1、October 2016 English price group 22No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.040.40!%1:“2581423www.din.deD
2、IN EN 19694-5Stationary source emissions Determination of greenhouse gas (GHG) emissions in energyintensive industries Part 5: Lime industry;English version EN 196945:2016,English translation of DIN EN 19694-5:2016-10Emissionen aus stationren Quellen Bestimmung von Treibhausgasen (THG) aus energiein
3、tensiven Industrien Teil 5: Kalkindustrie;Englische Fassung EN 196945:2016,Englische bersetzung von DIN EN 19694-5:2016-10missions de sources fixes Dtermination des missions de gaz effet de serre (GES) dans les industries nergointensives Partie 5: Industrie de la chaux;Version anglaise EN 196945:201
4、6,Traduction anglaise de DIN EN 19694-5:2016-10www.beuth.deDocument comprises 60 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.This standard has been included in the VDI/DIN Handbook on air quality, Volume 2. 10.16 DIN EN 196
5、94-5:2016-10 2 A comma is used as the decimal marker. National foreword This document has been prepared by Technical Committee CEN/TC 264 “Air quality”, Working Group WG 33 “Greenhouse gas (GHG) emissions in energy-intensive industries”. The responsible German body involved in its preparation was th
6、e Kommission Reinhaltung der Luft im VDI und DINNormenausschuss KRdL (Commission on Air Pollution Prevention of VDI and DIN Standards Committee KRdL), Section I Umweltschutztechnik. The DIN Standards corresponding to the European and International Standards referred to in this document are as follow
7、s: EN 15442 DIN EN 15442 ISO 14040 DIN EN ISO 14040 ISO 14044 DIN EN ISO 14044 National Annex NA (informative) Bibliography DIN EN 15442, Solid recovered fuels Methods for sampling DIN EN ISO 14040, Environmental management Life cycle assessment Principles and framework DIN EN ISO 14044, Environment
8、al management Life cycle assessment Requirements and guidelines EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 19694-5 July 2016 ICS 13.040.40 English Version Stationary source emissions - Determination of greenhouse gas (GHG) emissions in energy-intensive industries - Part 5: Lime industry mi
9、ssions de sources fixes - Dtermination des missions de gaz effet de serre (GES) dans les industries nergo-intensives - Partie 5: Industrie de la chaux Emissionen aus stationren Quellen - Bestimmung von Treibhausgasen (THG) aus energieintensiven Industrien - Teil 5: Kalkindustrie This European Standa
10、rd was approved by CEN on 5 May 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such n
11、ational standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own la
12、nguage and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Gree
13、ce, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG C
14、EN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 19694-5:2016 EEN 19694-5:2016 (E) 2 Contents Page European foreword . 4 1 Scope 5 2 Normative references 6 3 Terms
15、 and definitions . 6 4 Symbols and abbreviations . 8 5 Introduction . 10 5.1 Overview of the lime manufacturing process 10 5.2 Direct greenhouse gas emissions from calcination of kiln stone (process emissions) 11 5.3 Direct greenhouse gas emissions from fuels for kiln operation (combustion emissions
16、) . 11 5.4 Energy indirect greenhouse gas emissions 12 6 System boundaries 12 6.1 Appropriate boundaries to distinguish . 12 6.2 Organizational boundaries . 12 6.3 Operational boundaries . 13 6.4 Sources and greenhouse gases to be included. 14 6.5 Internal lime transfers . 14 6.6 Assessment period .
