1、Designation: F 30 96 (Reapproved 2009)Standard Specification forIron-Nickel Sealing Alloys1This standard is issued under the fixed designation F 30; the number immediately following the designation indicates the year of originaladoption or, in the case of revision, the year of last revision. A numbe
2、r in parentheses indicates the year of last reapproval. A superscriptepsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers iron-nickel alloys that areintended primarily for sealing to glass in electronic applica-tions.NOTE 1Some of these
3、 alloys may be used for sealing to ceramics, butthis specification in its present form is not intended to cover material formetal-to-ceramic seals.1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are
4、 provided for information onlyand are not considered standard.1.3 This standard does not purport to address the safetyconcerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety andhealth practices and determine the applicability of
5、 regulatorylimitations prior to use. The hazard statement pertains only tothe test method sections, Sections 10 and 12.2. Referenced Documents2.1 ASTM Standards:2E18 Test Methods for Rockwell Hardness of MetallicMaterialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance
6、with SpecificationsE112 Test Methods for Determining Average Grain SizeE 228 Test Method for Linear Thermal Expansion of SolidMaterials With a Push-Rod DilatometerF14 Practice for Making and Testing Reference Glass-Metal Bead-SealF 140 Practice for Making Reference Glass-Metal ButtSeals and Testing
7、for Expansion Characteristics by Polari-metric MethodsF 144 Practice for Making Reference Glass-Metal Sand-wich Seal and Testing for Expansion Characteristics byPolarimetric Methods3. Ordering Information3.1 Orders for material under this specification shall includethe following information:3.1.1 Si
8、ze,3.1.2 Temper (Section 6),3.1.3 Surface finish (Section 8),3.1.4 Marking and packaging (Section 16), and3.1.5 Certification if required.4. Chemical Composition4.1 The material shall conform to the requirements as tochemical composition prescribed in Table 1.5. Surface Lubricants5.1 All lubricants
9、used in processing shall be thoroughlyremoved. Protective coatings present on the material asshipped shall be readily removable by any of the commonorganic degreasing solvents.6. Temper6.1 The desired temper of the material shall be specified onthe purchase order. Unless otherwise specified, wire, r
10、od, bar,and tubing shall be given a final bright anneal by the manu-facturer. Strip and sheet shall be annealed properly to developdeep drawing properties. For deep drawing the hardness shallnot exceed Rockwell B82 for material 0.100 in. (2.54 mm) andless in thickness, and B85 for material over 0.10
11、0 in. thickwhen determined in accordance with Test Methods E 18.7. Grain Size7.1 Strip and sheet for deep drawing applications shall havean average grain size not larger than ASTM No. 5 (Note 2) andno more than 10 % of the grains shall be larger than No. 5when measured in accordance with Test Method
12、s E 112. For1This specification is under the jurisdiction of ASTM Committtee F01 onElectronics and is the direct responsibility of Subcommittee F01.03 on MetallicMaterials.Current edition approved May 1, 2009 Published July 2009. Originally approvedin 1977. Last previous edition approved in 2002 as
13、F 30 - 96 (2002).2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harb
14、or Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.materials less than 0.005 in. (0.13 mm) in thickness the grainsize shall be such that there are no less than 4 grains across thethickness.NOTE 2This corresponds to a grain size of 0.065 mm or 16 grains/in.of image of 1003.8. Surf
15、ace Finish8.1 The standard surface finishes available shall be thoseresulting from the following operations:8.1.1 Hot-rolling,8.1.2 Forging,8.1.3 Centerless grinding (rod),8.1.4 Belt polishing,8.1.5 Cold rolling, and drawing, and8.1.6 Wire drawing.9. Thermal Expansion Characteristics9.1 The average
