1、Designation: B 69 01a (Reapproved 2005)Standard Specification forRolled Zinc1This standard is issued under the fixed designation B 69; the number immediately following the designation indicates the year of originaladoption or, in the case of revision, the year of last revision. A number in parenthes
2、es indicates the year of last reapproval. A superscriptepsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers two types of commercial rolledzinc as describ
3、ed in 1.2. It should be understood that thespecification is general. Any closer limitations on permissiblevariations shall be a matter of agreement between the supplier(manufacturer) and the purchaser.1.2 Rolled zinc is furnished in two types as follows:1.2.1 Type I - Coils or sheets cut from strip
4、(ribbon) rolledzinc and1.2.2 Type II - Zinc plates such as boiler and hull platesproduced by any rolling method.1.3 The values stated in inch-pound units are to be regardedas the standard. The values given in parentheses are forinformation only.1.4 This standard does not purport to address all of th
5、esafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to become familiarwith all hazards including those identified in the appropriateMaterial Safety Data Sheet (MSDS) for this product/materialas provided by the manufacturer, to establish appropriate
6、safety and health practices, and determine the applicability ofregulatory limitations prior to use.2. Referenced Documents2.1 The issue of each of the following reference documentsshall be that which is current on the date the purchase order isaccepted by the supplier (manufacturer).2.2 ASTM Standar
7、ds:2B 899 Terminology Relating to Non-ferrous Metals andAlloysE8 Test Methods for Tension Testing of Metallic MaterialsE18 Test Methods for Rockwell Hardness and RockwellSuperficial Hardness of Metallic MaterialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with Spec
8、ificationsE55 Practice for Sampling Wrought Nonferrous Metals andAlloys for Determination of Chemical CompositionE60 Practice for Analysis of Metals, Ores, and RelatedMaterials by Molecular Absorption SpectrometryE88 Practice for Sampling Nonferrous Metals and Alloysin Cast Form for Determination of
9、 Chemical CompositionE 384 Test Method for Microindentation Hardness of Ma-terialsE 527 Practice for Numbering Metals and Alloys (UNS)E 536 Test Methods for ChemicalAnalysis of Zinc and ZincAlloysE 634 Practice for Sampling of Zinc and Zinc Alloys forOptical Emission Spectrometric Analysis3. Termino
10、logy3.1 Terms shall be defined in accordance with TerminologyB 899.3.2 Definitions of Terms Specific to This Standard:3.2.1 coiled sheet, nsheet coils with either slit or unslitedges.3.2.2 flat sheet, nsheet with sheared, slit, or sawed edgesthat has been flattened or leveled.3.2.3 plate, nrolled pr
11、oduct, rectangular in cross sectionand form, or thickness of more than 0.125 in. (3.175 mm) witheither untrimmed, sheared or sawed edges.3.2.4 ribbon anode, na long, continuous sacrificial anodeshape, with a diamond, square, rectangular, oval, or othercross-section, most commonly made of zinc, magne
12、sium oraluminum, having a core wire normally made of steel, that isusually supplied in coils or reels of 100 to 3600 ft dependingupon size and cross-section.3.2.5 rolled zinc, nwrought zinc or zinc alloy sheet, strip,or plate produced by hot and/or cold rolling.3.2.6 sheet, nrolled product, rectangu
13、lar in cross sectionand form of thickness of 0.003 in. (0.076 mm) through 0.125in. (3.175 mm) with sheared, slit, untrimmed or sawed edges.4. Ordering Information4.1 Orders for materials under this specification shall in-clude the following information:4.1.1 ASTM designation and year of issue,1This
14、specification is under the jurisdiction of ASTM Committee B02 onNonferrous Metals and Alloys and is the direct responsibility of SubcommitteeB02.04 on Zinc and Cadmium.Current edition approved Nov. 1, 2005. Published February 2006. Originallyapproved in 1926. Last previous edition approved in 2001 a
15、s B 69 - 01a.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1*A Summary of Changes section appears at the en
16、d of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.4.1.2 Quantity (weight),4.1.3 Name of material (rolled zinc),4.1.4 Type of rolled zinc,4.1.5 Dimensions (thickness, width, length, or coil),4.1.6 Chemical composition/
