1、 DEUTSCHE NORM June 2006DIN EN ISO 16000-2 This standard has been included in the VDI/DIN Handbook on air quality, Volume 5. ICS 13.040.20 Indoor air Part 2: Sampling strategy for formaldehyde (ISO 16000-2:2004) English version of DIN EN ISO 16000-2:2006-06 Innenraumluftverunreinigungen Teil 2: Prob
2、enahmestrategie fr Formaldehyd (ISO 16000-2:2004) Englische Fassung DIN EN ISO 16000-2:2006-06 Document comprises 22 pages No part of this standard may be reproduced without prior permission of DIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany, has the exclusi
3、ve right of sale for German Standards (DIN-Normen). English price group 12 www.din.de www.beuth.de !,o9e“11.06 9762266DIN EN ISO 16000-2:2006-06 2 National foreword International regulations regarding indoor air quality This standard has been published in accordance with a decision taken by CEN/TC 2
4、64 to adopt, without alteration, International Standard ISO 16000-2 as a European Standard. The responsible German body involved in its preparation was the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN (VDI/DIN Air Quality Commission), Section IV Umweltmesstechnik. The sampling strategy proc
5、edure described in this standard is based on Guideline VDI 4300 Part 3. The various parts of ISO 16000 describe general and substance-specific aspects of measurement planning which should be taken into consideration prior to or during measurements, as well as methods of measuring individual substanc
6、es or groups of substances in indoor air. National regulations regarding indoor air quality Aspects of planning indoor air measurements for particular substances or groups of substances are dealt with in the various parts of Guideline VDI 4300 (see National Annex NA). In some cases, these VDI guidel
7、ines served as the sole basis for drawing up certain parts of ISO 16000 (for instance, ISO 16000-1, ISO 16000-2 and ISO 16000-5). The determination (sampling, analysis) of these substances or substance groups in indoor air is dealt with in the VDI 4301 series. Methods which are suitable for both ind
8、oor air and ambient air measurements are described in other VDI Guidelines. Thus the following national technical rules for indoor air measurements are available: the DIN ISO 16000 series and the DIN EN ISO 16000 series: ISO standards which have been adopted as national standards, and the VDI 4300 s
9、eries: Guidelines which have been drawn up at the national level. The DIN Standards corresponding to the International Standards referred to in clause 2 of the EN are as follows: ISO Guide to the expression of uncertainty DIN V ENV 13005 in measurement (GUM), published jointly by BIPM, IEC, IFCC, IU
10、PAC, IUPAP, OIML, first edition 1995 ISO 6879 DIN ISO 6879 ISO 16000-3 DIN ISO 16000-3 ISO 16000-4 DIN ISO 16000-4 DIN EN ISO 16000-2:2006-06 3 National Annex NA (informative) Bibliography DIN V ENV 13005, Guide to the expression of uncertainty in measurement DIN EN 14412, Indoor air quality Diffuse
11、 samplers for the determination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 16000-1, Indoor air Part 1: General aspects of sampling strategy E DIN EN ISO 16000-5, Indoor air Part 5: Sampling strategy for volatile organic compounds (VOCs) E DIN EN ISO 16
12、000-7, Indoor air Part 7: Sampling strategy for determination of airborne asbestos fibre concentrations DIN EN ISO 16000-9, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN EN ISO 16000-10, Indoor ai
13、r Part 10: Determination of the emission of volatile organic compounds from building products and furnishing Emission test cell method DIN EN ISO 16000-11, Indoor air Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of sampl
14、es and preparation of test specimens DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and an
15、alysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories DIN ISO 6879, Air quality Performance characteristics and related conc
16、epts for air quality measuring methods DIN ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling method DIN ISO 16000-4, Indoor air Part 4: Determination of formaldehyde Diffusive sampling method DIN ISO 16000-6, Indoor air Part 6: Determination o
17、f volatile organic compounds in indoor and test chamber air by active sampling on TENAX TA sorbent, thermal desorption and gas-chromatography using MS/FID E DIN ISO 16000-8, Indoor air Part 8: Ventilation rate measurement VDI 2100 Part 1, Gaseous ambient air pollution measurement Indoor air pollutan
18、ts measurement Gas chromatographic determination of organic compounds Fundamentals VDI 2100 Part 2, Determination of gaseous compounds in ambient air Determination of indoor air pollutants Gas chromatographic determination of organic compounds Active sampling by accumulation on activated charcoal So
19、lvent extraction DIN EN ISO 16000-2:2006-06 4 VDI 2100 Part 3, Determination of gaseous compounds in ambient air Determination of indoor air pollutants Gas chromatographic determination of organic compounds Active sampling by accumulation on sorbents Thermal desorption VDI 2100 Part 4, Gaseous ambie
20、nt air measurement Indoor air pollution measurement Gas chromatographic determination of organic compounds Calibration procedures as a measure for quality assurance VDI 2100 Part 5, Gaseous ambient air measurement Indoor air pollution measurement Gas chromatographic determination of organic compound
21、s Determination of volatile organic compounds, especially ozone precursors VDI 3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with the sulfite pararosaniline method VDI 3484-2, Gaseous ambient air
22、measurements Indoor-air pollution measurements Measurement of the formaldehyde concentration with the acetylacetone method VDI 3492, Indoor air measurement Ambient air measurement Measurement of inorganic fibrous particles Scanning electron microscopy method VDI 3498 Part 1, Ambient air measurement
23、Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using large filters VDI 3498 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4300 Part 1, Indoor a
24、ir pollution measurement General aspects of measurement strategy VDI 4300 Part 2, Indoor air pollution measurement Measurement strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated bibhenyle (PCBs) V