16、linear coefficients of thermal expansionshall be within the limits specified in Table 2.10. Test for Thermal Expansion10.1 Determine the thermal expansion characteristics with aprecision dilatometer after heating the specimen as follows:10.1.1 Heat the specimen in a hydrogen atmosphere for 1 hat 900
17、C and then cool it from 900 to 200C at a rate notexceeding 5C/min.10.1.2 The thermal expansion properties are determined inaccordance with Test Method E 228.10.2 The thermal expansion match between the alloy and aglass may be evaluated by testing the assembly in accordancewith Practices F 14, F 140,
18、 or F 144.11. Dimensions and Permissible Variations11.1 Cold-Rolled StripCold-rolled strip shall conform tothe permissible variations in dimensions prescribed in Table 3,Table 4, and Table 5.11.2 Round Wire and RodWire and rod shall conform tothe permissible variations in dimension prescribed in Tab
19、le 6.11.3 Cold-Drawn TubingCold-drawn tubing, available ei-ther as seamless or welded, shall conform to the permissiblevariations prescribed in Table 7.12. Rounding Results12.1 Observed or calculated values obtained from analysis,measurements, or tests shall be rounded in accordance withPractice E 2
20、9, to the nearest unit in the last right place offigures used in expressing the specified limit.13. General Requirements13.1 The material shall be commercially smooth, uniform incross section, in composition, and in temper; it shall be freefrom scale, corrosion, porosity, cracks, seams, scratches, s
21、liv-ers, and other defects as best commercial practice will permit.14. Packaging and Package Marking14.1 Packaging shall be subject to agreement between thepurchaser and the seller.14.2 The material as furnished under this specification shallbe identified by the name or symbol of the manufacturer an
22、d bymelt number. The lot size for determining compliance with therequirements of this specification shall be one heat.15. Investigation of Claims15.1 Where any material fails to meet the requirements ofthis specification, the material so designated shall be handled inaccordance with the agreement mu
23、tually agreed upon by thepurchaser and the seller.16. Keywords16.1 glass-to-metal sealing applications; iron-nickel alloys;UNS K94600; UNS K94800; UNS N14052; vacuumelectronicsTABLE 1 Chemical RequirementsComposition, %42 AlloyUNSK9410046 AlloyUNSK9460048 AlloyUNSK9480051 Alloy52 AlloyUNSN14052Nicke
24、l,Anominal 41 46 48 51.5 50.5Manganese, max 0.80 0.80 0.80 0.60 0.60Silicon, max 0.30 0.30 0.30 0.30 0.30Carbon, max 0.05 0.05 0.05 0.05 0.05Chromium, max 0.25 0.25 0.25 0.25 0.25Cobalt, maxBBBBBPhosphorus, max 0.025 0.025 0.025 0.0250 0.025Sulfur, max 0.025 0.025 0.025 0.0250 0.025Aluminum, max 0.1
25、0 0.10 0.10 0.100 0.10Iron remainder remainder remainder remainder remainderAThe nickel contents listed are nominal. The nickel contents of the alloys shallbe adjusted by the manufacturer so that the alloys meet the requirements forthermal expansion. The 52Alloy is specifically intended to match lea
26、d (Pb) sealingglasses.BCobalt is present as an incidental element and shall be reported separately.TABLE 2 Thermal Expansion RequirementsAUNS Number Alloy No.TemperatureRange, CAverage LinearCoefficient ofThermalExpansion,m/mCK94100 42 30 to 300 4.0 to 4.730 to 450 6.7 to 7.4K94600 46 30 to 350 7.1
27、to 7.830 to 500 8.2 to 8.9K94800 48 30 to 400 8.2 to 9.230 to 550 9.6 to 10.3. 51 30 to 450 9.9 to 10.530 to 550 10.0 to 10.7N14052 52 30 to 450 9.7 to 10.230 to 550 10.0 to 10.5ATypical expansion data up to 1000C are given in the Appendix.F 30 96 (2009)2TABLE 3 Permissible Variations in Thickness o
28、f Cold-Rolled StripNOTE 1Measurements shall be made at least38 in. (9.5 mm) from the edge of strip that is over 1 in. (25.4 mm) wide.Specified Thickness, in. (mm)Permissible Variations in Thickness for Width Given, plus or minus, in. (mm)Under 3 (76) Over 3 to 6 (76 to 152) Over 6 to 12 (152 to 305)
29、Over 12 to 16 (305 to406)0.160 to 0.100 (4.06 to 2.54), incl 0.002 (0.051) 0.003 (0.076) 0.004 (0.102) 0.004 (0.102)0.099 to 0.069 (2.51 to 1.75), incl 0.002 (0.051) 0.003 (0.076) 0.003 (0.076) 0.004 (0.102)0.068 to 0.050 (1.73 to 1.27), incl 0.002 (0.051) 0.003 (0.076) 0.003 (0.076) 0.003 (0.076)0.
