eb tideed sselnu teh tyfepseca hwic
19、h are mededdeb era licdesne to dna tsniladel on teh moctupre epfrromign the ideti.gn In odgnidaolnw this file, raptise ccatpe trehien teh serilibisnopty fo ton fnirignign sebodA gnisnecil ilopcy. The ISO tneCral Sceterarita catpecs no libaility in this aera. ebodA si a trmedarak of Adebo Stsysme Iro
20、cntarop.de teDails of teh fostware prtcudos desu to crtaee tsih PFD feli nac be fdnuo ni the Glarene Info talerive to the f;eli teh PDF-taercnoi rapmateers weer tpodezimi for pritn.gni vErey cera sah eebn tkane to rusnee ttah the feli is tiusbael for ues by ISO mrebme seidob. In teh kilnuley evtne t
21、tah a pborlme talerign to ti si f,dnuo saelpe ifnrom teh tneClar Stercearita ta the serddas givne olebw. ISO 1002 llA rithgs rresev.de Unless torehiwse sficep,dei on rapt of tihs buptacilion may be rperdecudo ro tuilidez in any form ro by nay m,snae ele-c trinoc or m,lacinahce gnidulcni tohppocoyign
22、 dna cimrfo,mli tiwtuoh repminoiss ni rwitgni fmor eitreh ISO at teh serddas olebw ro ISOs mme- reb ydob in the cuotnry fo the rtseuqeer. ISO cporythgi fofiec esaC tsopael 65 1121-HC Geneva 02 Te.l + 41 22 947 10 11 Fax + 14 22 479 09 47 E-liam copyrightsio.ch Web wwwsi.oc.h ENISO4610:2001 iii Conte
23、nts Page 1 Scope . 1 2 Normative reference . 1 3 Term and definition . 1 4 Sampling . 1 5 Sample preparation 1 6 Apparatus . 2 7 Procedure . 3 8 Expression of results 3 9 Precision . 4 10 Test report 4 ENISO4610:2001 iv Foreword ISO (the International Organization for Standardization) is a worldwide
24、 federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that
25、committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in acc
26、ordance with the rules given in the ISO/IEC Directives, Part 3. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention
27、 is drawn to the possibility that some of the elements of this International Standard may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. International Standard ISO 4610 was prepared by Technical Committee ISO/TC 61, Plastics, Subcomm
28、ittee SC 9, Thermoplastic materials. This second edition cancels and replaces the first edition (ISO 4610:1977), which has been modified as follows: emulsion-polymerized PVC has been included in the scope; a second obligatory measurement has been included; a precision statement, based on current tes
29、t data, has been included. ENISO4610:2001 ANRETNIITOLAN TSDNADRA ISO 1641002:0)E( ISO 1002 All rithgs rreseved 1 Plastics Vinyl chloride homopolymer and copolymer resins Sieve analysis using air-jet sieve apparatus 1 Scope This International Standard specifies a method for the determination of the s
30、ieve retention and particle size distribution of preferably free-flowing vinyl chloride homopolymer and copolymer resins prepared by the “suspension”, “bulk” and “emulsion” polymerization processes. Control of these characteristics can help to ensure consistency of supply and predictable processing
31、behaviour. 2 Normative reference The following normative document contains provisions which, through reference in this text, constitute provisions of this International Standard. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties
32、 to agreements based on this International Standard are encouraged to investigate the possibility of applying the most recent edition of the normative document indicated below. For undated references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain r
33、egisters of currently valid International Standards. ISO 565, Test sieves Metal wire cloth, perforated metal plate and electroformed sheet Nominal sizes of openings 3 Term and definition For the purposes of this International Standard, the following term and definition applies. 3.1 sieve retention t
34、he percentage of the mass of resin remaining on the sieve after the test 4 Sampling Take a sample which is representative of the resin as delivered and of sufficient size to permit the determination of the size distribution. Generally, shall be used for each sieve analysis. For fine-particle resins,
