1、BRITISH STANDARD BS EN ISO 11542-1:2001 Incorporating Corrigendum No. 1 Plastics Ultra-high- molecular-weight polyethylene (PE-UHMW) moulding and extrusion materials Part 1: Designation system and basis for specifications The European Standard EN ISO 11542-1:2001 has the status of a British Standard
2、 ICS 83.080.20 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBS EN ISO 11542-1:2001 This British Standard, having been prepared under the direction of the Sector Committee for Materials and Chemicals, was published under the authority of the Standards Committee and comes into
3、 effect on 15 July 2001 BSI 24 January 2002 ISBN 0 580 37864 0 National foreword This British Standard is the official English language version of EN ISO 11542-1:2001. It is identical with ISO 11542-1:2001. It supersedes BS ISO 11542-1:1994 which is withdrawn. The UK participation in its preparation
4、 was entrusted to Technical Committee PRI/82, Thermoplastic materials, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is drawn to the fact that CEN and CENELEC Standards normally include a
5、n annexe which lists normative references to international publications with their corresponding European publications. The British Standards which implement these international or European publications may be found in the BSI Standards Catalogue under the section entitled “International Standards C
6、orrespondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard doe
7、s not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European devel
8、opments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO Foreword page, the ISO title page, pages ii and iii, a blank page, pages 1 to 7, the Annex ZA page, an inside back cover and a back cover. The BSI c
9、opyright date displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date Comments 13644 Incorporating Corrigendum No.1 24 January 2002 Corrected the EN ISO foreword and inserted the Annex ZA page.EUROPEANSTANDARD NORMEEUROPENNE EUROPISCH
10、ENORM ENISO115421 February2001 ICS83.080.20 Englishversion PlasticsUltrahighmolecularweightpolyethylene(PEUHMW) mouldingandextrusionmaterialsPart1:Designationsystem andbasisforspecifications(ISO115421:2001) PlastiquesMatriauxbasedepolythylnetrshaute massemolculaire(PEUHMW)pourmoulageetextrusion Part
11、ie1:Systmededsignationetbasede spcifications(ISO115421:2001) ThisEuropeanStandardwasapprovedbyCENon15February2001. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusofanationalstandardwithoutanyalteration.Uptodatelistsan
12、dbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheManagementCentreortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation undertheresponsibilityofaCENmemberintoitsownlanguageandnot
13、ifiedtotheManagementCentrehasthesamestatusasthe official versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,CzechRepublic,Denmark,Finland,France,Germany,Greece, Iceland,Ireland,Italy,Luxembourg,Netherlands,Norway,Portugal,Spain,Sweden,SwitzerlandandUnitedKingdom. EUROPEANCOMMITTEEFOR
14、STANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:ruedeStassart,36B1050Brussels 2001CEN Allrightsofexploitationinanyformandbyanymeansreserved worldwideforCENnationalMembers. Ref.No.ENISO115421:2001EForeword ThetextoftheInternationalStandardISO115421:2001hasbeen
15、preparedbyTechnical CommitteeISO/TC61“Plastics“incollaborationwithTechnicalCommitteeCEN/TC249 “Plastics“,thesecretariatofwhichisheldbyIBN. ThisEuropeanStandardshallbegiventhestatusofanationalstandard,eitherbypublication ofanidenticaltextorbyendorsement,atthelatestbyAugust2001,andconflictingnational
16、standardsshallbewithdrawnatthelatestbyAugust2001. AccordingtotheCEN/CENELECInternalRegulations,thenationalstandardsorganizationsof thefollowingcountriesareboundtoimplementthisEuropeanStandard:Austria,Belgium, CzechRepublic,Denmark,Finland,France,Germany,Greece,Iceland,Ireland,Italy, Luxembourg,Nethe
17、rlands,Norway,Portugal,Spain,Sweden,SwitzerlandandtheUnited Kingdom. Endorsementnotice ThetextoftheInternationalStandardISO115421:2001wasapprovedbyCENasa EuropeanStandardwithoutanymodification. NOTE:NormativereferencestoInternationalStandardsarelistedinannexZA(normative). ENISO115421:2001 Reference
18、number ISO 11542-1:2001(E) INTERNATIONAL STANDARD ISO 11542-1 Second edition 2001-02-15 Plastics Ultra-high-molecular-weight polyethylene (PE-UHMW) moulding and extrusion materials Part 1: Designation system and basis for specifications Plastiques Matriaux base de polythylne trs haute masse molculai
19、re (PE-UHMW) pour moulage et extrusion Partie 1: Systme de dsignation et base de spcifications ENISO115421:2001 ISO -245111:(1002E) t ii ENISO115421:2001 ISO -245111:(1002E)iii Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (I
20、SO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, gov
21、ernmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC
22、 Directives, Part 3. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of t
23、he elements of this part of ISO 11542 may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. International Standard ISO 11542-1 was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials. This sec
24、ond edition cancels and replaces the first edition (ISO 11542-1:1994), which has been technically revised. The major change is that density has been replaced by Charpy notched impact strength as one of the designatory properties. ISO 11542 consists of the following parts, under the general title Pla
25、stics Ultra-high-molecular-weight polyethylene (PE-UHMW) moulding and extrusion materials: Part 1: Designation system and basis for specifications Part 2: Preparation of test specimens and determination of properties ENISO115421:2001 ENISO115421:2001 INTENRATIONAL TSANDADR ISO -245111:(1002E)1 Plast
26、ics Ultra-high-molecular-weight polyethylene (PE-UHMW) moulding and extrusion materials Part 1: Designation system and basis for specifications 1 Scope 1.1 This part of ISO 11542 establishes a system of designation for PE-UHMW thermoplastic materials which may be used as the basis for specifications
27、. For the purposes of this part of ISO 11542, PE-UHMW materials are polyethylene materials having a melt mass- flow rate (MFR), measured at 190 C and 21,6 kg load, of less than 0,1 g/10 min. 1.2 The types of PE-UHMW are differentiated from each other by a classification system based on appropriate l
