1、BS EN ISO14419:2010ICS 59.080.01NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDTextiles Oilrepellency Hydrocarbonresistance test (ISO14419:2010)This British Standardwas published under theauthority of the StandardsPolicy and StrategyCommittee on 31 March2010 BS
2、I 2010ISBN 978 0 580 68538 5Amendments/corrigenda issued since publicationDate CommentsBS EN ISO 14419:2010National forewordThis British Standard is the UK implementation of EN ISO 14419:2010.It supersedes BS EN ISO 14419:1999 which is withdrawn.The UK participation in its preparation was entrusted
3、to TechnicalCommittee TCI/24, Physical testing of textiles.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Users are responsible for its correct application.Compli
4、ance with a British Standard cannot confer immunityfrom legal obligations.EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 14419 March 2010 ICS 59.080.01 Supersedes EN ISO 14419:1999English Version Textiles - Oil repellency - Hydrocarbon resistance test (ISO 14419:2010) Textiles - Olofugatio
5、n - Essai de rsistance aux hydrocarbures (ISO 14419:2010) Textilien - Oleophobie - Prfung der lbestndigkeit mit Hilfe von Kohlenwasserstoffen (ISO 14419:2010) This European Standard was approved by CEN on 6 February 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations whic
6、h stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European St
7、andard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national
8、standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland
9、and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO
10、14419:2010: EBS EN ISO 14419:2010EN ISO 14419:2010 (E) 3 Foreword This document (EN ISO 14419:2010) has been prepared by Technical Committee ISO/TC 38 “Textiles“ in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products”, the secretariat of which is held by BSI. This Europe
11、an Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2010, and conflicting national standards shall be withdrawn at the latest by September 2010. Attention is drawn to the possibility that some of the e
12、lements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 14419:1999. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the fol
13、lowing countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slo
14、vakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 14419:2010 has been approved by CEN as a EN ISO 14419:2010 without any modification. BS EN ISO 14419:2010ISO 14419:2010(E) ISO 2010 All rights reserved iiiContents Page Foreword iv 1 Scope1 2 Norma
15、tive references1 3 Terms and definitions .1 4 Principle2 5 Safety precautions 2 6 Reagents.2 7 Apparatus.3 8 Test specimens3 9 Procedure.3 10 Evaluation.4 11 Evaluation of results .4 12 Test report5 Annex A (informative) Precision and bias statement6 Bibliography7 BS EN ISO 14419:2010ISO 14419:2010(
16、E) iv ISO 2010 All rights reservedForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body int
17、erested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnic
18、al Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the
19、technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights.
20、ISO shall not be held responsible for identifying any or all such patent rights. ISO 14419 was prepared by Technical Committee ISO/TC 38, Textiles, Subcommittee SC 2, Cleansing, finishing and water resistance tests. This second edition cancels and replaces the first edition (ISO 14419:1998), of whic
21、h it constitutes a minor revision. It also incorporates Technical Corrigendum ISO 14419:1998/Cor.1:2004. BS EN ISO 14419:2010INTERNATIONAL STANDARD ISO 14419:2010(E) ISO 2010 All rights reserved 1Textiles Oil repellency Hydrocarbon resistance test 1 Scope This International Standard is applicable to
22、 the evaluation of a substrates resistance to absorption of a selected series of liquid hydrocarbons of different surface tensions. This International Standard is intended to provide a guide to oil stain resistance. It can provide a rough index of oil stain resistance as, generally, the higher the o
23、il repellency grade, the better resistance to staining by oily materials, especially liquid oil substances. This is particularly true when comparing various finishes for a given substrate. This International Standard can also be utilized in determining if washing and/or drycleaning treatments have a
24、ny adverse effect on the oil repellency characteristics of a substrate. NOTE 1 Washing and drycleaning treatment procedures are described in ISO 6330 or ISO 3175 (all parts), respectively. This International Standard is not intended to give an absolute measure of the resistance of the substrate to s
25、taining by all oily materials. Other factors, such as composition and viscosity of the oily substances, substrate construction, fibre type, dyes and other finishing agents, also influence stain resistance. This International Standard is not intended to estimate the resistance to penetration of the s
26、ubstrate by oil-based chemicals. NOTE 2 For the evaluation of the resistance to penetration of the substrate by oil-based chemicals, see ISO 6530. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition
27、cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 139, Textiles Standard atmospheres for conditioning and testing 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 grade
28、 symbol for any step of a multistep standard reference scale for a quality characteristic NOTE The grade is assigned to test specimens exhibiting a degree of the quality comparable to that step of the standard reference scale. 3.2 oil repellency characteristic of a fabric whereby it resists absorpti
29、on of oily liquids BS EN ISO 14419:2010ISO 14419:2010(E) 2 ISO 2010 All rights reserved4 Principle Drops of standard test liquids, consisting of a selected series of hydrocarbons with different surface tensions, are placed on the substrate surface and then observed for absorption, wicking and contac