35、 which for the purpose of this International Standard are defined as between and , smaller quantities are more convenient, for example . 5 Sample preparation Unless otherwise agreed, analyse the sample as received (i.e. as delivered). If the sample is not analysed on the day of receipt, it shall be
36、kept in a sealed container under ambient conditions. To prevent difficulty in sieving caused by electrostatic charging of the resin, add an antistatic agent, for example by mass of -alumina, unless otherwise specified, to the resin at the start of the analysis. 25 g 80 m 100 m 10 g 0,5 % ENISO4610:2
37、00116 Apparatus 6.1 Sieves, circular, having a sieving surface corresponding to a diameter of . The sides and mesh of each sieve shall be made of metal. The mesh shall be as defined in ISO 565. The choice of mesh aperture depends on the requirements and the particle size distribution of the resin to
38、 be examined. NOTE A suitable method of cleaning sieves is to use an ultrasonic cleaning device containing water and a detergent. 6.2 Air-jet sieve apparatus (see Figure 1), consisting of a casing designed to contain a sieve (6.1), in the lower part of which are an outlet, to which suction may be ap
39、plied, and an air inlet. The casing shall be covered with a preferably transparent lid. Key 1S i e v e 2C a s i n g 3 Rotating jet 4 Air inlet 5 Manometer 6T o v a c u u m 7 Adjustable slot 8 Lid (preferably transparent) Figure 1 Air-jet sieve apparatus 200 mm ENISO4610:20012ISO 1641002:0)E( ISO 100
40、2 All rithgs rreseved 3 The air inlet shall be fitted with a rotating jet consisting of a slot-shaped nozzle arranged radially beneath and very close to the sieve, so that when in rotation it blows air continuously through the sieve to keep the particles suspended. The exhaust air pulls the finer pa
41、rticles through the sieve. The flow of air can be controlled by adjusting the working pressure, measured at the outlet; this may be achieved by means of an adjustable slot on the vacuum attachment. NOTE Apparatus of construction different from than that given in Figure 1 is allowed, provided that it
42、 has been verified that the results obtained are equivalent. 6.3 Timer (e.g. stopwatch), which indicates minutes and seconds and is equipped, if required, with a disconnecting switch for the motor of the sieve apparatus (6.2). 6.4 Balance, capable of being read to . 7 Procedure Securely fix a sieve
43、(see 6.1) into the sieve apparatus (6.2). Weigh, to the nearest , the material to be sieved, transfer it onto the sieve, and place the cover on the sieve apparatus. Regulate the flow of air to give a partial vacuum of (for example by means of the adjustable slot on the vacuum attachment see 6.2). Op
44、erate the motors of the sieve apparatus and the vacuum device for for each sieving test. If during the sieving process a deposit becomes visible under the lid, sieving shall be interrupted and the deposit brushed down onto the sieve. The accuracy and precision of the method are not as good when the
45、screen residue is small (less than , for example). In such cases it is of interest to extend the sieving time (to or even ). However, for referee (in particular for designation) purposes, the value obtained after shall be used. After switching off the motors, weigh the residue on the sieve to the ne
46、arest (for example by weighing the sieve and its contents and subtracting the tare). Repeat the procedure, as necessary, with sieves of different mesh aperture. 8 Expression of results Calculate the sieve retention , as a percentage, from the equation where is the mass, in grams, of sample used for
47、the analysis; is the mass, in grams, of the residue on the sieve. Report the result to one decimal place. 0,01 g 0,1 g 2,5 kPa 4 min 15 s 5% 10 min 15 min 4 min 15 s 0,1 g R R = m 1 m 0 100 m 0 m 1 ENISO4610:20013ISO :0164(1002)E 4 ISO 1002 All rithgs rreseved 9P r e c i s i o n Interlaboratory tria
48、ls were conducted on four resins (including suspension homopolymer, emulsion homopolymer and graft copolymer) in five laboratories. For standard suspension resins, the repeatability standard deviation (within the same laboratory) and the reproducibility standard deviation (among different laboratories) are as given in Ta b l e 1 . The full report on the round robin can be consulted at the following website
