1、March 2013 Translation by DIN-Sprachendienst.English price group 22No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS
2、13.060.45!$1$“1961401www.din.deDDIN EN ISO 5667-3Water quality Sampling Part 3: Preservation and handling of water samples (ISO 5667-3:2012);English version EN ISO 5667-3:2012,English translation of DIN EN ISO 5667-3:2013-03Wasserbeschaffenheit Probenahme Teil 3: Konservierung und Handhabung von Was
3、serproben (ISO 5667-3:2012);Englische Fassung EN ISO 5667-3:2012,Englische bersetzung von DIN EN ISO 5667-3:2013-03Qualit de leau chantillonnage Partie 3: Conservation et manipulation des chantillons deau (ISO 5667-3:2012);Version anglaise EN ISO 5667-3:2012,Traduction anglaise de DIN EN ISO 5667-3:
4、2013-03SupersedesDIN EN ISO 5667-3:2004-05 andDIN EN ISO 5667-3Corrigendum 1:2006-08www.beuth.deDocument comprises 54 pagesIn case of doubt, the German-language original shall be considered authoritative.03.13DIN EN ISO 5667-3:2013-03 2 A comma is used as the decimal marker. National foreword This d
5、ocument (EN ISO 5667-3:2012) has been prepared by Technical Committee ISO/TC 147 “Water quality” in collaboration with Technical Committee CEN/TC 230 “Water analysis” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Pract
6、ice Standards Committee), Working Committee NA 119-01-03-01-01 AK Probenahme of NA 119-01-03 AA Wasseruntersuchung. ISO 5667 consists of the following parts, under the general title Water quality Sampling: Part 1: Guidance on the design of sampling programmes and sampling techniques Part 3: Preserva
7、tion and handling of water samples Part 4: Guidance on sampling from lakes, natural and man-made Part 5: Guidance on sampling of drinking water from treatment works and piped distribution systems Part 6: Guidance on sampling of rivers and streams Part 7: Guidance on sampling of water and steam in bo
8、iler plants Part 8: Guidance on the sampling of wet deposition Part 9: Guidance on sampling from marine waters Part 10: Guidance on sampling of waste waters Part 11: Guidance on sampling of groundwaters Part 12: Guidance on sampling of bottom sediments Part 13: Guidance on sampling of sludges Part 1
9、4: Guidance on quality assurance of environmental water-sampling and handling Part 15: Guidance on the preservation and handling of sludge and sediment samples Part 16: Guidance on biotesting of samples Part 17: Guidance on sampling of bulk suspended solids Part 19: Guidance on sampling of marine se
10、diments Part 20: Guidance on the use of sampling data for decision making Compliance with thresholds and classification systems Part 21: Guidance on sampling of drinking water distributed by tankers or means other than distribution pipes Part 22: Guidance on the design and installation of groundwate
11、r monitoring points Part 23: Guidance on passive sampling in surface waters DIN EN ISO 5667-3:2013-03 3 The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 3696 DIN ISO 3696 ISO 5663 DIN EN 25663 ISO 5667-1 DIN EN ISO 5667-1 ISO 5814 DIN EN
12、 ISO 5814 ISO 5961 DIN EN ISO 5961 ISO 6468 DIN EN ISO 6468 ISO 6878 DIN EN ISO 6878 ISO 7027 DIN EN ISO 7027 ISO 7887 DIN EN ISO 7887 ISO 7888 DIN EN 27888 ISO 7980 DIN EN ISO 7980 ISO 8467 DIN EN ISO 8467 ISO 9377-2 DIN EN ISO 9377-2 ISO 9439 DIN EN ISO 9439 ISO 9562 DIN EN ISO 9562 ISO 9963-1 DIN
13、 EN ISO 9963-1 ISO 9964-3 DIN ISO 9964-3 ISO 10304-1 DIN EN ISO 10304-1 ISO 10304-3 DIN EN ISO 10304-3 ISO 10304-4 DIN EN ISO 10304-4 ISO 10523 DIN EN ISO 10523 ISO 10566 DIN ISO 10566 ISO 10695 DIN EN ISO 10695 ISO 11369 DIN EN ISO 11369 ISO 11732 DIN EN ISO 11732 ISO 11885 DIN EN ISO 11885 ISO 119
14、69 DIN EN ISO 11969 ISO 12020 DIN EN ISO 12020 ISO 12846 DIN EN ISO 12846 ISO 13395 DIN EN ISO 13395 ISO 14402 DIN EN ISO 14402 ISO 14403-1 DIN EN ISO 14403-1 ISO 14403-2 DIN EN ISO 14403-2 ISO 14911 DIN EN ISO 14911 ISO 15061 DIN EN ISO 15061 ISO 15586 DIN EN ISO 15586 ISO 15680 DIN EN ISO 15680 IS
15、O 15681-1 DIN EN ISO 15681-1 ISO 15681-2 DIN EN ISO 15681-2 ISO 15682 DIN EN ISO 15682 ISO 15705 DIN ISO 15705 ISO 15913 DIN EN ISO 15913 ISO 16264 DIN EN ISO 16264 ISO 17294-2 DIN EN ISO 17294-2 ISO 17353 DIN EN ISO 17353 ISO 17852 DIN EN ISO 17852 ISO 17993 DIN EN ISO 17993 ISO 18412 DIN EN ISO 18
16、412 ISO 18856 DIN EN ISO 18856 ISO 18857-1 DIN EN ISO 18857-1 ISO 18857-2 DIN EN ISO 18857-2 ISO 19458 DIN EN ISO 19458 ISO 23913 DIN EN ISO 23913 DIN EN ISO 5667-3:2013-03 4 Designation of method A 21 “Preservation and handling of water samples (A 21)”: Method DIN EN ISO 5667-3 A 21 Expert assistan
