1、September 2017 DIN-Normenausschuss Sicherheitstechnische Grundstze (NASG)Preisgruppe 13DIN Deutsches Institut fr Normung e. V. Jede Art der Vervielfltigung, auch auszugsweise, nur mit Genehmigung des DIN Deutsches Institut fr Normung e. V., Berlin, gestattet.ICS 13.040.30Zur Erstellung einer DIN SPE
2、C knnen verschiedene Verfahrensweisen herangezogen werden: Das vorliegende Dokument wurde nach den Verfahrensregeln eines Fachberichts erstellt.!%h9R“2692247www.din.deDIN CEN/TR 17055Exposition am Arbeitsplatz Messung von chemischen Arbeitsstoffen, welche die Anforderungen nach EN 482sowie nach eine
3、r von EN 838, EN 1076, EN 13205, EN 13890 und EN 13936 erfllen Auswahl von Verfahren;Englische Fassung CEN/TR 17055:2017Workplace exposure Measurement of chemical agents complying with the requirements given in EN 482 and eitherone of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936 Choice of proced
4、ures;English version CEN/TR 17055:2017Exposition sur les lieux de travail Mesurage des agents chimiques conformment aux exigences spcifies dans lEN 482 et danslune des normes EN 838, EN 1076, EN 13205, EN 13890 et EN 13936 Choix des modes opratoires;Version anglaise CEN/TR 17055:2017Alleinverkauf de
5、r Spezifikationen durch Beuth Verlag GmbH, 10772 Berlin www.beuth.deGesamtumfang 28 SeitenDIN SPEC 33890 DDIN CEN/TR 17055 (DIN SPEC 33890):2017-09 2 Nationales Vorwort Dieses Dokument enthlt die englische Referenzfassung des CEN Technischen Berichts CEN/TR 17055:2017, der vom Technischen Komitee CE
6、N/TC 137 Bewertung der chemischen und biologischen Stoffbelastung am Arbeitsplatz (Sekretariat: DIN, Deutschland) des Europischen Komitees fr Normung (CEN) erarbeitet wurde. Das zustndige deutsche Gremium ist der Arbeitsausschuss NA 095-03-01 AA Messstrategien und Anforderungen an Messverfahren“ des
7、 DIN-Normenausschusses Sicherheitstechnische Grundstze (NASG). Es wird auf die Mglichkeit hingewiesen, dass einige Texte dieses Dokuments Patentrechte berhren knnen. Das DIN und/oder die DKE sind nicht dafr verantwortlich, einige oder alle diesbezglichen Patentrechte zu identifizieren. Es wurde kein
8、e deutsche Sprachfassung erstellt, weil in den deutschen Fachkreisen die englische Referenzfassung verwendet wird. TECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHER BERICHT CEN/TR 17055 February 2017 ICS 13.040.30 English Version Workplace exposure Measurement of chemical agents complying with the requ
9、irements given in EN 482 and either one of EN 838, EN 1076, EN 13205, EN 13890 and EN 13936 Choice of procedures Exposition sur les lieux de travail Mesurage des agents chimiques conformment aux exigences spcifies dans lEN 482 et dans lune des normes EN 838, EN 1076, EN 13205, EN 13890 et EN 13936 C
10、hoix des modes opratoires Exposition am Arbeitsplatz Messung von chemischen Arbeitsstoffen, welche die Anforderungen nach EN 482 sowie nach einer von EN 838, EN 1076, EN 13205, EN 13890 und EN 13936 erfllen Auswahl von Verfahren This Technical Report was approved by CEN on 9 January 2017. It has bee
11、n drawn up by the Technical Committee CEN/TC 137. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuan
12、ia, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix
13、17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 17055:2017 ECEN/TR 17055:2017 (E) 2 Contents Page European foreword 3 Introduction 4 1 Scope 5 2 Measuring procedures . 5 2.1 General 5 2.2 Selection of c
14、hemical agents 5 3 Method lists 6 3.1 General 6 3.2 Origin of the measuring procedure . 6 3.3 Structure of the method lists . 9 4 Evaluation of measuring procedures . 10 4.1 General 10 4.2 Rating . 10 4.3 Downgrade of a rating . 13 4.4 Expanded uncertainty 13 (informative) Selection of chemical agen
15、ts related to 2.2 14 Anhang A(informative) Examples of method lists 18 Anhang BBibliography . 26 DIN CEN/TR 17055 (DIN SPEC 33890):2017-09 CEN/TR 17055:2017 (E) 3 European foreword This document (CEN/TR 17055:2017) has been prepared by Technical Committee CEN/TC 137 “Assessment of workplace exposure
16、 to chemical and biological agents”, the secretariat of which is held by DIN. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. DIN CEN/TR 17055 (DIN S
17、PEC 33890):2017-09 CEN/TR 17055:2017 (E) 4 Introduction Article 3 (10) of the Chemical Agents Directive 98/24/EC 1 called for suitable analytical methods for hazardous substances in workplace atmospheres. However, CEN/TC 137 has adopted a significantly different strategy of standardization which has
18、 not involved preparation of separate European Standards for measuring procedures. Instead, CEN/TC 137 has developed several European Standards that present general requirements for measuring procedures and which are used to test whether measuring procedures meet these requirements. A measuring proc
