AECMA PREN 2436-06-2005 Aerospace series Paints and varnishes Corrosion resistant chromate-free two component cold curing epoxy primer Part 06 High corrosion resistance for militar.pdf

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1、AECMA STANDARD NORME AECMA AECMA NORM Edition approved for publication 31 January 2005 prEN 2436-06 Edition P 1 January 2005 Comments should be sent within six months after the date of publication to Non-metallic Material Domain AECMA-STAN ICs: Descriptors: ENGLISH VERSION Aerospace series Paints an

2、d varnishes Corrosion resistant chromate-free two component cold curing epoxy primer Part 06: High corrosion resistance for military application Srie arospatiale Peintures et vernis Peinture primaire anti-corrosion sans chromate deux composants polymrisant temprature ambiante Partie 06: Haute rsista

3、nce la corrosion pour applications militaires Luft- und Raumfahrt Anstrichstoffe Korrosionsbestndiger Zweikomponenten-Grundanstrich, kalthrtend chromatfrei Teil 06: Hoher Korrosionsschutz fr militrische Anwendung This “Aerospace Series“ frestandard has been drawn up under the responsibility of AECMA

4、-STAN (The European Association of Aerospace Industries - Standardization). It is published for the needs of the European Aerospace Industry. It has been technically approved by the experts of the concerned Domain following member comments. Subsequent to the publication of this frestandard, the tech

5、nical content shall not be changed to an extent that interchangeabilify is affected, physically or functionally, without re-identification of the standard. After examination and review by users and formal agreement of AECMA-STAN, it will be submitted as a draft European Standard (prEN) to CEN (Europ

6、ean Committee for Standardization) for formal vote and transformation to full European Standard (EN). The CEN national members have then to implement the EN at national level by giving the EN the status of a national standard and by withdrawing any national standards conflicting with the EN. I I Cop

7、ytight 2005 O by AECMA-STA1 Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS under license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 2 prEN 2436-06:2005 Foreword This standard was reviewed by the Domain

8、Technical Coordinator of AECMA-STANS Non-metallic Material Domain. After inquiries and votes carried out in accordance with the rules of AECMA-STAN defined in AECMA- STANS General Process Manual, this standard has received approval for Publication. Contents Page 1 Scope 3 2 Normative references . 3

9、Definitions 4 4 Classification . 5 5 Batch release and qualification testing . 5 5.1 Qualification tests 5 5.2 Batch acceptance testing . 5 6 Designation 13 7 Requirements for fibre reinforced composites 13 Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS und

10、er license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 3 prEN 2436-06:2005 1 Scope This standard defines the requirements for a two component, chromate and lead free epoxy, high corrosion resistant primer. The coating shall be suitable for use on

11、 chromic acid anodised or conversion coated aluminium alloys, fibre reinforced composite materials and other suitably prepared substrates. 2 Normative references This European Standard incorporates by dated or undated reference, provisions from other publications. These normative references are cite

12、d at the appropriate places in the text and the publications are listed hereafter. For dated references, subsequent amendments to or revisions of any of these publications apply to this European Standard only when incorporated in it by amendment or revision. For undated references the latest edition

13、 of the publication referred to applies (including amendments). IS0 151 3, IS0 151 7, IS0 151 8, IS0 151 9, IS0 1520, IS0 1524, IS0 2409, IS0 2431, IS0 281 1-1, IS0 281 1-2, IS0 281 1-3, IS0 281 1-4, IS0 2812-1, IS0 281 2-2, IS0 3251, IS0 3270, IS0 3675, IS0 3678, IS0 3680, Paints and varnishes - Ex

14、amination and preparation of samples for testing Paints and varnishes - Surface-drying test - Ballotini method Paints and varnishes - Scratch test Paints and varnishes - Bend test (cylindrical mandrel) Paints and varnishes - Cupping test Paints, varnishes and printing inks - Determination of finenes

15、s of grind Paints and varnishes - Cross-cut test Paints and varnishes - Determination of flow time by use of flow cups Paints and varnishes - Determination of density - Patt I: Pyknometer method Paints and varnishes - Determination of density - Patt 2: Immersed body (plummet) method Paints and varni

16、shes - Determination of density - Patt 3: Oscillation method Paints and varnishes - Determination of density - Patt 4: Pressure cup method Paints and varnishes - Determination of resistance to liquids - Patt I: General methods Paints and varnishes - Determination of resistance to liquids - Patt 2: W

17、ater immersion method Paints, varnishes and plastics - Determination of non-volatile-matter content Paints and varnishes and their raw materials - Temperatures and humidities for conditioning and testing Crude petroleum and liquid petroleum products - Laboratory determination of density - Hydrometer

