1、 ENGINEERING MATERIAL SPECIFICATIONDate Action Revisions 2006 01 13 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.9, 3.10 & 4 1993 08 02 Released EP00E10258823000 K. Gerhards Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 1 of 5 POLYAMIDE 12 (PA12), RIGID, HEAT STABIL
2、IZED WSK-M4D739-A3 MOLDING COMPOUND, INTERIOR 1. SCOPE The material defined by this specification is a rigid, heat stabilized type 12 polyamide molding compound. 2. APPLICATION This specification was released originally for material used for cover retension hook. 3. REQUIREMENTS 3.0 STANDARD REQUIRE
3、MENTS FOR PRODUCTION MATERIALS Material supplier and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.1.1 All requirements of this specification, identified by symbol(s), shall be met with data representing 3 sigma values. 3.3 CONDITIONIN
4、G AND TEST CONDITIONS All test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% (test according to ISO 960, Method B). All test materials immediately after processing have to be sealed in containers that are impermeable to water vapor. If the moist
5、ure content exceeds 0.2%, condition the material for a minimum of 16 h at 40 - 50 C at a reduced pressure below 133 Pa. 3.4 MOLDING COMPOUND (s) 3.4.1 Melt Temperature, min 175 - 185 C (ISO 3146, Method C, 10 C/min heating rate) 3.5 MOLDED TEST SPECIMEN 3.5.1 Preparation of Test Specimens Unless oth
6、erwise specified all tests shall be carried out on injection molded one-end gated test specimens. The following dimensions are required: A. 150 min x 10 x 4.0 +/- 0.2 mm (Tensile Bar, ISO 3167) B. 120 x 10 x 4.0 +/- 0.2 mm Specimens with shorter dimensions shall be cut from the center portion of the
7、 test specimen A and/or B. The specimens shall be prepared according to ISO 294. No annealing allowed. ENGINEERING MATERIAL SPECIFICATIONWSK-M4D739-A3Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 2 of 5 3.5.2 Density 1.00 - 1.03 g/cm3(ISO 1183, Method A) (s) 3.5.
8、3 Tensile Strength at Yield, min 38 MPa (ISO R 527, 150 minimum x 10 x 4.0 +/- 0.2 mm specimen, 50 mm/min test speed, (s) 3.5.3.1 Elongation at Yield, min 4% (Test Method according to para 3.5.3) (s) 3.5.4 Flexural Modulus, min 1.2 GPa (ISO 178, 80 x 10 x 4.0 +/- 0.2 mm specimen, 2 mm/min test speed
9、, 64 mm support span) 3.5.5 Shear Modulus at 23 C 470 - 710 MPa (ASTM D 4065, forced constant amplitude, fixed frequency of 1 Hz +/- 15%, strain level below 1%. Specimen approx. 60 x 10 x 4.0 +/- 0.2 mm cut from the center of specimen A. Specimen length between clamps 35-40 mm. Soak time at each tem
10、perature interval - 3 minutes minimum). Additionally, a Shear Modulus versus Temperature curve shall be plotted for -50 to +160 C temperature range, at 5 C minimum intervals. The plotted curve must be within tolerance range shown on page 5. (s) 3.5.6 Impact Strength, Izod, min (ISO 180/1A, 80 x 10 x
11、 4.0 +/- 0.2 mm specimen, 10 specimens for each test) 3.5.6.1 At 23 +/- 2 C 4 kJ/m23.5.6.2 At -40 +/- 1 C kJ/m2The test specimens must be conditioned for minimum of 6 h at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box. (s) 3.5.7 Heat
12、Deflection Temperature, min (ISO 75, 120 x 10 x 4.0 +/- 0.2 mm specimen, 0.34 +/- 0.01 mm deflection) 3.5.7.1 At 1.80 MPa 40 C 3.5.7.2 At 0.45 MPa 90 C ENGINEERING MATERIAL SPECIFICATIONWSK-M4D739-A3Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 3 of 5 3.5.8 Heat
13、Aging Performance (ISO 188, except 150 +/- 50 air changes/h, 1000 h at 130 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.5.8.1 Tensile Strength a
14、t Max Load Change +/- 25% (Test Method per para 3.5.3) 3.6 FOGGING (FLTM BO 116-03, 3 h at 100 C) Fog Number, min 60 Formation of clear film or droplets is cause for rejection. 3.7 FLAMMABILITY (ISO 3795) Burn Rate, max 100 mm/minute The specimen size required for material approval is 355 x 100 x 1.
15、0 +/- 0.1 mm with a smooth surface. 3.8 WEATHERING RESISTANCE After exposure in accordance with 3.8.1 and 3.8.2 the material shall show no fading or color change in excess of specified Gray Scale rating (AATCC Evaluation Procedure 1/ISO 105-A02). In addition, there shall be no cracking, crazing or o
16、ther deterioration. A slight loss of gloss or chalking will be allowed provided an acceptable appearance can be achieved by washing with mild detergents and water (ratio 5:95 by volume), or equivalent, after the Florida exposure. All initial approvals will be based on the preliminary Weatherometer e
17、xposure, pending Florida exposure results for final approval. 3.8.1 Xenon Arc Weatherometer Rating 4 (SAE J1885, 313.5 kJ/m2exposure minimum, specimen size: 150 x 100 mm minimum, 3.2 +/- 0.2 mm thick, molded in smooth polished mold) 3.8.2 12 months Florida Rating 4 (FLTM BI 160-01, 5 south, under gl
18、ass, specimen size: 150 x 100 mm, minimum, 3.2 +/- 0.2 mm thick, molded in smooth polished mold) ENGINEERING MATERIAL SPECIFICATIONWSK-M4D739-A3Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 4 of 5 5. GENERAL INFORMATION The information given below is provided for
19、 clarification and assistance in meeting the requirements of this specification. 5.1 COEFFICIENT OF LINEAR THERMAL EXPANSION 9 13-5/ C (ASTM E 228 or TMA, temperature range -30 to +30 C) 5.2 MOLD SHRINKAGE (ISO 2577, approx. 150 x 100 x 3.2 +/- 0.2 mm injection molded specimen) 5.2.1 Molding Shrinka
20、ge . After 48 h at 23 +/- 2 C 1.3 - 1.7% 5.2.2 Post Shrinkage (Separate specimens required for each test) . After 48 h at 80 C 0.03 - 0.1% . After 30 min at 120 C 0.1 - 0.3% 5.3 WATER ABSORPTION 0.1 - 0.3% (ISO 62, 24 h immersion, 50 +/- 1 mm diameter, 3.2 +/- 0.2 mm thick specimen) 5.4 RECYCLING CODE PA12 ENGINEERING MATERIAL SPECIFICATIONWSK-M4D739-A3Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 5 of 5