25、DI 4300 Part 3, Measurement of indoor air pollutants Measurement strategy for formaldehyde VDI 4300 Part 4, Indoor air pollution measurement Measurement strategy for pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Part 5, Indoor air pollution measurement Measureme
26、nt strategy for nitrogen dioxide (NO2) VDI 4300 Part 6, Measurement of indoor air pollution Measurement strategy for volatile organic compounds (VOCs) VDI 4300 Part 7, Indoor air pollution measurement Measurement of indoor air change rate VDI 4300 Part 8, Measurement of indoor air pollution Sampling
27、 of house dust VDI 4300 Part 9, Measurement of indoor air pollution Measurement strategy for carbon dioxide (CO2) VDI 4301 Part 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide Manual photometric method (Saltzman) VDI 4301 Part 2, Indoor air pollution measur
28、ement Measurement of pentaclorphenol (PCP) and -hexachlorcyclohexane (lindane) GC/MS-method VDI 4301 Part 3, Measurement of indoor air pollution Measurement pentaclorophenol (PCP) and -hexachlorcyclohexane (lindane) GC/ECD method E VDI 4301 Part 4, Measurement of indoor air pollution Measurement of
29、pyrethroids and piperonylbutoxide in air, house dust and solvent wipe samples EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 16000-2 April 2006 ICS 13.040.20 English Version Indoor air - Part 2: Sampling strategy for formaldehyde (ISO 16000-2:2004) Air intrieur - Partie 2: Stratgie dchanti
30、llonnage du formaldhyde (ISO 16000-2:2004) Innenraumluftverunreinigungen - Teil 2: Probenahmestrategie fr Formaldehyd (ISO 16000-2:2004)This European Standard was approved by CEN on 9 March 2006. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions
31、 for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three offic
32、ial versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, B
33、elgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDA
34、RDIZATION COMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 16000-2:2006: EEN ISO 16000-2:2006 (E) 2 Foreword
35、 The text of ISO 16000-2:2004 has been prepared by Technical Committee ISO/TC 146 “Air quality” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 16000-2:2006 by Technical Committee CEN/TC 264 “Air quality” the secretariat of which is held by DIN. This Eur
36、opean Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by October 2006, and conflicting national standards shall be withdrawn at the latest by October 2006. According to the CEN/CENELEC Internal Regulations, the na
37、tional standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
38、Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 16000-2:2004 has been approved by CEN as a EN ISO 16000-2:2006 without any modification. ISO 16000 consists of the following parts, under the general title Indoor air : Part 1: Ge
39、neral aspects of sampling strategy Part 2: Measurement strategy for formaldehyde Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling method Part 4: Determination of formaldehyde Diffusive sampling method Part 6: Determination of volatile organic compounds in indoor and
40、 test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas-chromatography using MS/FID The following parts of ISO 16000 are under preparation: Part 5: Sampling strategy for volatile organic compounds (VOCs) Part 7: Sampling strategy for determination of airborne asbestos fi
41、bre concentrations Part 8: Ventilation rate measurement Part 9: Determination of the emission of volatile organic compounds Emission test chamber method Part 10: Determination of the emission of volatile organic compounds Emission test cell method Part 11: Determination of the emission of volatile o
42、rganic compounds Sampling, storage of samples and preparation of test specimens EN ISO 16000-2:2006 (E) 3 Contents Page Foreword .2 Introduction.4 1 Scope5 2 Normative references5 3 Sources and occurrence of formaldehyde .5 4 Measurement techniques .7 4.1 General .7 4.2 Short-term monitoring 8 4.3 L
43、ong-term monitoring.8 4.4 Methods for screening tests 8 5 Sampling strategy .8 5.1 General .8 5.2 Objectives of the measurement and conditions 8 5.3 Time of sampling.10 5.4 Duration of sampling and frequency of measurement10 5.5 Sampling location10 5.6 Reporting on results and uncertainties 10 5.7 Q
44、uality assurance11 Annex A (informative) Properties of formaldehyde.12 Annex B (informative) Overview of important sources and typical concentrations13 Annex C (informative) Correlation of formaldehyde concentrations in naturally ventilated rooms depending on ventilation14 Annex D (informative) Depe
45、ndence of the confidence interval on the number of samples .15 Annex E (informative) Examples of screening tests .16 Bibliography18 EN ISO 16000-2:2006 (E) 4 Introduction This part of ISO 16000 describes basic aspects to be considered when working out a sampling strategy for the analysis of formalde
46、hyde in indoor air. NOTE The term “formaldehyde” is used in this International Standard instead of the term “methanal”, as specified by IUPAC regulations. It is intended to be a link between Part 1 of ISO 16000, which describes a measurement strategy, and Parts 3 and 4 of ISO 16000, which describe t
47、he analytical procedures dealing with active or diffusive sampling of formaldehyde respectively. This part of ISO 16000 presupposes knowledge of Part 1 of ISO 16000. The sampling strategy procedure is based on VDI 4300, Part 31. VOC measurements in different fields of air pollution are described in
48、ISO 16017, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling Part 2: Diffusive sampling EN ISO 16000-2:2006 (E) 5 1 Scope This part of ISO 16000 is intended as an aid to planni
49、ng formaldehyde indoor pollution measurements. In the case of indoor air measurements1), the careful planning of sampling and the entire measurement strategy are of particular significance, since the result of the measurement can have far-reaching consequences, for example, with regard to the need for remedial action or the success of such an action. 2 Normative references The following refe