17、ce and specialized laboratories will be required to perform the analyses described in this standard. Existing safety requirements are to be observed. Depending on the objective of the analysis, a check shall be made on a case-by-case basis as to whether and to what extent additional conditions will
18、have to be specified. This standard has been prepared by the Normenausschuss Wasserwesen (Water Practice Standards Committee) in collaboration with the Wasserchemische Gesellschaft - Fachgruppe in der Gesellschaft Deutscher Chemiker (Water Chemistry Society - Division of the German Chemical Society)
19、. It is part of the series Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung (German standard methods for the examination of water, waste water and sludge): Preservation and handling of water samples (A 21). Standard methods published as DIN Standards are obtainable from Beut
20、h Verlag GmbH, either individually or grouped in volumes. The standard methods included in the loose-leaf publication entitled Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung will continue to be published by Wiley-VCH Verlag GmbH b) the technical content has been brought in
21、 line with the modified specifications in the relevant analytical standards; c) the standard has been editorially revised. Previous editions DIN EN ISO 5667-3: 1996-04, 2004-05 DIN EN ISO 5667-3 Corrigendum 1: 2006-08 National Annex NA (informative) Bibliography DIN EN 25663, Water quality Determina
22、tion of Kjeldahl nitrogen Method after mineralization with selenium DIN EN 27888, Water quality Determination of electrical conductivity DIN EN ISO 5667-1, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques DIN EN ISO 5814, Water quality Determinatio
23、n of dissolved oxygen Electrochemical probe method DIN EN ISO 5961, Water quality Determination of cadmium by atomic absorption spectrometry DIN EN ISO 6468, Water quality Determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes Gas-chromatographic method af
24、ter liquid-liquid DIN EN ISO 6878, Water quality Determination of phosphorus Ammonium molybdate spectrometric method DIN EN ISO 7027, Water quality Determination of turbidity DIN EN ISO 7887, Water quality Examination and determination of colour DIN EN ISO 7980, Water quality Determination of calciu
25、m and magnesium Atomic absorption spectrometric method DIN EN ISO 8467, Water quality Determination of permanganate index DIN EN ISO 5667-3:2013-03 6 DIN EN ISO 9377-2, Water quality Determination of hydrocarbon oil index Part 2: Method using solvent extraction and gas chromatography DIN EN ISO 9439
26、, Water quality Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium Carbon dioxide evolution test DIN EN ISO 9562, Water quality Determination of adsorbable organically bound halogens (AOX) DIN EN ISO 9963-1, Water quality Determination of alkalinity Part 1: Determ
27、ination of total and composite alkalinity DIN EN ISO 103041, Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate DIN EN ISO 10304-3, Water quality Determination of dissolved ani
28、ons by liquid chromatography of ions Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate DIN EN ISO 10304-4, Water quality Determination of dissolved anions by liquid chromatography of ions Part 4: Determination of chlorate, chloride and chlorite in water with low contami
29、nation DIN EN ISO 10523, Water quality Determination of pH DIN EN ISO 10695, Water quality Determination of selected organic nitrogen and phosphorus compounds Gas chromatographic methods DIN EN ISO 11369, Water quality Determination of selected plant treatment agents Method using high performance li
30、quid chromatography with UV detection after solid-liquid extraction DIN EN ISO 11732, Water quality Determination of ammonium nitrogen Method by flow analysis (CFA and FIA) and spectrometric detection DIN EN ISO 11885, Water quality Determination of selected elements by inductively coupled plasma op
31、tical emission spectrometry (ICP-OES) DIN EN ISO 11969, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride technique) DIN EN ISO 12020, Water quality Determination of aluminium Atomic absorption spectrometric methods DIN EN ISO 12846, Water quality Determination o