30、t angle. The oil repellency grade is the highest numbered test liquid which is not absorbed by the substrate surface. 5 Safety precautions SAFETY PRECAUTIONS These safety precautions are for information purposes only. The precautions are ancillary to the testing procedures and are not intended to be
31、 all inclusive. It is the users responsibility to use safe and proper techniques in handling materials in this International Standard. Manufacturers should be consulted for specific detail such as material safety data sheets and other manufacturers recommendations. 5.1 Good laboratory practices shou
32、ld be followed. Wear safety glasses and impervious gloves when handling test liquids in all laboratory areas. 5.2 Some of the hydrocarbons specified in this International Standard are flammable. Keep away from heat, sparks and open flame. Use with adequate ventilation. Avoid prolonged breathing of v
33、apour or contact with skin. Do not take internally. 6 Reagents All reagents shall be of a suitable analytical grade. Ensure the standard test liquids are used and stored at a temperature of (20 2) C. All reagents and standard test liquids have a maximum shelf life of three years. 6.1 Test liquids, p
34、repared and numbered according to Table 1. The purity of test liquids affects surface tension of the liquid. Use only analytical grades of test liquids. 6.2 White mineral oil, USP white mineral oil 340-355 SSU at 37,8 C with Saybolt colour +30. Table 1 Standard test liquids Composition Oil test liqu
35、id number Density Surface tension kg/l N/m at 25 C None (fails with white mineral oil) 0 White mineral oil 1 0,84 0,87 0,031 5 65:35 white mineral oil: n-hexadecane by volume 2 0,82 0,029 6 n-hexadecane 3 0,77 0,027 3 n-tetradecane 4 0,76 0,026 4 n-dodecane 5 0,75 0,024 7 n-decane 6 0,73 0,023 5 n-o
36、ctane 7 0,70 0,021 4 n-heptane 8 0,69 0,019 8 BS EN ISO 14419:2010ISO 14419:2010(E) ISO 2010 All rights reserved 37 Apparatus 7.1 Dropping bottles, each marked with the appropriate oil test liquid number, to which, for convenience, it is desirable to transfer the test liquids from stock solutions. A
37、 typical system found useful consists of 60 ml dropping bottles with ground-in pipettes and neoprene bulbs. Prior to use, the bulbs should be soaked in heptane for several hours and then rinsed in fresh heptane to remove soluble substances. It has been found helpful to place the test liquids in sequ
38、ential order on a wooden platform on the grading table. 7.2 White textile blotting paper, of approximately (0,71 0,1) mm in thickness, weight of (370 5 %) g/m2and an absorbent capacity of (220 30) %.1)7.3 Laboratory gloves of general purpose are sufficient. 8 Test specimens Three test specimens of a
39、pproximately 20 cm 20 cm are needed. Test specimen size should be chosen to represent all physical and colour characteristics of the fabric and allow ample room for testing. Condition the test specimens for a minimum of 4 h at (20 2) C and (65 4) % RH prior to testing. See ISO 139. 9 Procedure 9.1 P
40、lace the first test specimen flat on the white textile blotting paper (7.2) on a smooth, horizontal surface with the face side on top. Testing should be conducted in standard atmosphere for testing in accordance with ISO 139. Testing should be completed within 30 min, if test specimens are removed f
41、rom a conditioning chamber. 9.1.1 When evaluating open-weave or “thin” substrates, place the test specimen on at least two layers of the substrate; otherwise, the test liquid can wet the underlying surface, not the actual test substrate, and thereby cause confusion in the reading of the results. 9.1
42、.2 Equipment, benches and gloves should be free of silicone. Use of silicone-containing products could adversely affect oil repellency grades. 9.2 Wearing clean laboratory gloves (7.3), brush the pile of napped or pile substrates using the hand, in the direction giving the greatest lay of the surfac
43、e prior to placing the drops of the test liquid. (The direction giving the lowest pile.) 9.3 Beginning with the lowest-numbered test liquid (oil test liquid No. 1), carefully place small drops (approximately 5 mm in diameter or 0,05 ml volume) on the test specimen in a minimum of five locations repr
44、esenting all physical and colour characteristics of the fabric. The drops should be approximately 4,0 cm apart. The dropper tip should be held at a height of approximately 0,6 cm from the substrate surface while placing drops. Do not touch the substrate with the dropper tip. Observe the drops for (3
45、0 2) s from approximately a 45 angle. Assess each drop in accordance with Figure 1. Immediately examine the reverse of the fabric for any wetting. 1) White Textile Blotting Paper is the trade name of a product supplied by the American Association of Textile Chemists and Colorists (AATCC), P.O. Box 1
46、2215, Research Triangle Park, NC 27709-2215. This information is given for the convenience of users of this International Standard and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if they can be shown to lead to the same results. BS EN ISO 14419:201
47、0ISO 14419:2010(E) 4 ISO 2010 All rights reserved9.4 If no penetration or wetting of the substrate at the liquidsubstrate interface and also no wicking around the drops occur, place drops of the next high-numbered test liquid at an adjacent site on the substrate so as not to interfere with the previ
48、ous test and again observe for (30 2) s. Assess each drop in accordance with Figure 1. Immediately examine the reverse of the fabric for any wetting. 9.5 Continue this procedure until one of the test liquids shows obvious wetting or wicking of the substrate under or around the drop within (30 2) s.
49、A maximum of six tests (oil test liquids) may be performed on one test specimen. 9.6 Repeat the procedure with the second sample. A third sample may be required (see Clause 11). 10 Evaluation 10.1 The oil repellency grade of a substrate is the numerical value of the highest-numbered test liquid which will not wet the substrate within a period of (30 2) s. A grade of zero (0) is assigned when the substrate fails the white mineral oil liquid test. Wetting of the substrate is normally evidenced by a darkening