30、049 to 0.035 (1.24 to 0.89), incl 0.002 (0.051) 0.0025 (0.064) 0.003 (0.076) 0.003 (0.076)0.034 to 0.029 (0.86 to 0.74), incl 0.0015 (0.038) 0.002 (0.051) 0.0025 (0.064) 0.0025 (0.064)0.028 to 0.026 (0.71 to 0.66), incl 0.0015 (0.038) 0.0015 (0.038) 0.002 (0.051) 0.002 (0.051)0.025 to 0.020 (0.64 to
31、 0.51), incl 0.001 (0.025) 0.0015 (0.038) 0.002 (0.051) 0.002 (0.051)0.019 to 0.017 (0.48 to 0.43), incl 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038) 0.002 (0.051)0.016 to 0.012 (0.41 to 0.31), incl 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038) 0.0015 (0.038)0.011 to 0.0101 (0.28 to 0.26), incl 0.001 (0.
32、025) 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038)0.010 to 0.0091 (0.25 to 0.23), incl 0.001 (0.025) 0.001 (0.025) 0.001 (0.025) 0.001 (0.025)0.009 to 0.006 (0.23 to 0.15), incl 0.00075 (0.019) 0.00075 (0.019) . .Under 0.006 (0.15) 0.0005 (0.013) 0.0005 (0.013) . .TABLE 4 Permissible Variations in Thic
33、kness Across Width of Cold-Rolled StripSpecified Thickness, in. (mm)Maximum Variation in Thickness Across Width of Strip (Within Limits Specified in Table 3 for EdgeMeasurements) for Widths and Thicknesses Given, in. (mm)5 (127) and under Over 5 to 12 (127 to 305)Over 12 to 24 (305to 610), incl0.005
34、 to 0.010 (0.13 to 0.25), incl 0.00075 (0.019) 0.001 (0.025) 0.0015 (0.038)Over 0.010 to 0.025 (0.25 to 0.64), incl 0.001 (0.025) 0.0015 (0.038) 0.002 (0.051)Over 0.025 to 0.065 (0.64 to 1.65), incl 0.0015 (0.038) 0.002 (0.051) 0.0025 (0.064)Over 0.065 to 3/16 (1.65 to 4.8), excl 0.002 (0.051) 0.002
35、5 (0.064) 0.003 (0.076)TABLE 5 Permissible Variations in Width of Coil-Rolled Strip Supplied in CoilsSpecified Thickness, in. (mm)Permissible Variations in Width for Widths Given, plus or minus, in. (mm)Under12 to316 (12.7to 4.8)12 to 6 (12.7 to 152)Over 6 to 9 (152 to229)Over 9 to 12 (229 to305)Ove
36、r 12 to 20 (305 to508)0.187 to 0.161 (4.75 to 4.09) . 0.016 (0.41) 0.020 (0.51) 0.020 (0.51) 0.031 (0.79)0.160 to 0.100 (4.06 to 2.54) 0.010 (0.25) 0.010 (0.25) 0.016 (0.41) 0.016 (0.41) 0.020 (0.51)0.099 to 0.069 (2.51 to 1.75) 0.008 (0.20) 0.008 (0.20) 0.010 (0.25) 0.010 (0.25) 0.016 (0.41)0.068 (
37、1.73) and under 0.005 (0.13) 0.005 (0.13) 0.005 (0.13) 0.010 (0.25) 0.016 (0.41)F 30 96 (2009)3APPENDIX(Nonmandatory Information)X1. THERMAL EXPANSION DATAX1.1 Typical thermal expansion data for the alloys coveredby this specification are given in Table X1.1 for informationonly.TABLE 6 Permissible V
