KS M ISO 6503-2007 Paints and varnishes-Determination of total lead-Flame atomic absorption spectrometric method《涂料和清漆 铅总含量的测定 火焰原子吸收光谱测定法》.pdf

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KS M ISO 6503-2007 Paints and varnishes-Determination of total lead-Flame atomic absorption spectrometric method《涂料和清漆 铅总含量的测定 火焰原子吸收光谱测定法》.pdf_第1页
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1、 KS M ISO 6503 KSKSKSKS SKSKSKS KSKSKS SKSKS KSKS SKS KS KS M ISO 6503 :2007 (2012 ) 2007 9 28 http:/www.kats.go.krKS M ISO 6503:2007 : ( ) ( ) LH () () KCC ( ) : (http:/www.standard.go.kr) : :2002 1 14 :2007 9 28 : 2012 12 20 : 20120740 : ( 02-509-7270) (http:/www.kats.go.kr). 10 5 , . KS M ISO 650

2、3:2007 (2012 ) Paints and varnishes Determination of total lead Flame atomic absorption spectrometric method 1984 1 ISO 6503, Paints and varnishesDetermination of total lead Flame atomic absorption spectrometric method , . 1 . 0.012 %(m/m) . 2 %(m/m) , 7.2 . , (4.) . KS M ISO 38561 . 2 . . KS A ISO

3、5725( ), ( ) KS L ISO 3851, 1: KS L ISO 1042, KS M ISO 1513, KS M ISO 3696, KS M ISO 38561, “” 1: ISO 1512, Paints and varnishesSampling of products in liquid or paste form KS M ISO 6503:2007 3 . 4 4.1 , 475 . 4.2 , KS M ISO 3696 3 . 4.2.1 () 4.2.2 4.2.3 4.2.4 4.2.5 10 g/L 4.2.6 180 g/L. 36 %(m/m),

4、1.18 g/mL 450 mL 1 000 mL . 4.2.7 18 g/L. (4.2.6) 100 mL 1 000 mL . 4.2.8 315 g/L. 65 %(m/m), 1.4 g/mL . 4.2.9 (1 g Pb/L) . a) (4.2.8) 30 mL 1 000 mL 1 g . b) 105 2 Pb(NO 3 ) 21.598 g 1 mg 1 000 mL (4.2.8) 30 mL 2 KS M ISO 6503:2007 . 1 mL 1 mg . 4.2.10 (100 mg Pb/L) . (4.2.9) 10 mL 100 mL (4.2.7) .

5、 1 mL 100 g . 4.3 , . 4.3.1 , . 4.3.2 (47525) . 4.3.3 . 4.4 ISO 1512 , . KS M ISO 1513 . 4.5 4.5.1 , . , . 4.5.2 . 5 g (4.3.1) 10 mg . (4.5.1) 2 g (4.2.4) . 3 KS M ISO 6503:2007 4.5.3 (fume) (4.3.3) . 2 g (4.2.2) 10 350 (4.3.2) (47525) 60 . . 4.5.4 4.5.4.1 (4.5.1 ) 250 mL 100 mL (4.2.6) (4.3.3) 15 ,

6、 15 . 1 ) 250 mL . . 250 mL . 4.5.4.2 (4.5.1 ) (4.5.3) (4.2.1) (4.2.3) 10 g . , 1 2 . . (4.2.5) . 250 mL 15 mL (4.2.8) (4.3.3) 15 , 100 mL (4.2.6) 30 . 250 mL 1) . . 250 mL . 4.5.5 (4.5.4) 1 . 1) Whatman Nos. 42 and 44, Schleicher and Schll Nos. 589/3 and 589/6 4 KS M ISO 6503:2007 1 %(m/m) mL 0.4 0

7、.41 12 25 10 5 2 %(m/m) . 100 mL . 5 mL 10 mL (4.2.6) 10 mL . . 4.5.6 4.5.3, 4.5.4.1, 4.5.4.2 4.5.5 . 5 5.1 ( A) ( B) . EDTA ( ) . . 5.2 , KS M ISO 3696 3 . 5.2.1 96 %(m/m) 1.84 g/mL 5.2.2 30 %(m/m) 50 %(m/m) 5.2.3 65 %(m/m) 1.40 g/mL 5.2.4 315 g/L. (5.2.3) . 5 KS M ISO 6503:2007 5.2.5 85 g NH 3 /L