19、edure that fulfils these requirements is suitable for the measurement of hazardous substances in workplace atmospheres in the sense of Directive 98/24/EC. To fulfil the demand of Directive 98/24/EC it is necessary to find out whether measuring procedures are available that meet the requirements of t
20、he European Standards elaborated by CEN/TC 137. Several EU Members have committees or organisations which issue measuring procedures. Furthermore, for example, the US National Institute for Occupational Safety and Health (NIOSH) and other institutions of Non-EU-Members publish suitable measuring pro
21、cedures. The main aim of this CEN Technical Report is to check whether these measuring procedures fulfil the requirements of EN 482. EN 482 is one of the basic standards elaborated by CEN/TC 137. Whereas, its first edition was already published in 1994, the second edition was published in 2006 subse
22、quent to a major revision that took the principles on laid down in ISO/IEC Guide 98-3 (GUM). As consequence of the issue of the revised EN 482 in 2006 its “daughter standards” EN 838, EN 1076, EN 13890 and EN 13936 needed to be revised fundamentally, too. In 2012, a third edition of EN 482 was publi
23、shed taking into account the changes introduced to its daughter standards during their revisions. In 2015, EN 482 has been amended by introducing a new sub-clause dealing with chemical agents with low limit values and republished as fourth edition of EN 482 consolidated with its Amendment 1. The “ma
24、jor revision” of EN 482 was one main task of the European project “Analytical methods for chemical agents” funded by the Commission under the Mandate BC/CEN/EN/TR 000/2002-16. The second part of this project was the selection and examination of existing measuring procedures. The European project rep
25、ort comprises measuring procedures for 126 high profile hazardous substances. The measuring procedures were listed in “methods sheets” and selected (analytical) methods were rated with regard to the requirements of the first edition of EN 482 published in 1994. To make these lists and method sheets
26、easily accessible, a database was established and made publicly available on the IFA homepage designated as “GESTIS - Analytical methods” 2. From todays point of view, the lists and method sheets are no longer up to date. For some chemical agents the occupational exposure limit values have changed i
27、n recent years. Additionally, in the meantime several new measuring procedures have been published which base on the requirements of subsequent editions of EN 482. For those reasons, it was decided to update the database “Analytical methods for chemical agents” accordingly. DIN CEN/TR 17055 (DIN SPE
28、C 33890):2017-09 CEN/TR 17055:2017 (E) 5 1 Scope This CEN Technical Report describes how the measuring procedures for chemical agents complying with the requirements given in EN 482 and either one of EN 838, EN 1076, EN 13890, EN 13936 and/or the EN 13205 series, as far as applicable, have been chos
29、en. This document refers on the selection of chemical agents and related substance groups and the establishment of corresponding method lists. It describes the evaluation of available measuring procedures in order to select for a particular chemical agent the most appropriate one. This document is a
30、lso intended to: provide a means to compare for a given chemical agent a new measuring procedure with those listed in the database GESTIS Analytical methods 2; to evaluate and rate a given measuring procedure (from an accepted source) for a given chemical agent not yet selected in the database GESTI
31、S Analytical methods 2. 2 Measuring procedures 2.1 General Measuring procedures (“analytical methods”) for chemical agents in workplace atmospheres are available from many sources. In Europe, for example in France, Germany, Spain and UK “official” measuring procedures for workplace atmospheres are p
32、ublished. Furthermore, a number of International Standards have been promulgated the use in this field, but the most important sources of measuring procedures from countries outside Europe are those published by OSHA and NIOSH. 2.2 Selection of chemical agents Further surveys show that there are abo
33、ut 2000 different chemical agents, mixtures and preparations with existing limit values in Europe 3. Beyond, many so called “derived no-effect levels” (DNELs) have been published by the European Chemical Agency (ECHA) since 2010 4. It is far beyond the application range of the database to select mea
34、suring procedures for all chemical agents with a limit value. In any case for many chemical agents no measuring procedure exists. Furthermore, due to the very specific problems of fibre measurements and measurements of nanoparticles, no procedures for these chemical agents are listed. The selection