38、ariations in Diameter of Wire and RodSpecified Diameter, in. (mm) Permissible Variations in Diameter, plus or minus, in. (mm)Wire (Coiled, Spooled, or Straight Lengths)0.002 to 0.0043 (0.051 to 0.109) 0.002 (0.051)0.0044 to 0.0079 (0.112 to 0.201) 0.00025 (0.006)0.008 to 0.0149 (0.203 to 0.378) 0.00
39、03 (0.007)0.015 to 0.0199 (0.381 to 0.505) 0.0004 (0.010)0.020 to 0.0309 (0.508 to 0.785) 0.0005 (0.013)0.031 to 0.0409 (0.787 to 1.039) 0.0006 (0.015)0.041 to 0.0609 (1.041 to 1.547) 0.0007 (0.018)0.061 to 0.0809 (1.549 to 2.055) 0.0008 (0.020)0.081 to 0.1259 (2.057 to 3.198) 0.001 (0.025)0.126 to
40、0.1569 (3.200 to 3.985) 0.0015 (0.038)0.157 to 0.250 (3.99 to 6.35) 0.002 (0.051)Rod, Centerless Ground Finish (Straight Lengths)0.030 to 0.0549 (0.762 to 1.394) 0.0005 (0.013)0.055 to 0.1249 (1.397 to 3.172) 0.001 (0.025)0.125 to 0.499 (3.175 to 12.67) 0.0015 (0.038)0.500 to 0.999 (12.70 to 25.38)
41、0.002 (0.051)1.000 to 1.625 (25.40 to 41.27) 0.0025 (0.064)1.626 to 1.749 (41.30 to 44.43) 0.003 (0.076)1.750 to 1.999 (44.45 to 50.78) 0.004 (0.102)2.000 to 4.000 (50.80 to 101.60) 0.005 (0.13)TABLE 7 Permissible Variations in Dimensions of Standard TubingASpecified Outside Diameter, in. (mm) Outsi
42、de Diameter, in. (mm) Inside Diameter, in. (mm) Wall Thickness, plus or minus, %Under332 (2.4) + 0.002 (0.051) + 0.000 100.000 0.002 (0.051)332 to316 (2.4 to 4.8), excl + 0.003 (0.076) + 0.000 100.000 0.003 (0.076)316 to12 (4.8 to 12.7), excl + 0.004 (0.102) + 0.000 100.000 0.004 (0.102)12 to 112 (1
43、2.7 to 38.1), excl + 0.005 (0.127)0.000+ 0.0000.005 (0.127)10F 30 96 (2009)4ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validit
44、y of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comment
45、s are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not
46、 received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copi
47、es) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).TABLE X1.1 Typical Results of Thermal Expansion TestsTemperature Range, C Average Linear Coefficient of T
48、hermal Expansion, m/mC42 AlloyUNS K9410046 AlloyUNS K9460048 AlloyUNS K9480051 Alloy 52 AlloyUNS N1405230 to 300 4.4 7.5 8.8 10.2 10.130 to 400 6.0 7.5 8.7 10.2 9.930 to 500 7.9 8.5 9.4 10.1 9.930 to 600 9.6 9.8 10.4 11.0 10.830 to 700 10.5 10.7 11.3 11.9 11.730 to 800 11.4 11.6 12.1 12.7 12.530 to 900 12.3 12.5 13.0 13.5 13.330 to 1000 13.2 13.4 13.9 14.4 14.2F 30 96 (2009)5
