1、BS EN ISO 105-C06:2010ICS 59.080.01NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDTextiles Tests forcolour fastnessPart C06: Colour fastness to domesticand commercial launderingThis British Standardwas published under theauthority of the StandardsPolicy and Str
2、ategyCommittee on 30 April2010. BSI 2010ISBN 978 0 580 65480 0Amendments/corrigenda issued since publicationDate CommentsBS EN ISO 105-C06:2010National forewordThis British Standard is the UK implementation of EN ISO 105-C06:2010. It supersedes BS EN ISO 105-C06:1997 which is withdrawn.The UK partic
3、ipation in its preparation was entrusted to TechnicalCommittee TCI/81, Colour fastness and colour measurement of textiles.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a con
4、tract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunityfrom legal obligations.EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 105-C06 March 2010 ICS 59.080.01 Supersedes EN ISO 105-C06:1997English Version Textiles - Tests for colour
5、 fastness - Part C06: Colour fastness to domestic and commercial laundering (ISO 105-C06:2010) Textiles - Essais de solidit des coloris - Partie C06: Solidit des coloris aux lavages domestiques et industriels (ISO 105-C06:2010) Textilien - Farbechtheitsprfungen - Teil C06: Farbechtheit bei der Haush
6、altswsche und der gewerblichen Wsche (ISO 105-C06:2010) This European Standard was approved by CEN on 18 February 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without
7、 any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language ma
8、de by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Fin
9、land, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES
10、KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 105-C06:2010: EEN ISO 105-C06:2010 (E) 3 Foreword This document (EN ISO 105-C06:2010) has been prepare
11、d by Technical Committee ISO/TC 38 “Textiles“ in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products”, the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endor
12、sement, at the latest by September 2010, and conflicting national standards shall be withdrawn at the latest by September 2010. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for i
13、dentifying any or all such patent rights. This document supersedes EN ISO 105-C06:1997. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
14、 Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 105-C06:201
15、0 has been approved by CEN as a EN ISO 105-C06:2010 without any modification. BS EN ISO 105-C06:2010INTERNATIONAL STANDARD ISO 105-C06:2010(E) ISO 2010 All rights reserved 1Textiles Tests for colour fastness Part C06: Colour fastness to domestic and commercial laundering 1 Scope This part of ISO 105
16、 specifies methods intended for determining the resistance of the colour of textiles of all kinds and in all forms to domestic or commercial laundering procedures used for normal household articles using a reference detergent. Industrial and hospital articles may be subjected to special laundering p
17、rocedures which may be more severe in some aspects. The colour loss and staining resulting from desorption and/or abrasive action in one single (S) test closely approximates to one commercial or domestic laundering. The results of one multiple (M) test may in some cases be approximated by the result
18、s of up to five domestic or commercial launderings at temperatures not exceeding 70 C. The M tests are more severe than the S tests because of an increase in mechanical action. These methods do not reflect the effect of optical brighteners present in commercial washing products. These methods are de
19、signed for the detergents and bleach systems given. Other detergents and bleach systems may require different conditions and levels of ingredients. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition
20、 cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 105-A01, Textiles Tests for colour fastness Part A01: General principles of testing ISO 105-A02, Textiles Tests for colour fastness Part A02: Grey scale for assessing change
21、in colour ISO 105-A03, Textiles Tests for colour fastness Part A03: Grey scale for assessing staining ISO 105-A04, Textiles Tests for colour fastness Part A04: Method for the instrumental assessment of the degree of staining of adjacent fabrics ISO 105-A05, Textiles Tests for colour fastness Part A0