18、 method Determination of flash point - Rapid equilibrium closed cup method Determination of flashho flash - Rapid equilibrium closed cup method Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS under license with AECMANot for ResaleNo reproduction or networkin

19、g permitted without license from IHS-,-,-Page 4 prEN 2436-06:2005 IS0 4623-2, Paints and varnishes - Determination of resistance to filiform corrosion - Patt 2: Aluminium substrates IS0 4628-2, Paints and varnishes - Evaluation of degradation of coatings - Designation of quantity and size of defects

20、, and of intensity of uniform changes in appearance - Patt 2: Assessment of degree of blistering IS0 4628-8, Paints and varnishes - Evaluation of degradation of coatings - Designation of quantity and size of defects, and of intensify of uniform changes in appearance - Patt 8: Evaluation of corrosion

21、 around the scribe IS0 4628-1 O, Paints and varnishes - Evaluation of degradation of coatings - Designation of quantity and size of defects, and of intensity of uniform changes in appearance - Patt IO: Assessment of degree of filiform corrosion IS0 6270-1, Paints and varnishes - Determination of res

22、istance to humidity - Patt I: Continuous condensation IS0 7253, Paints and varnishes - Determination of resistance to neutral salt spray (fog) IS0 7724-1, Paints and varnishes - Colorimetry - Patt I: Principles IS0 7724-2, Paints and varnishes - Colorimetry - Patt 2: Colour measurement IS0 7724-3, P

23、aints and varnishes - Colorimetry- Patt 3: Calculation of colour differences IS0 91 17, Paints and varnishes - Determination of through-dry state and through-dry time - Method of test IS0 9514, Paints and varnishes - Determination of the pot-life of liquid systems - Preparation and conditioning of s

24、amples and guidelines for testing IS0 11890-1, Paints and varnishes - Determination of volatile organic compound (VOC) content - Patt I: Difference method IS0 11890-2, Paints and varnishes - Determination of volatile organic compound (VOC) content - Patt 2: Gas-chromatographic method EN 2434-05, EN

25、3212, EN 3837, EN 3840, EN 3847, EN 4160, Aerospace series - Paints and varnishes - Two component cold curing polyurethane finish - Patt 05: High flexibilify and chemical agent resistance for military application Aerospace series - Paints and varnishes - Corrosion test by alternate immersion in a bu

26、ffered sodium chloride solution Aerospace series - Paints and varnishes - Nature and method for surface preparation of test pieces in aluminium alloys 1 ) Aerospace series - Paints and varnishes - Technical specification Aerospace series - Paints and varnishes - Determination of sedimentation rating

27、 ) Aerospace series - Non-metallic materials - Paints and varnishes - Test methods - Determination of the effects of thermal exposure ) 3 Definitions See EN 3840. 1) Published as AECMA Prestandard at the date of publication of this standard Copyright Association Europeene des Constructeurs de Materi

28、el Aerospatial Provided by IHS under license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 5 prEN 2436-06:2005 4 Classification The primer is classified according to the following types and classes: Type I Standard solvent content; Type II Low vola

29、tile organic content ( 350 gh). Class A Standard pigments; Class B Low infrared reflective pigments. 5 Batch release and qualification testing 5.1 Qualification tests For product qualification, all tests defined in this standard, in the Tables 1 to 7, shall be performed. A minimum of three batches s

30、hall be tested for qualification purposes. 5.2 Batch acceptance testing For batch acceptance the tests marked with the symbol * shall be performed. Table 1 - General requirements Material description Formulation Preparation Technical specification Marking Storage stability Application and use Drying

31、 conditions Freedom from defects Quality assurance Packaging Health and safety Lead and chromate free epoxy primer with corrosion resistance for aerospace applications Base - epoxy resin Activator with amino functional groups Thinner These components shall be mixed in simple whole number proportions

32、, by volume or weight, in accordance with the manufacturerss instructions. EN 3840 See EN 3840. See EN 3840. Dry film thickness of (25 f 5) pm IS0 3270 for 168 h before testing. See EN 3840. See EN 3840. See EN 3840. See EN 3840. Copyright Association Europeene des Constructeurs de Materiel Aerospat

33、ial Provided by IHS under license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 6 prEN 2436-06:2005 I* Table 2 - Physical and chemical characteristics - Delivery conditions Non volatile matter 2 reference value 2 reference 2 reference value value k

