1、May 2015 Translation by DIN-Sprachendienst.English price group 13No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 71
2、.100.80!%B_b“2316063www.din.deDDIN EN 15030Chemicals used for treatment of water intended for humanconsumption Silver salts for intermittent use;English version EN 15030:2012+A1:2015,English translation of DIN EN 15030:2015-05Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch Silbersa
3、lze fr den nicht systematischen Gebrauch;Englische Fassung EN 15030:2012+A1:2015,Englische bersetzung von DIN EN 15030:2015-05Produits chimiques utiliss pour le traitement de leau destine la consommationhumaine Sels dargent pour usage intermittent;Version anglaise EN 15030:2012+A1:2015,Traduction an
4、glaise de DIN EN 15030:2015-05SupersedesDIN EN 15030:2013-01www.beuth.deDocument comprises 24 pagesIn case of doubt, the German-language original shall be considered authoritative.04.15 DIN EN 15030:2015-05 2 A comma is used as the decimal marker. National foreword This document (EN 15030:2012+A1:20
5、15) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the DIN-Normenausschuss Wasserwesen (DIN Standards Committee Water Practice), Working Committee NA 119-07-04-01 UA Aufbereitungsstoffe und
6、-anlagen. Users of this standard are advised of the reservations stated in the Introduction of the European Standard and should note that national regulations exist in Germany dealing with water for human consumption, in particular the Trinkwasserverordnung (TrinkwV 2001) (German Drinking Water Ordi
7、nance). The DIN Standards corresponding to the International Standards referred to in this document are as follows, whereby EN ISO Standards are only listed below if these have not been published as DIN EN ISO Standards with the same number: EN ISO 3696 DIN ISO 3696 Amendments This standard differs
8、from DIN EN 15030:2013-01 as follows: a) the scope has been extended to include silver chloride; b) limits for the impurities gold, iridium, palladium, platinum, rhodium and ruthenium have been deleted; c) specifications relating to the means of delivery and storage of the products have been revised
9、; d) specifications on pictograms and hazard statements have been corrected; e) specifications relating to the treatment dose have been supplemented; f) information relating to secondary effects has been corrected; g) Annex B “General rules relating to safety” has been revised; h) the Bibliography h
10、as been updated. Previous editions DIN EN 15030: 2006-06, 2013-01 DIN EN 15030 Corrigendum 1: 2009-12 DIN EN 15030:2015-05 3 National Annex NA (informative) Bibliography DIN ISO 3696, Water for analytical laboratory use Specification and test methods Verordnung ber die Qualitt von Wasser fr den mens
11、chlichen Gebrauch (Trinkwasserverordnung TrinkwV 2001) (German Drinking Water Ordinance), as of 02 August 2013 (BGBI. (German Federal Law Gazette) I, 2013, no. 46, pp. 2977-3004), as amended by Article 4, Paragraph 22 of the Act of 07 August 2013 (BGBI. I, no. 48, pp. 3154-3211)*)*)Obtainable from:
12、Bundesministerium der Justiz (German Federal Ministry of Justice) (Internet: http:/www.gesetze-im-internet.de). DIN EN 15030:2015-05 4 This page is intentionally blank EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15030:2012+A1 March 2015 ICS 71.100.80 Supersedes EN 15030:2012English Version
13、Chemicals used for treatment of water intended for human consumption - Silver salts for intermittent use Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Sels dargent pour usage intermittent Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Si
14、lbersalze fr den nicht systematischen Gebrauch This European Standard was approved by CEN on 23 September 2012 and includes Amendment 1 approved by CEN on 5 January 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
15、 Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (E
16、nglish, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgiu
17、m, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerl
18、and, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national M
19、embers. Ref. No. EN 15030:2012+A1:2015 EEN 15030:2012+A1:2015 (E) 2 Contents Page Foreword 3 Introduction . 4 1 Scope 5 2 Normative references 5 3 Description . 6 4 Purity criteria 9 5 Test methods 10 6 Labelling - transportation - storage . 13 Annex A (informative) General information on silver sal
20、ts . 16 Annex B (normative) General rules relating to safety 18 Annex C (informative) Environmental, health and safety precautions within the chemical laboratory . 19 Bibliography 20 DIN EN 15030:2015-05 EN 15030:2012+A1:2015 (E) 3 Foreword This document (EN 15030:2012+A1:2015) has been prepared by
21、Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2015, and conflicting national standards shall b
22、e withdrawn at the latest by September 2015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes !EN 15030:2012“.