22、5: Instrumental assessment of change in colour for determination of grey scale rating ISO 105-F01, Textiles Tests for colour fastness Part F01: Specification for wool adjacent fabric ISO 105-F02, Textiles Tests for colour fastness Part F02: Specification for cotton and viscose adjacent fabrics ISO 1
23、05-F03, Textiles Tests for colour fastness Part F03: Specification for polyamide adjacent fabric ISO 105-F04, Textiles Tests for colour fastness Part F04: Specification for polyester adjacent fabric BS EN ISO 105-C06:2010ISO 105-C06:2010(E) 2 ISO 2010 All rights reservedISO 105-F05, Textiles Tests f
24、or colour fastness Part F05: Specification for acrylic adjacent fabric ISO 105-F06, Textiles Tests for colour fastness Part F06: Specification for silk adjacent fabric ISO 105-F07, Textiles Tests for colour fastness Part F07: Specification for secondary acetate adjacent fabric ISO 105-F10, Textiles
25、Tests for colour fastness Part F10: Specification for adjacent fabric: Multifibre ISO 3696, Water for analytical laboratory use Specification and test methods 3 Principle A specimen of the textile in contact with specified adjacent fabric or fabrics is laundered, rinsed and dried. Specimens are laun
26、dered under appropriate conditions of temperature, alkalinity, bleaching and abrasive action such that the result is obtained in a conveniently short time. The abrasive action is accomplished by the use of a low liquor ratio and an appropriate number of steel balls. The change in colour of the speci
27、men and the staining of the adjacent fabric or fabrics are assessed by comparison with the grey scales or instrumentally. 4 Apparatus, materials and reagents 4.1 Suitable mechanical device, consisting of a water bath containing a rotatable shaft which supports, radially, stainless steel containers w
28、ith a diameter of (75 5) mm and a height of (125 10) mm, of capacity (550 50) ml, the bottom of the containers being (45 10) mm from the centre of the shaft. The shaft/container assembly is rotated at a frequency of (40 2) min1. The temperature of the water bath is thermostatically controlled to mai
29、ntain the test solution at the prescribed temperature 2 C. Other mechanical devices may be used for this test, provided that the results are identical to those obtained using the apparatus described. 4.2 Non-corrodible (stainless) steel balls, 6 mm in diameter. 4.3 Adjacent fabrics (see ISO 105-A01)
30、. Use either 4.3.1 or 4.3.2. NOTE Supplies of spun acetate may be limited due to decreased manufacturing. 4.3.1 A multifibre adjacent fabric, complying with ISO 105-F10, appropriate to the temperature used: a multifibre adjacent fabric DW1) containing wool and acetate (tests at 40 C and 50 C and in
31、certain cases, to be indicated in the test report, also at 60 C); a multifibre adjacent fabric TV2) not containing wool and acetate (in certain tests at 60 C, and in all tests at 70 C and 95 C). Consideration should be made in the use of multifibre with wool as the combination of temperature and sod
32、ium perborate at 60 C might be harmful to the wool. 4.3.2 Two single-fibre adjacent fabrics, complying with the relevant ISO 105-F01 to F07 standards. One of the adjacent fabrics shall be made of the same kind of fibre as that of the textile to be tested, or that predominating in the case of blends,
33、 and the second piece made of the fibre as indicated in Table 1 or, in the case of blends, of the kind of fibre second in order of predominance, or as otherwise specified. 1) DW = diacetate is the first yarn; wool is the second yarn. 2) TV = triacetate and viscose. BS EN ISO 105-C06:2010ISO 105-C06:
34、2010(E) ISO 2010 All rights reserved 3Table 1 Pairs of adjacent fabrics Second piece to be: If first piece is: For tests A and B For tests C, D and E Cotton Wool Viscose Wool Cotton Silk Cotton Viscose Wool Cotton Acetate Viscose Viscose Polyamide Wool or Cotton Cotton Polyester Wool or Cotton Cotto
35、n Acrylic Wool or Cotton Cotton 4.3.3 If required, a non-dyeable fabric (e.g. polypropylene). 4.4 Detergent, without optical brightener (WOB). 4.4.1 Detergent solution. A minimum volume of 1 litre of detergent solution shall be prepared, because of possible lack of homogeneity of the detergent powde