32、f mercury Method using atomic absorption spectrometry (AAS) with and without enrichment DIN EN ISO 13395, Water quality Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection DIN EN ISO 14402, Water quality Determination
33、of phenol index by flow analysis (FIA and CFA) DIN EN ISO 14403-1, Water quality Determination of total cyanide and free cyanide using flow analysis (FIA and CFA) Part 1: Method using flow injection analysis (FIA) DIN EN ISO 14403-2, Water quality Determination of total cyanide and free cyanide usin
34、g flow analysis (FIA and CFA) Part 2: Method using continuous flow analysis (CFA) DIN EN ISO 14911, Water quality Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+und Ba2+using ion chromatography Method for water and waste water DIN EN ISO 5667-3:2013-03 7 DIN EN ISO 15061, Water
35、 quality Determination of dissolved bromate Method by liquid chromatography of ions DIN EN ISO 15586, Water quality Determination of trace elements using atomic absorption spectrometry with graphite furnace DIN EN ISO 15680, Water quality Gas-chromatographic determination of a number of monocyclic a
36、romatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and thermal desorption DIN EN ISO 15681-1, Water quality Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) Part 1: Method by flow injection analysis (FIA) DIN EN ISO 15
37、681-2, Water quality Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) Part 2: Method by continuous flow analysis (CFA) DIN EN ISO 15682, Water quality Determination of chloride by flow analysis (CFA and FIA) and photometric or potentiometric detection DIN
38、EN ISO 15913, Water quality Determination of selected phenoxyalkanoic herbicides, including bentazones and hydroxybenzonitriles by gas chromatography and mass spectrometry after solid phase extraction and derivatization DIN EN ISO 16264, Water quality Determination of soluble silicates by flow analy
39、sis (FIA and CFA) and photometric detection DIN EN ISO 17294-2, Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 2: Determination of 62 elements DIN EN ISO 17353, Water quality Determination of selected organotin compounds Gas chromatographic method DIN EN ISO
40、17852, Water quality Determination of mercury Method using atomic fluorescence spectrometry DIN EN ISO 17993, Water quality Determination of 15 polycyclic aromatic hydrocarbons (PAH) in water by HPLC with fluorescence detection after liquid-liquid extraction DIN EN ISO 18412, Water quality Determina
41、tion of chromium (VI) Photometric method for weakly contaminated water DIN EN ISO 18856, Water quality Determination of selected phthalates using gas chromatography/mass spectrometry DIN EN ISO 18857-1, Water quality Determination of selected alkylphenols Part 1: Method for non-filtered samples usin
42、g liquid-liquid extraction and gas chromatography with mass selective detection DIN EN ISO 18857-2, Water quality Determination of selected alkylphenols Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following s
43、olid-phase extraction and derivatisation DIN EN ISO 19458, Water quality Sampling for microbiological analysis DIN EN ISO 23913, Water quality Determination of chromium(VI) Method using flow analysis (FIA and CFA) and spectrometric detection DIN ISO 3696, Water for analytical laboratory use Specific
44、ation and test methods DIN EN ISO 5667-3:2013-03 8 DIN ISO 9964-3, Water quality Determination of sodium and potassium Part 3: Determination of sodium and potassium by flame emission spectrometry DIN ISO 10566, Water quality Determination of aluminium Spectrometric method using pyrocatechol violett
45、DIN ISO 15705, Water quality Determination of the chemical oxygen demand index (ST-COD) Small-scale sealed tube method EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 5667-3 November 2012 ICS 13.060.45 Supersedes EN ISO 5667-3:2003English Version Water quality - Sampling - Part 3: Preservat
46、ion and handling of water samples (ISO 5667-3:2012) Qualit de leau - chantillonnage - Partie 3: Conservation et manipulation des chantillons deau (ISO 5667-3:2012)Wasserbeschaffenheit - Probenahme - Teil 3: Konservierung und Handhabung von Wasserproben (ISO 5667-3:2012) This European Standard was ap
47、proved by CEN on 14 November 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nati
48、onal standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own langu
49、age and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, L
