1、Designation: F 1186 03 (Reapproved 2008)e1Standard Classification System forChemicals According to Functional Groups1This standard is issued under the fixed designation F 1186; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the ye
2、ar of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.e1NOTEEditorially revised a footnote in February 2008.1. Scope1.1 This standard provides a classification system forchemica
3、l compounds whereby chemicals are assigned a 3-digitcode based primarily on chemical class.2Poly-functionalcompounds should be classified by all applicable code numbersassociated with their component functional groups.2. Significance and Use2.1 In many situations where chemicals are interacting with
4、other chemicals or materials, the interaction is strongly depen-dent and often correlated with the functional group(s) present.These interactions include chemical reaction, dissolution, andswelling/permeation of polymeric materials. For this reason, itis useful to have a standard means for classifyi
5、ng chemicals.2.2 One application for this classification system is in theselection of chemical protective clothing based on the chemicalresistance of the clothing materials.3,4,5Chemical resistancedata are available for only a very small fraction of thechemicals for which protective clothing is used
6、. However, forchemicals for which no data are available, a knowledge of thechemical class sometimes can give insight into the resistance ofa prospective clothing material.NOTE 1The present state of knowledge precludes reliable estimatesfrom chemical class alone.2.3 The classification system also fac
7、ilitates the develop-ment of predictive methodology by researchers in a variety offields, in addition to protective clothing.3. Terminology3.1 Definitions:3.1.1 functional groupthe atom or group of atoms thatdefines the chemical class of a particular family of organiccompounds and, at the same time,
8、 determines their properties.4. Basis of Classification4.1 Three-digit numbers were assigned to each class. Themajor classes generally were a multiple of 10 (printed in boldtype), with subclasses numbered between.4.2 Subcommittee F23.30 has jurisdiction for designatingnew classes. Proposals should b
9、e made to that group. The listwill be updated periodically through the ASTM ballotingprocess as needed; interim lists will be made immediatelyavailable from the subcommittee.4.3 See Annex A1 for the classification system.5. Keywords5.1 chemical classification; chemical resistance; chemicals;clothing
10、; protective; groups; functional1This classification system is under the jurisdiction ofASTM Committee F23 onPersonal Protective Clothing and Equipment and is the direct responsibility ofSubcommittee F23.30 on Chemicals.Current edition approved Feb. 1, 2008. Published February 2008. Originallyapprov
11、ed in 1988. Last previous edition approved in 2003 as F1186 03.2Classification in this guide is based on assignment of 3-digit codes, originallyfound in the Guidelines for the Selection of Chemical Protective Clothing, 3rd Ed.(Vols I and II), Schwope et al. NTIS Accession Nos. ADA179 516 andADA179 1
12、64, to the groups listed in the Functional Group Index, Kodak LaboratoryChemicals, Kodak Laboratory Products Catalog No. 53, 19871988, p 1f30f.3Chemical Protective Clothing Permeation and Degradation Database, K.Forsberg et al., Lewis Publisher, CRC Press Inc., 2000 Corporate Blvd., N.W., BocaRaton,
13、 FL 33431-9964.4Guidelines for the Selection of Chemical Protective Clothing, Johnson et al.,U.S. Dept. of Energy Report DE-02357T, 1991.5Quick Selection Guide to Chemical Protective Clothing, 5thed., Forsberg andMansdorf, John Wiley and Sons, Inc., Hoboken, NJ (2007) ISBN 978-0-470-14681-1.1Copyrig
14、ht ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.ANNEX(Mandatory Information)A1. CLASSIFICATION OF CHEMICALS/CHEMICAL CLASS NUMBERSCLASS CHEMICAL CLASS/SUBCLASS NAME100 Acids Carboxylic102 Aliphatic and Alicyclic, Unsubstituted103 Aliphatic a
15、nd Alicyclic, Substituted104 Aliphatic and Alicyclic, Polybasic105 Aromatic, Benzoic106 Aromatic, Others110 Acid Halides, Carboxylic111 Aliphatic and Alicyclic112 Aromatic113 Chloroformates120 Aldehydes121 Aliphatic and Alicyclic122 Aromatic130 Amides132 Aliphatic and Alicyclic133 Aromatic134 Acetan
16、ilides135 Acrylamides137 Carbamides and Guanidines140 Amines141 Aliphatic and Alicyclic, Primary142 Aliphatic and Alicyclic, Secondary143 Aliphatic and Alicyclic, Tertiary145 Aromatic, Primary146 Aromatic, Secondary and Tertiary147 Alkyl-Aryl, Monoamines148 Aliphatic and Alicyclic Polyamines149 Arom
17、atic Polyamines150 Hydroxylamines and Ketoximes160 Anhydrides161 Aliphatic and Alicyclic162 Aromatic170 Azo/Azox4 Compounds210 Isocyanates211 Aliphatic and Alicyclic212 Aromatic220 Esters Carboxylic221 Formates222 Acetates223 Acrylates and Methacrylates224 Aliphatic, Others225 Lactones226 Benzoates
18、and Phthalates227 Aromatic, Others230 Esters Non-Carboxylic231 Ortho Esters232 Carbonates233 Carbamates and Others240 Ethers241 Aliphatic and Alicyclic242 Aromatic243 Alkyl-Aryl244 Ketals, Acetals245 Glycol Ethers246 Vinylic260 Halogen Compounds261 Aliphatic and Alicyclic263 Aromatic264 Vinylic265 A
19、llylic266 Benzylic270 Heterocyclic Compounds271 Nitrogen, Pyridines274 Nitrogen, Others275 Oxygen, Epoxides276 Carbohydrates277 Oxygen, Furans278 Oxygen, Others279 Sulfur280 Hydrazines290 Hydrocarbons291 Aliphatic and Alicyclic, Saturated292 Aromatic293 Aromatic Polynuclear294 Aliphatic and Alicycli
20、c, Unsaturated295 Acetylenes296 Polyenes and Poly-ynes300 Peroxides310 Hydroxylic Compounds311 Aliphatic and Alicyclic, Primary312 Aliphatic and Alicyclic, Secondary313 Aliphatic and Alicyclic, Tertiary314 Aliphatic and Alicyclic, Polyols315 Aliphatic and Alicyclic, Substituted316 Phenols317 Naphtho
21、ls318 Aromatic, Others330 Elements340 Inorganic Saltsand Inorganic Salt Solutions345 Inorganic Cyano Compounds350 Inorganic Gases and Vapors360 Inorganic Acid HalidesF 1186 03 (2008)e12365 Inorganic Acid Oxides370 Inorganic Acids380 Inorganic Bases390 Ketones391 Aliphatic and Alicylic392 Aromatic393
22、 Alkyl-Aryl410 Quinones430 Nitriles431 Aliphatic and Alicyclic432 Aromatic440 Nitro Compounds441 Unsubstituted442 Substituted450 Nitroso Compounds460 Organo-Phosphorus Compounds461 Phosphines462 Derivates of phosphourus-based acids470 Organo-Metallic Compounds480 Organo-Silicon Compounds500 Sulfur C
23、ompounds501 Thiols502 Sulfides and Disulfides503 Sulfones and Sulfoxides504 Sulfonic Acids505 Sulfonyl Chlorides506 Sulfonamides507 Sulfonates, Sulfates, and Sulfites508 Thiones509 Others510 Nitrates and Nitrites520 Ureas530 Zwittrerions550 Organic Saltsand Organic Salt Solutions590 MiscellaneousAST
24、M International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are en
25、tirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsa
26、nd should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee
27、on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).F 1186 03 (2008)e13