35、of chemical agents is based mainly on the number of measurements carried out in France and Germany. Both countries have similar databases for measurements in workplace atmospheres, and in both countries several hundred thousand measurements have been performed since the early 1970s 5, 6. These datab
36、ases give a very good overview about chemical agents of high priority. The chemical agents for the method lists are mainly selected from that group of chemical agents which remained more or less unchanged since 2006, and a few other criteria: high number of measurements; high profile substances (e.g
37、. diesel fume); EU limit value and a reasonable number of measurements; limit values in most countries of the EU. DIN CEN/TR 17055 (DIN SPEC 33890):2017-09 CEN/TR 17055:2017 (E) 6 The following substances or groups of chemical agents were selected: a) aerosols inhalable and respirable dust; crystall
38、ine silica; diesel fume; metal working fluids/oil mist. b) metals Ag, As, Ba-soluble, Be, Cd, Co, Cr, Cr (VI), Cu, Hg, Mn, Ni, Ni-soluble, Pb, Sb, Sn. c) Organic substances Acetonitrile, Acrylates, Alcohols, Aldehydes, Aliphatic amines, Aliphatic ester alcohols, Aliphatic ethers, Alkanolamines, N-Al
39、kyl-2-pyrrolidons, Amides, Chlorinated aromatic hydrocarbons, Cresols, Cyclic ethers, hydrocarbons (aliphatic, aromatic, cyclic), Esters, Glycol esters, Halogenated hydrocarbons (aliphatic), Isocyanates, Ketones (aliphatic and cyclic), Organic acids, Oxiranes, Phenol d) Gases CO, CO2, NH3, N2O, NO,
40、NO2, PH3, SO2, halogens e) Inorganic acids and alkaline substances Hydrogen cyanide and Cyanides, Hydrogen fluoride and fluorides, Hydroxides, Particulate inorganic acids and anhydrides, Volatile inorganic acids A list of the chemical agents selected for the database GESTIS Analytical methods 2 is g
41、iven in Annex A. 3 Method lists 3.1 General After selection of chemical agents and related substance groups the basic requirements given in 3.2 are specified. 3.2 Origin of the measuring procedure The following criteria are taken into account for the compilation of the measuring procedures: a) The m
42、easuring procedure is examined by an independent group and has already been published in another set of (measuring) procedures for measurements in workplace atmospheres. b) The measuring procedure has been designed for personal exposure measurement and requires the use of a personal sampler. c) Meas
43、uring procedures either using static (area) sampling only or developed for ambient air are excluded from further considerations. The accepted sources are listed in Table 1. DIN CEN/TR 17055 (DIN SPEC 33890):2017-09 CEN/TR 17055:2017 (E) 7 Table 1 Accepted sources of methods for workplace air measure
44、ments Abbreviation Language Source Web address EN English (French/ German) European Organization for Standardization (CEN), CEN-CENELEC Management Centre Avenue Marnix 17, B-1000 Brussels, Belgium European Standards Also available from National Standards Bodies, e.g. AFNOR, AENOR, BSI, DIN, SIS etc.
45、 http:/www.cen.eu/ with costs ISO English (French) International Organization for Standardization (ISO), ISO Central Secretariat Chemin de Blandonnet 8, Case Postale 401 CH-1214 Vernier, Geneva, Switzerland: International Standards Also available from National Standards Bodies, e.g. AFNOR, AENOR, BS
46、I, DIN, SIS etc. http:/www.iso.org with costs DGUV I German Deutsche Gesetzliche Unfallversicherung (DGUV): Von den Berufsgenossenschaften anerkannte Analysenverfahren zur Feststellung der Konzentration krebserzeugender Arbeitsstoffe in der Luft in Arbeitsbereichen 83 methods since 1983 (some method
47、s are published in DFG (E) http:/publikationen.dguv.de/dguv/udt_dguv_main.aspx?QPX=TUlEPSZDSUQ9MTAwNzI6U0cjR2VmYWhyc3RvZmZl for free IFA German Institut fr Arbeitsschutz der Deutschen Gesetzlichen Unfallversicherung IFA-Arbeitsmappe, Messung von Gefahrstoffen, Sankt Augustin. Erich Schmidt Verlag, B
48、erlin, Loose leaf edition, 50 supplements since 1988 http:/bgia-arbeitsmappedigital.de/login.html with costs DFG (D) German Deutsche Forschungsgemeinschaft (DFG): Analytische Methoden zur Prfung gesundheitsschdlicher Arbeitsstoffe Luftanalysen, Ed. H. Greim, Wiley-VCH, Weinheim, Germany Loose leaf e
49、dition, 18 supplements since 1976 http:/ for free DIN CEN/TR 17055 (DIN SPEC 33890):2017-09 CEN/TR 17055:2017 (E) 8 Abbreviation Language Source Web address DFG (E) English Deutsche Forschungsgemeinschaft (DFG): Analyses of Hazardous Substances in Air, Wiley-VCH. Weinheim, New York http:/ for free MDHS English Health and Safety Laboratory (HSL), Harpur Hill, Buxton,