23、 This document includes Amendment 1 approved by CEN on 2015-01-04. The start and finish of text introduced or altered by amendment is indicated in the text by tags !“. The significant technical differences between this edition and EN 15030:2006 are as follows: Modification of 6.2 on labelling, delet
24、ion of the reference to EU Directive 80/778/EEC of 15 July 1980 in order to take account of the latest Directive in force. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgiu
25、m, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerl
26、and, Turkey and the United Kingdom. DIN EN 15030:2015-05 EN 15030:2012+A1:2015 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for human consumption caused by the products covered by this European Standard: a) this European Standard provides no information
27、 as to whether the products may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of these products remain in
28、force. !NOTE 1“ Conformity with this European Standard does not confer or imply acceptance or approval of the products in any of the member states of the EU or EFTA. The use of the products covered by this European Standard is subject to regulation or control by national authorities. !NOTE 2 These p
29、roducts are used as biocides and comply with the relevant legislation in force. In the European Union, at the time of publication, this legislation is Regulation (EU) No 528/2012 1.“ Water which is to be preserved with silver !ions“ should fulfil the relevant legal requirements before the silver sal
30、t is added, in particular microbiological requirements. DIN EN 15030:2015-05 EN 15030:2012+A1:2015 (E) 5 1 Scope This European Standard is applicable to silver nitrate and silver sulfate !and silver chloride“ for the preservation of water intended for human consumption in intermittent applications i
31、n: water supply plants, including their pipeline networks (small-size plants); water for the preparation of foodstuffs; water which is stored in packaged form or kept in enclosed systems (for example, water supply systems in land, water and airborne vehicles). The purpose of adding silver salts is t
32、o prevent the detrimental proliferation of microorganisms in water during storage or in enclosed supply systems. This European Standard describes the characteristics of silver salts, specifies the requirements for silver salts and gives reference to the analytical methods. It gives information on th
33、eir use in water treatment. It also determines the rules relating to safe handling and use of silver salts (see Annex B). 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references,
34、only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1233, Water quality Determination of chromium Atomic absorption spectrometric methods EN ISO 3696, Water for analytical laboratory use Specification and test m
35、ethods (ISO 3696) EN ISO 5961, Water quality Determination of cadmium by atomic absorption spectrometry (ISO 5961) EN ISO 10304-1, Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and su
36、lphate (ISO 10304-1) EN ISO 11885, Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885) EN ISO 11969, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride technique) (ISO 11969) EN ISO 128
37、46, Water quality Determination of mercury Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) ISO 3165, Sampling of chemical products for industrial use Safety in sampling ISO 6206, Chemical products for industrial use Sampling Vocabulary ISO 8213, Chemical pro
38、ducts for industrial use Sampling techniques Solid chemical products in the form of particles varying from powders to coarse lumps ISO 8288:1986, Water quality Determination of cobalt, nickel, copper, zinc, cadmium and lead Flame atomic absorption spectrometric methods DIN EN 15030:2015-05 EN 15030:
39、2012+A1:2015 (E) 6 ISO 9965, Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique) 3 Description 3.1 Identification 3.1.1 Chemical name a) Silver nitrate; b) Silver sulfate; ! c) silver chloride.“ 3.1.2 Synonym or common name !The naturally occurring mine
40、ral is called chlorargyrite or cerargirite, if weathered by air named as horn silver.“ 3.1.3 Relative molecular mass a) 169,87; b) 311,97; ! c) 143,23.“ 3.1.4 Empirical formula a) AgNO3; b) Ag2SO4; ! c) AgCl.“ 3.1.5 Chemical formula a) AgNO3; b) Ag2SO4; ! c) AgCl.“ DIN EN 15030:2015-05 EN 15030:2012
41、+A1:2015 (E) 7 3.1.6 CAS Registry Number 1)a) 7761-88-8; b) 10294-26-5; ! c) 7783-90-6.“ 3.1.7 !EINECS number“ 2)a) 231-853-9; b) 233-653-7; ! c) 232-033-3.“ 3.2 Commercial forms !The products are solids, available as powders or pelletized.“ 3.3 Physical properties 3.3.1 Appearance !White to slightl
42、y grey or yellowish. NOTE Silver chloride quickly darkens on exposure to light by disintegrating into elemental chlorine and metallic silver; the latter is responsible for the colour change.“ 3.3.2 Density ! a) 4,35 g/cm3(crystal density); b) 5,45 g/cm3(crystal density); c) 5,56 g/cm3(crystal densit
43、y).“ 3.3.3 Solubility (in water) ! a) 2,16 g/l; b) 8 g/l; 1)Chemical Abstracts Service Registry Number. 2)European Inventory of Existing Commercial Chemical Substances. DIN EN 15030:2015-05 EN 15030:2012+A1:2015 (E) 8 c) 1,88 mg/l at 25 C.“ 3.3.4 Vapour pressure at 20 C Not applicable. 3.3.5 Boiling
44、 point at 100 kPa 3)! a) 444 C (decomposition); b) 1 085 C (decomposition); c) 1 550 C.“ 3.3.6 Melting point ! a) 212 C; b) 652 C; c) 455 C.“ 3.3.7 Specific heat Not known. 3.3.8 Viscosity (dynamic) Not applicable. 3.3.9 Critical temperature Not applicable. 3.3.10 Critical pressure Not applicable. 3
45、.3.11 Physical hardness Not applicable. 3.4 Chemical properties a) silver nitrate in solution is almost neutral (the pH value of an aqueous solution at 100 g/l is approximately 6); 3)100 kPa = 1 bar. DIN EN 15030:2015-05 EN 15030:2012+A1:2015 (E) 9 b) silver sulfate in solution is almost neutral (th
46、e pH value of an aqueous solution at 5 g/l is approximately 5 to 6); ! c) the saturated aqueous solution (see 3.3.3) is pH neutral. Silver chloride is insoluble in alcohol, other organic solvents, dilute acids and concentrated nitric acid, but soluble in concentrated sulphuric acid and (depending on
47、 the individual concentration) in aqueous solutions of ammonia, chlorides, bromides, thiosulfates and cyanides under complexation of the silver ion. The standard redox potential (E0) of Ag+/Ag in neutral aqueous solution at 25 C is: E = +0,80 V. The standard redox potential (E0) of AgCl/Ag in neutra
48、l solution at 25 C is: E = +0,22 V.“ 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for silvers salts used for the preservation of water intended for human consumption. Limits are given for impurities commonly present in the products. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. Users o