36、r. Either of the detergents in 4.4.2 or 4.4.3 may be used. 4.4.2 AATCC3)1993 Standard Reference Detergent WOB. The detergent is low-sudsing; the surfactants composing the detergent are anionic, with a small proportion of non-ionic, and are biodegradable. Properties and composition are given in Table
37、 2. 3) American Association of Textile Chemists and Colorists (AATCC), PO Box 12215, 1 Davis Drive, Research Triangle Park, North Carolina 27709 USA. Telephone: +1-919-549-8141; Fax: +1-919-549-8933; http:/www.aatcc.org/. BS EN ISO 105-C06:2010ISO 105-C06:2010(E) 4 ISO 2010 All rights reservedTable
38、2 AATCC 1993 Standard Reference Detergent WOB Composition Mass fraction % Linear alkylbenzene sulfonate sodium salta18 Sodium aluminosilicate solids 25 Sodium carbonate 18 Sodium silicate solidsb0,50 Sodium sulfate 22,13 Polyethylene glycolc2,76 Sodium polyacrylate 3,50 Silicone, suds suppressor 0,0
39、4 Moisture 10 Miscellaneous (unreacted in surfactant stocks) 0,07 Total 100 aC11.8LAS, introduced as Stepans Calsoft L-50-12. bSiO2/Na2O = 1,6. c2 % introduced via base granulates and 0,76 % introduced via a suds suppressor admixture. 4.4.3 ECE4)Detergent with Phosphates. In countries where perborat
40、es are used in laundering, the ECE Reference Detergent for colour fastness testing, without optical brightener, may be used. The nominal composition of the ECE Detergent with Phosphates is given in Table 3. NOTE Information on the availability of this detergent can be obtained from national standard
41、s organizations. 4) European Colourfastness Establishment (ECE), Gartenstrasse 5, D-14169 Berlin, Germany. BS EN ISO 105-C06:2010ISO 105-C06:2010(E) ISO 2010 All rights reserved 5Table 3 ECE Detergent with Phosphates Composition Mass fraction % Linear sodium alkylbenzenesulfonate (mean length of alk
42、ane chain C11,5) 8,0 0,02 Ethoxylated tallow alcohol (14 EO) 2,9 0,02 Sodium soap, chain length C12 C16: 13 % to 26 % C18 C22: 74 % to 87 % 3,5 0,02 Sodium tripolyphosphate 43,7 0,02 Sodium silicate (SiO2:Na2O = 3,3:1) 7,5 0,02 Magnesium silicate 1,9 0,02 Carboxymethylcellulose (CMC) 1,2 0,02 Ethyle
43、nediaminetetraacetic acid (EDTA), sodium salt 0,2 0,02 Sodium sulfate 21,2 0,02 Water 9,9 0,02 Total 100 4.5 If required, sodium carbonate (Na2CO3). 4.6 Sodium hypochlorite solution or lithium hypochlorite solution. The pH value and available chlorine content of a large number of trade-named solutio
44、ns of sodium hypochlorite (NaOCl) vary from pH 9,8 to pH 12,8 and the Cl2content from 40 g/l to 160 g/l. The actual available chlorine shall be determined before use and the following method is suggested. Pipette a 1,00 ml portion of the stock sodium hypochlorite solution into a conical flask and di
45、lute to 100 ml with grade 3 water (4.8). Add 20 ml of 294 g/l sulfuric acid (H2SO4) solution and 6 ml of 120 g/l potassium iodide (Kl) solution. Titrate with standard volumetric sodium thiosulfate solution, c(Na2S2O35H2O) = 0,1 mol/l. The available chlorine (Cl2) content is given, as a percentage by
46、 mass, by the formula 000,035 5100VcV where V0 is the volume, in millilitres, of sodium hypochlorite solution taken; 0is the density, in grams per millilitre, of the sodium hypochlorite solution; V is the volume , in millilitres, of sodium thiosulfate solution used; c is the amount of substance conc
47、entration, in moles per litre, of the sodium thiosulfate solution. 4.7 If required, sodium perborate tetrahydrate (NaBO34H2O). 4.8 Grade 3 water, complying with ISO 3696. 4.9 Grey scale for assessing change in colour, complying with ISO 105-A02. BS EN ISO 105-C06:2010ISO 105-C06:2010(E) 6 ISO 2010 A
48、ll rights reserved4.10 Grey scale for assessing staining, complying with ISO 105-A03. 4.11 Spectrophotometer or colorimeter for assessing change in colour and staining, complying with ISO 105-A04 and ISO 105-A05. 4.12 If required for souring treatment, acetic acid solution containing 0,2 g of glacia
49、l acetic acid per litre. 5 Test specimen 5.1 If the textile to be tested is fabric, either a) attach a specimen measuring (100 2) mm (40 2) mm to a piece of the multifibre adjacent fabric (4.3.1), also measuring (100 2) mm (40 2) mm, by sewing along one of the shorter edges, with the multifibre adjacent fabric next to the face side of the specimen, or b) attach a specimen measuring (100 2) mm (40 2) mm betw