28、evels of the designatory properties a) viscosity number b) elongational stress c) Charpy notched impact strength and on information about intended application and/or method of processing, important properties, additives, colorants, fillers and reinforcing materials. 1.3 This part of ISO 11542 is app
29、licable to all PE-UHMW homopolymers and to ultra-high-molecular-weight copolymers of ethylene having a content of other 1-olefinic monomers of less than 50 % by mass and a content of non-olefinic monomers with functional groups up to a maximum of 3 % by mass. It applies to materials ready for normal
30、 use in the form of powder, granules or pellets and to materials unmodified or modified by colorants, additives, fillers, etc. 1.4 It is not intended to imply that materials having the same designation give necessarily the same performance. This part of ISO 11542 does not provide engineering data, p
31、erformance data or data on processing conditions which may be required to specify a material for a particular application and/or method of processing. If such additional properties are required, they shall be determined in accordance with the test methods specified in part 2 of this International St
32、andard, if suitable. 1.5 In order to specify a thermoplastic material for a particular application or to ensure reproducible processing, additional requirements may be given in data block 5 (see 3.1). 2 Normative references The following normative documents contain provisions which, through referenc
33、e in this text, constitute provisions of this part of ISO 11542. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties to agreements based on this part of ISO 11542 are encouraged to investigate the ENISO115421:2001 ISO -245111:(100
34、2E) 2 possibility of applying the most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain registers of currently valid International Standards. ISO 1043-1: 1) , Plastics
35、 Symbols and abbreviated terms Part 1: Basic polymers and their special characteristics. ISO 1628-3:1991, Plastics Determination of viscosity number and limiting viscosity number Part 3: Polyethylenes and polypropylenes. ISO 5834-1:1998, Implants for surgery Ultra-high molecular weight polyethylene
36、Part 1: Powder form. ISO 11542-2:1998, Plastics Ultra-high-molecular-weight polyethylene (PE-UHMW) moulding and extrusion materials Part 2: Preparation of test specimens and determination of properties. 3 Designation system 3.1 General The designation system for thermoplastics is based on the follow
37、ing standardized pattern: Designation Identity block Individual-item block Description block (optional) International Standard number block Data block 1 Data block 2 Data block 3 Data block 4 Data block 5 The designation consists of an optional description block, reading “Thermoplastics“, and an ide
38、ntity block comprising the International Standard number and an individual-item block. For unambiguous coding, the individual-item block is subdivided into five data blocks comprising the following information: Data block 1: Identification of the plastic by its symbol PE-UHMW in accordance with ISO
39、1043-1 (see 3.2). Data block 2: Position 1: Intended application or method of processing (see 3.3). Positions 2 to 8: Important properties, additives and supplementary information (see 3.3). Data block 3: Designatory properties (see 3.4). Data block 4: Fillers or reinforcing materials and their nomi
40、nal content (see 3.5). Data block 5: For the purpose of specifications, a fifth data block may be added containing additional information (see 3.6). The first character of the individual-item block shall be a hyphen. The data blocks shall be separated from each other by commas. If a data block is no
41、t used, this shall be indicated by doubling the separation sign, i.e. by two commas (,). 1) To be published. (Revision of ISO 1043-1:1997) ENISO115421:2001 ISO -245111:(1002E)3 3.2 Data block 1 In this data block, after the hyphen, PE-UHMW plastics are identified by the symbol PE-UHMW, in accordance
42、 with ISO 1043-1. 3.3 Data block 2 In this data block, information about intended application and/or method of processing is given in position 1 and information about important properties, additives and colour in positions 2 to 8. The code-letters used are specified in Table 1. If information is pre
43、sented in positions 2 to 8 and no specific information is given in position 1, the letter X shall be inserted in position 1. Table 1 Code-letters used in data block 2 Code-letter Position 1 Code-letter Positions 2 to 8 A Processing stabilized C Coloured D Powder E Extrusion E Expandable F Extrusion
44、of films F Special burning characteristics G General use G Granules H Heat aging stabilized K Metal deactivated L Light or weather stabilized M Moulding N Natural (no colour added) Q Compression moulding R Mould release agent S Sintering S Lubricated X No indication X No indication Y Textile yarns,
45、spinning Y Increased electrical conductivity Z Antistatic 3.4 Data block 3 3.4.1 General In this data block, the range of the viscosity number is represented by a single-figure code-number (see 3.4.2), the elongational stress by a single-figure code-number (see 3.4.3), and the Charpy notched impact
46、strength by a single-figure code-number (see 3.4.4). The code-numbers are separated from each other by hyphens. ENISO115421:2001 ISO -245111:(1002E) 4 If a property value falls on or near a range limit, the manufacturer shall state which range will designate the material. If subsequent individual te
47、st values lie on, or either side of, the limit because of manufacturing tolerances, the designation is not affected. NOTE Not all combinations of the values of the designatory properties may be possible for currently available polymers. 3.4.2 Viscosity number The viscosity number shall be determined
48、 in accordance with ISO 1628-3, using a nitrogen atmosphere. The possible values of viscosity number are divided into six ranges, each represented by a single-figure code- number, as specified in Table 2. Only materials with code-numbers 1 to 5 in Table 2 shall be used if the abrasion resistance of the material is important to the application. Table 2 Ranges of viscosity number in data block 3 C