17、alloy, and4.1.7 Others as agreed upon between the purchaser and thesupplier.5. Materials and Manufacture5.1 The supplier (manufacturer) shall ensure that each rolledzinc product:(a) conforms to the chemical composition specified in thepurchase order,(b) is free of deleterious inclusions, and(c) is o
18、f satisfactory appearance.The products covered by this specification shall be producedby casting, rolling, and other processes found in a mill productplant.6. Chemical Composition6.1 AlloysThe material shall conform to the chemicalrequirements prescribed in Table 1.7. Mechanical Properties7.1 The ma
19、terial shall conform to the mechanical propertyrequirements in the longitudinal rolling direction in Table 2.7.1.1 The testing wrought zinc for determination of tensileproperties shall be conducted in accordance with Test MethodsE8, with the additional recommendation that the rate ofseparation of th
20、e heads during a test be maintained between0.115 to 0.135 in/in/min (0.115 to 0.135 mm/mm/min) at roomtemperature (68 to 75F (20 to 24C) suggested).7.1.2 The testing of zinc for hardness shall be made on aRockwell superficial hardness tester set up for the 15T scale, inaccordance with Test Methods E
21、 18, or on a microhardnesstester, in accordance with Test Method E 384. Zinc is a timedependent material; therefore, the dwell time of the major loadshall be specified between supplier and customer, for example,4to15s.8. Dimensions and Permissible Variations8.1 ThicknessThe permissible variations in
22、 thickness ofrolled zinc shall be as specified in Table 3, along the length ofthe coil shall be made within 12 in. (305 mm) of each other, norTABLE 1 Chemical Composition of Rolled Zinc AlloysAAlloy (UNS)BCu Pb Fe Cd Ti Al Sn Mn Mg ZnRolled SpecialHigh Grade Zinc(Z13004)0.003 max 0.003 max 0.003 max
23、 0.003 max . . . 0.002 max 0.001 max. .CCommerciallyPure Rolled Zinc(Z15006)0.08 max 0.03 max 0.02 max 0.01 max 0.02 max 0.01 max 0.003 max. .CZinc-Low CopperRolled Zinc Alloy(Z40101)0.08 to0.0400.01 max 0.01 max 0.005 max 0.02 max 0.01 max 0.003 max. .CZinc-High CopperRolled Zinc Alloy(Z40301)0.50
24、to1.00.01 max 0.01 max 0.005 max 0.04 max 0.01 max 0.003 max. .CZinc-Low Copper-Titanium Rolled ZincAlloy (Z41121)0.08 to0.490.01 max 0.01 max 0.005 max 0.05 to0.180.01 max 0.003 max. .CZinc-High Copper-Titanium Rolled ZincAlloy (Z41321)0.50 to1.000.01 max 0.01 max 0.005 max 0.08 to0.180.01 max 0.00
25、3 max. .CZinc-Lead RolledZinc Alloy (Z20301)0.005 max 0.10 max 0.01 max 0.01 max 0.02 max 0.002 max. . .CZinc-Lead-CadmiumRolled Zinc Alloy(Z21721)0.005 max 1.0 max 0.01 max 0.07 max 0.02 max 0.002 max. . .CZinc-Lead-Manganese RolledZinc Alloy (Z24311)0.005 max 0.03-0.08 0.01 max 0.005 max 0.02 max
26、0.002 max.0.015max0.0015 maxCZinc-AluminumRolled Zinc Alloy5.0 max 0.05 max 0.1 max 0.15 max 0.2 max 1.4 to 34.0 .003 max.0.10 maxCAThe following applies to all specified limits in this table: For purposes of determining conformance with this specification, the observed value or calculated valueobta
27、ined from analysis shall be rounded off to the nearest unit in the last right-hand place of figures used in expressing the specified limit, in accordance with the roundingmethod of Practice E29.BUNS designations were established in accordance with Practice E 527.CZinc: balance by difference.B 69 01a
28、 (2005)2shall measurement in any one line across the width of the coilbe used as a basis of rejection.8.2 WidthThe permissible variations in width of all typesof rolled zinc shall be as specified in Table 4.8.3 LengthThe permissible variations in length in alltypes of rolled zinc shall be as follows
29、: sheets, strips, and platesmay be ordered to exact lengths with the following variationsin length permitted, 6 0.125 in. (3.2 mm), or to a tolerancerange agreed to by buyer and seller.8.4 Sidewise Bend and Curvature (Camber)Type I rolledzinc in lengths over 10 ft (3048 mm) shall not exhibit sidewis
30、ebend or curvature in excess of 1 in. (25.4 mm) in any length of10 ft, or to a tolerance range agreed to by buyer and seller.9. Workmanship, Finish and Appearance9.1 The material shall be uniform in quality and finish,commercially straight or flat, and free of injurious imperfec-tions.10. Sampling10
31、.1 The sampling plan for zinc for purposes of chemicalanalysis or mechanical property testing shall be designed suchthat any lot of finished product may be adequately described bythe results of the tests performed on the samples. Lot or portionsize shall be as agreed upon between purchaser and suppl
