1、Designation: D 765 87 (Reapproved 2009)Standard Specification forRaw and Burnt Sienna Pigments1This standard is issued under the fixed designation D 765; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A
2、number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers the pigments commerciallyknown as raw sienna and burnt sienna.2. Referenced Documents2.1 ASTM Standards:2D50
3、Test Methods for Chemical Analysis of Yellow, Or-ange, Red, and Brown Pigments Containing Iron andManganeseD 185 Test Methods for Coarse Particles in PigmentsD 280 Test Methods for Hygroscopic Moisture (and OtherMatter Volatile Under the Test Conditions) in PigmentsD 387 Test Method for Color and St
4、rength of ChromaticPigments with a Mechanical MullerD 1208 Test Methods for Common Properties of CertainPigments3. Composition and Properties3.1 Dry PigmentsThe pigments shall conform to thefollowing requirements:3.1.1 Raw SiennaThe pigment shall be in a soft, dry formand shall be a hydrated oxide o
5、f iron permeating a siliceousbase. The pigment shall conform to the requirements forcomposition prescribed in Table 1.3.1.2 Burnt SiennaThe pigment shall be produced by thecalcination of raw sienna and shall conform to the requirementsfor composition prescribed in Table 1.3.2 Paste in OilFor both ra
6、w and burnt sienna, the pastein oil shall be made by thoroughly grinding the pigment withlinseed oil (with or without a small amount of volatile thinner)together with (where necessary) small amounts of wetting ordispersing agents to produce a paste or semipaste of satisfac-tory consistency. As recei
7、ved, it shall not be caked in thecontainer and shall break up readily in linseed oil to form asmooth paint of brushing consistency. It shall mix readily in allproportions, without curdling, with linseed oil, turpentine, orvolatile petroleum spirits, or any mixture of these substances.The paste shall
8、 conform to the following requirements:Pigment, min, % 60Nonvolatile vehicle, min, of vehicle 80Moisture by distillation, max, % 2.0Coarse particles and skins (total residue retained on a No. 325 (45-m)sieve), max, % of dry pigment1.03.3 The mass color and character of the tint and the tintingstreng
9、th formed by a mixture with a white pigment shall bewithin mutually agreed upon limits of a standard acceptable toboth the purchaser and the seller.4. Sampling4.1 Two samples shall be taken at random from differentpackages from each lot, batch, days pack, or other unit ofproduction in a shipment. Wh
10、en no markings distinguishingbetween units of production appear, samples shall be takenfrom different packages in the ratio of two samples for each 5tons (inch-pound or SI), except that for shipments of less than10 000 lb two samples shall be taken. At the option of thepurchaser, the samples may be
11、tested separately or afterblending in equal quantities the samples from the sameproduction unit to form a composite sample.5. Test Methods5.1 Tests shall be conducted in accordance with the appro-priate ASTM test methods. Test procedures not covered byASTM test methods shall be mutually agreed upon
12、by thepurchaser and the seller.5.1.1 Total Iron Oxide, Calcium Compound, and OrganicColoring MatterTest Methods D50.5.1.2 Coarse ParticlesTest Methods D 185.5.1.3 Pigment and Linseed Oil in Paste in OilTest Meth-ods D 1208.1This specification is under the jurisdiction of ASTM Committee D01 on Painta
13、nd Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.31 on Pigment Specifications.Current edition approved June 1, 2009. Published June 2009. Originallyapproved in 1944. Last previous edition approved in 2003 as D 765 87 (2003).2For referenced ASTM sta
14、ndards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.TABLE 1 Requirements for Composition of Raw and BurntSiennaRawSiennaBurntSiennaIron o
15、xide (Fe2O2), min, % 38 40Calcium compounds (as CaO) max, % 5.0 5.0Moisture and other volatile matter, max, % 4.0 4.0Coarse particles (total residue retained on a No. 325(45-m) sieve), max, %2.0 2.0Organic colors, max, % none none1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, Wes
16、t Conshohocken, PA 19428-2959, United States.5.1.4 Moisture in Paste in OilTest Methods D 280, exceptthat the sample shall be weighed instead of measured and theresults shall be expressed as percentage by weight instead ofvolume.5.1.5 Mass Color and Tinting StrengthTest MethodD 387.6. Keywords6.1 bu
17、rnt sienna; iron; manganese; pigment; raw siennaASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights,
18、 and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for rev
19、ision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you
20、 shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D 765 87 (2009)2
