1、Designation: D 2199 03 (Reapproved 2007)Standard Test Method forMeasurement of Plasticizer Migration From Vinyl Fabrics toLacquers1This standard is issued under the fixed designation D 2199; the number immediately following the designation indicates the year oforiginal adoption or, in the case of re
2、vision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers an accelerated test for themeasurement of a tendency for plasticizers in
3、finished vinylfabric to be transferred to coatings with which they come incontact.NOTE 1Age of fabric sample may affect results of test. To ensure mostreliable results, test with fabric sample closest in age to what will becoated.1.2 The values stated in SI units are to be regarded as thestandard. T
4、he values given in parentheses are for informationonly.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility
5、 of regulatory limitations prior to use.2. Summary of Test Method2.1 A small sample of vinyl fabric is placed on a condi-tioned coating film under a pressure of 3.45 kPa (12 psi). Theassembly is placed in an oven for 3 days at elevated tempera-ture. At the end of that time, the coating is examined f
6、ormarring or softening. For coatings that may block or print at50C or lower, a lower test temperature and a longer test timemay have to be used.3. Significance and Use3.1 Plasticizers in finished vinyl fabric can be transferred tocoatings with which they come in contact. When this takesplace, object
7、ionable marring and softening occur. This testmethod covers an accelerated test for measurement of thistendency.4. Apparatus4.1 Drawdown Blade, 125-m (5-mils) clearance to providea wet film of approximately 63 m (2.5 mils) in thickness.4.2 Plate Glass Panels.4.3 Window Glass, 51 by 51-mm (2 by 2-in.
8、) square, doublestrength.4.4 Sponge Rubber, 51 by 51-mm (2 by 2-in.) square by14in. (6.3 mm) thick.4.5 Weights, flat-bottom, sufficient to place a total weight of910 g (2 lb) on each test sample.4.6 Forced-Convection Oven, thermostatically controlled to62C.4.7 Photograph Roller.24.8 Aluminum Foil.5.
9、 Procedure5.1 Apply the coating to the glass panel with the drawdownblade to provide a uniform film with an area of at least a51-mm (2-in.) square and a dry thickness of at least 25 m (1mil) or as agreed upon. Dry the coating in accordance with therecommendations of the manufacturer or for a minimum
10、 of 24h at room temperature and2hat50C.5.2 Preheat the glass plate bearing the coating, the 51 by51mm (2 by 2-in.) glass square, and the weights for 30 min at50C. Place the square of vinyl fabric on the coating with careand ensure intimate contact by rolling with the photographicroller. Cover the fa
11、bric with foil, sponge rubber, glass, andweight in that order. The total weight shall be 910 g (2 lb).5.3 Place the assembly in the forced convection oven at atemperature of 50C for 72 h. After removal from the oven andcooling, remove the weight, sponge rubber, and aluminum foil,and carefully remove
12、 the vinyl fabric. Note and report anyresistance to removal. Wipe the surface of the fabric with a softrag dampened with heptane and examine for removal ofexuded plasticizer.6. Rating6.1 Rate the degree of migration by viewing the surface ofthe coating at a low angle against the light within 2 h aft
13、ertermination of heating and within 15 min of removal of thefabric.7. Report7.1 Report marring or softening, or both, on the scale of nochange, faint imprint, severe imprint, or marring.1This test method is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and App
14、lications and is the direct responsibility ofSubcommittee D01.55 on Factory Applied Coatings on Preformed Products.Current edition approved June 1, 2007. Published July 2007. Originally approvedin 1963. Last previous edition approved in 2003 as D 2199 03.2A squeegee-type roller is satisfactory.1Copy
15、right ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.7.2 If plasticizer is evident when the surface is wiped, thisshall be reported.8. Precision and Bias8.1 PrecisionIt is not possible to specify the precision ofthe procedure in Test Method D
16、2199 for measuring plasticizermigration since the test result is nonquantitative. Repeated testshave demonstrated that several laboratories will assign thesame rating to various coating fabric combinations. Also,replicate tests by one laboratory are in good agreement.8.2 BiasNo information can be pr
17、esented on the bias ofthe procedure in Test Method D 2199 for measuring plasticizermigration since no material having an acceptable referencevalue is available.9. Keywords9.1 lacquer; plasticizer migration; vinyl fabricsASTM International takes no position respecting the validity of any patent right
18、s asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any t
19、ime by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will
20、 receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM
21、 International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D 2199 03 (2007)2