32、ier.11. Chemical Analysis11.1 Samples for chemical analysis shall be taken in accor-dance with 10.1 and 11.2, 11.2.1 or 11.2.3 according to theform of zinc and zinc alloy to be analyzed and the analysismethod to be used.11.2 Samples from molten metal, cast, semi-finished orfinished product for optic
33、al emission spectrochemical analysisshall be sampled in accordance with Practice E 634.11.2.1 Samples for the analysis of metal from incomingmaterial in the ingot or slab form shall be taken in accordancewith Practice E 55. Drillings or millings shall be taken inapproximately equal weight from each
34、of the samples piecesselected in accordance with 10.1 and combined into onecomposite sample.11.2.2 Samples for the analysis of metal in the molten formtaken in the process of pouring of castings shall be taken in anadequate number and spacing such that the casting, simulta-neously poured castings, m
35、ay be described by the analysis ofthe sample(s).11.2.3 Samples for the analysis of metal in the cast formshall be sampled in accordance with Practice E 88.11.2.4 Samples for the analysis of metal in the semi-finishedor finished product form, shall be taken each 35 000 lbs.(15876 kg) or fraction ther
36、eof.11.3 Analysis Method to Be Used:11.3.1 The determination of chemical composition shall bemade in accordance with one or more of the following: anappropriate chemical method, Test Methods E 536, opticalemission spectrographic methods, or Practice E 60, Standardsfor such assay work shall be tracea
37、ble to NIST standards orother national standards.11.4 In the event that heat identification or traceability isrequired the purchaser shall specify the details desired.12. Inspection12.1 Inspection of the material shall be agreed upon be-tween the purchaser and the supplier (manufacturer) as part oft
38、he purchase agreement.13. Certification13.1 When specified on the purchase order, the supplier(manufacturer) shall furnish to the purchaser a certificateTABLE 2 Mechanical Properties of Rolled Zinc Alloys(Tensile Tested in Longitudinal Direction)Alloy (UNS) Tensile StrengthElongation%HardnessHR15Tks
39、i mpaRolled SpecialHigh Grade Zinc(Z13004)9-18 62-124 15-45 24-40CommerciallyPure Rolled Zinc(Z15006)10-18 69-124 15-60 28-45Zinc-Low CopperRolled Zinc Alloy(Z40101)12-27 83-186 28-60 34-64Zinc-High CopperRolled Zinc Alloy(Z40301)20-34 138-234 30-90 54-72Zinc-Low Copper-Titanium Rolled ZincAlloy (Z4
40、1121)14-28 96-193 30-70 35-67Zinc-High Copper-Titanium Rolled ZincAlloy (Z41321)20-34 138-234 30-90 54-72Zinc-Lead RolledZinc Alloy (Z20301)18-28 124-193 40-65 50-68Zinc-Lead-CadmiumRolled Zinc Alloy(Z21721)14-30 96-207 30-50 52-70Zinc-Lead-Manganese RolledZinc Alloy (Z24311)14 96-193 45-80 40-70Zin
41、c-AluminumRolled Zinc Alloy21-80 145-550 3-90 46-84TABLE 3 Permissible Variations in Thickness ofRolled ZincThickness, in. (mm) Tolerance, in. (mm)0.009 (0.229) and under) 10 % of thickness0.0100.030 (0.254 to 0.762) 6 0.001 (0.0254)0.0310.060 (0.787 to 1.524) 6 0.002 (0.0508)0.0610.090 (1.549 to 2.
42、286) 6 0.003 (0.0762)0.0910.125 (2.311 to 3.175) 6 0.004 (0.1016)0.126 and above (3.200 and above) 6 0.007 (0.1270)TABLE 4 Permissible Variations in WidthWidth Form Tolerance, in. (mm)Slit widths 6 0.010 (0.254)Sheared widths 6 0.062 (1.575) Type IB 69 01a (2005)3stating that each lot has been sampl
43、ed, tested, and inspected inaccordance with this specification and has met the require-ments.14. Packaging and Package Marking14.1 The material shall be separated by size and composi-tion, and prepared for shipment to ensure acceptance bycommon carrier for transportation and to afford protection fro
44、mthe normal hazards of transportation.14.2 Each shipping unit shall be legibly marked with thepurchase order number, metal or alloy designation, size, grossand net weight, and name of supplier. The specification numbershall be shown when required.15. Keywords15.1 rolled zinc; zinc; zinc alloys; zinc
45、 plate; zinc sheetSUMMARY OF CHANGESThis section contains the principal changes to the standard that have been incorporated since the last issue.(1) Definition for ribbon anode added.ASTM International takes no position respecting the validity of any patent rights asserted in connection with any ite
46、m mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical comm
47、ittee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a m
48、eeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive
49、, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).B 69 01a (2005)4