34、 2 % ref. k 2 % ref. 10 Fineness of grind Test Test criteria Test req ui remen ts according to EN 3840 * - test method IS0 1513 (as received in the original container) Condition requirement Shall be free from extraneous matter and show no skinning, gelling, hard settlement, or other defect which wil

35、l prevent satisfactory application to produce a defect free film. IS0 3251 test method requirement % I base I activator I thinner k 2 % ref. k 2 % ref. value ab I valueab I- 49 IS0 1 1890-1, IS0 1 1890-2 base + activator + thinner g/l I ref. value IS0 3679 or IS0 3680 Volatile organic content (VOC)

36、(Type II only) test method test condition requirement test method 7 Flash point requirement “C I base I activator I thinner 8* I test method I IS02431 Flow time I :idition I base + activator I requirement I s k IO % ref. value ab 5 I Sedimentation I test method I EN 3847 rating I base + activator +

37、thinner test condition Irequirement m1/4 h I g30 I test method I IS0 281 1 I :idition I IS03270 base I activator I thinner requirement g/cm3 4* I Density I test method IS0 3675 IS0 3270 test condition hydrometer requirement g/cm3 base I activator thinner k 1 %ref. I valueab k 1 % ref. value ab test

38、method IS0 15 4 requirement base I activator thinner 30 I continued I I Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS under license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 7 prEN 2436-06:2005 Test T

39、able 2 - Physical and chemical characteristics - Delivery conditions (concluded) Test criteria Tests according to EN 3840 Pot life * - requirements The paint film applied shall result in a opaque even finish free from runs, sags, wrinkling, pin holing or other defects. test method IS0 9514 20 * sor

40、Pas 21 * Equal to the ref. value after 4 h, and shall meet or fulfil all the specification requirements. 22 * pretreatment coating 23 * EN 3837 - Process A, B or C coating to this standard Drying time - Print free test Test requirements test method IS0 3678 panel EN 3837 - A2 Application, 1 test met

41、hod 1 none properties and panel finish EN 3837 - A2 pretreatment coating coating to this standard EN 3837 - Process A or B or C pretreatment coating I :idition I IS03270 EN 3837 - Process A, B or C coating to this standard requirement Surface dry time h Type I 4 using a mass of 1 O00 g Type II 5 usi

42、ng a mass of 1 O00 g base + activator + thinner I :idition Through dry time requirement test method IS0 91 17 panel EN 3837 - A2 test method pretreatment coating panel EN 3837 - Process A, B or C coating to this standard EN 3837 - A2 I :idition I IS03270 requirement I h I Type I 1 Type II 2,5 I :idi

43、tion I IS03270 I :idition I IS03270 I requirement I h I 16 a The deviation is that compared to the reference value (see Note ). The reference value is that established during qualification. Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS under license with A

44、ECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 8 prEN 2436-06:2005 29 * Table 3 - Mechanical and physical characteristics - Dried film Scratch resistance test method pretreatment panel IS0 1518 EN 3837 - Process A or B or C EN 3837 - A2 test method panel

45、IS0 1520 EN 3837 - A:, test method panel IS0 7724 EN 3837 - A:, 31 requirement To be agreed between purchaser and supplier IR reflection test method EN 3840. annex E panel factor (Class B only) pretreatment EN 3837 - A2 EN 3837 - Process A, B or C 25 Bend test requirement test method To be agreed be

46、tween purchaser and supplier IS0 1519 pretreatment coatina EN 3837 - Process B coatina to this standard Test criteria n Test Test req ui remen ts according to EN 3840 24 * I test method I IS0 2409 Cross cut I panel I EN 3837 - A2 I pretreatment EN 3837 - Process A or B and C (B and C are I preferred

47、) I coating I coating to this standard I =Adition I IS03270 I coating I coating to this standard I =Adition I IS03270 I I I requirement I 2 1 500 g a 46 * Slow deformation I pretreatment I EN 3837 - Process B and C coating I coating to this standard I =Adition I IS03270 I requirement I 2 3 mm 30 * C

48、olour I pretreatment I EN 3837 - Process A, B or C coating I coating to this standard I =Adition I IS03270 coating I coating to this standard I =Adition I IS03270 cylindrical mandrel I panel I EN 3837 - A6 I =Adition I (-55k2)“C I I reauirement I mandrel - 6 mm a Substrate not exposed No cracking or

49、 detachment (x10 magnification) Copyright Association Europeene des Constructeurs de Materiel Aerospatial Provided by IHS under license with AECMANot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Page 9 prEN 2436-06:2005 pretreatment coating Tests according to EN 3840 EN 3837 - Process B and C coating to this standard 38 requirement 37 EN 3840 test 24 classificatio

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