8、. 25 %(m/m) 380 mL 1 000 mL . 5.2.6 EDTA (37 g/L ) 5.2.7 (1 g Pb/L) . a) 5.2.4 30 mL 1 000 mL 1 g . b) 105 2 Pb(NO 3 ) 21.598 g 1 mg 1 000 mL (5.2.4) 30 mL . 1 mL 1 mg . 5.2.8 (100 mg Pb/L) . (5.2.7) 10 mL 100 mL (5.2.4) . 1 mL 100 g . 5.3 , . 5.3.1 . 5.4 ISO 1512 , . KS M ISO 1513 . 5.5 5.5.1 . 0.5

9、 g 400 mL ( A) 250 mL ( B) . 1 mg . 6 KS M ISO 6503:2007 5.5.2 5.5.2.1 A (5.3.1) . 5 mL (5.2.1) 15 , . 10 5 mL (5.2.2) . . 10 5 . 5 mL 5 5 . 5 mL . , . , . 5.5.2.2 B . (5.2.1) 5 mL 10 . 10 5 mL (5.2.3) 5 mL , , . 10 5 5 mL 5 , 5 . 5 mL . , . 5.5.3 ( A) ( B) 50 mL EDTA (5.2.6) 10 mL (5.2.5) 50 mL . 1

10、5 250 mL . . 5.5.4 (5.5.3) 2 . 7 KS M ISO 6503:2007 2 %(m/m) mL 0.5 0.51 12 100( ) 75 50 2 %(m/m) . 100 mL , . 5.5.5 5.5.2.1( A) 5.5.2.2( B), 5.5.3 5.5.4 . 6 6.1 / 283.3 nm . 6.2 . 6.2.1 6.2.2 6.3 6.3.1 283.3 nm . 6.3.2 6.3.3 KS L ISO 3851 50 mL . 6.3.4 KS L ISO 1042 100 mL . 8 KS M ISO 6503:2007 6.

11、4 6.4.1 , . 6.4.1.1 . 100 mL (6.3.4) 4 (6.3.3) 3 (4.2.10 5.2.8) . (4.2.6) 10 mL , . 3 (4.2.10 5.2.8) Pb mL g/mL 0 a1 2 3 4 5 0 2 5 10 20 30 0 2 5 10 20 30 a 6.4.1.2 (6.3.1) (6.3.2) . 283.3 nm . (6.2.1) (6.2.2) . 3 5 . (6.4.1.1) 4 . . 6.4.1.3 ( g/mL), . 9 KS M ISO 6503:2007 6.4.2 6.4.2.1 (6.4.1.2) (6

12、.3.1) (4.5.6 5.5.5) . 3 . 3 4 . ( F). 6.4.2.2 2 % 1 % 6.4.2. 1 . 6.4.2.3 c . , . 7 7.1 . V m F c a 5 . 2 a : (mg/kg) c : ( g/mL) F :6.4.2.1 m :4.5.2 5.5.1 (g) V :4.5.5 5.5.4 (mL) 2 . 7.2 KS A ISO 572516 . . 7.2.1 (r ) , , 95 % . 4.5.4.1 : 5 % 4.5.4.2 : 10 % 5.5.2.1 : 5 % (7.2.2 2 ) 10 KS M ISO 6503:

13、2007 11 7.2.2 (R ) 95 % . 4.5.4.1 : 15 % 4.5.4.2 : 30 % 5.5.2.1 : 15 % ( ) 1 5.5.2.1( A) . 2 5.5.2.2( B) . 8 . a) b) (KS M ISO 6503) c) ( ) ( A B) d) 4.5.2 e) f) g) 153787 1 145 3(16) (02)26240114 (02)26240148 http:/ KS M ISO 6503 :2007KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Paints and varnishes Determination of total lead Flame atomic absorption spectrometric method ICS 87.040 Korean Agency for Technology and Standards http:/www.kats.go.kr

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