17、 14 7 Principles 14 8 Determination of greenhouse gas emissions: general requirements . 15 8.1 Monitoring Plan and other requirements for identifying, calculating and reporting of greenhouse gas emissions 15 8.2 Stack-measurement-based method or mass-balance-based method . 15 9 Direct greenhouse gas
18、 emissions) and their determination 15 9.1 Sources of direct greenhouse gas emissions and the applicability of determination methods . 15 9.2 Direct CO2greenhouse gas emissions from the calcination of kiln stone (process emissions) using the mass-balance-based method . 16 9.3 Direct greenhouse gas e
19、missions from kiln fuels (combustion emissions) using the mass-balance-based method 26 9.4 Direct greenhouse gas emissions from non-kiln fuels (combustion emissions) using the mass-balance-based method 30 10 Energy indirect greenhouse gas emissions and their determination . 33 10.1 Overview of the s
20、ources of energy indirect greenhouse gas emissions . 33 10.2 Determination of the quantity of externally generated electricity used (activity data) 33 10.3 Determination of the emission factor for externally generated electricity 35 11 Other indirect greenhouse gas emissions from imported kiln stone
21、 and transport of kiln stone by third parties 35 11.1 Other indirect indirect greenhouse gas emissions, third party and of site transportation . 35 11.2 Greenhouse gas emissions from manufacture of imported kiln stone . 35 11.3 GHG from transport of kiln stone by third parties . 36 DIN EN 19694-5:20
22、16-10 EN 19694-5:2016 (E) 3 12 Reporting and performance assessment . 37 12.1 Reporting data to include 37 12.2 Performance assessment . 37 13 Uncertainty of GHG inventories . 39 13.1 General principles 39 13.2 Assessment of uncertainty for the mass-balance- base method . 39 13.3 Assessment of uncer
23、tainty for the stack-measurement-based method . 43 14 Verification / certification . 43 Annex A (informative) Objective and outcome of the site trails . 44 Annex B (normative) Minimum content of the monitoring plan 47 Annex C (informative) Details about the calculation of process emissions from lime
24、 kilns using the mass balance-based-method . 50 Annex D (informative) Example of an uncertainty calculation . 56 Bibliography . 58 DIN EN 19694-5:2016-10 EN 19694-5:2016 (E) 4 European foreword This document (EN 19694-5:2016) has been prepared by Technical Committee CEN/TC 264 “Air quality”, the sec
25、retariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2017, and conflicting national standards shall be withdrawn at the latest by January 2017. Attention is dr
26、awn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate M/478 given to CEN by the European Commission and the
27、 European Free Trade Association. This part of EN 19694 deals with sector-specific aspects for the determination of greenhouse gas (GHG) emissions from lime manufacture. This European Standard can be used to measure, report and compare the GHG emissions of a lime manufacturing plant. Data for indivi
28、dual plants, sites or works may be combined to measure, report and compare GHG emissions for an organization, corporation or group. EN 19694, Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy intensive industries is a series of standards that consists of the follo
29、wing parts: Part 1: General aspects Part 2: Iron and steel industry Part 3: Cement industry Part 4: Aluminium industry Part 5: Lime industry Part 6: Ferroalloy industry According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to imp
30、lement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romani
31、a, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 19694-5:2016-10 EN 19694-5:2016 (E) 5 1 Scope This European Standard provides a harmonized methodology for calculating GHG emissions from the lime industry. It includes the manufacture of lime, and any downstrea
32、m lime products manufactured at the plant, such as ground or hydrated lime. This standard allows for reporting of GHG emissions for various purposes and on different basis, such as plant basis, company basis (by country or by region) or international organization basis. Since lime is defined as the
33、generic name for quicklime, dolime and sintered dolime, plants manufacturing at least one of these products shall be covered by this standard. This European Standard addresses all of the following direct and indirect sources of GHG included as defined in ISO 14064-1: direct greenhouse gas emissions
34、from greenhouse gas sources that are owned or controlled by the company, such as emissions resulting from the following sources: calcination of carbonates and combustion of organic carbon contained in the kiln stone; combustion of kiln fuels (fossil kiln fuels, alternative fossil fuels, mixed fuels
35、with biogenic carbon content, biomass fuels and bio fuels) related to lime production and/or drying of raw materials; combustion of non-kiln fuels (fossil kiln fuels, mixed fuels with biogenic carbon content, biomass fuels and bio fuels) related to equipment and on-site vehicles, heating/cooling and
36、 other on-site uses; combustion of fuels for on-site power generation. indirect greenhouse gas emissions from the generation of imported electricity, heat or steam consumed by the organization; other indirect greenhouse gas emissions, other than energy indirect GHG emissions, which is a consequence
37、of an organizations activities, but arises from greenhouse gas sources that are owned or controlled by other organizations such as from imported kiln stone. This European Standard is to be used in conjunction with EN 19694-1, which contains generic, overall requirements, definitions and rules applic
38、able to the determination of GHG emissions for all energy-intensive sectors, provides common methodological issues and defines the details for applying the rules. The application of this standard to the sector-specific standards ensures accuracy, precision and reproducibility of the results and is f
39、or this reason a normative reference standard. Together these standards provide a harmonized method for: a) measuring, testing and quantifying methods for GHG emissions; b) assessing the level of GHG emissions performance of production processes over time, at production sites; c) establishment and p
40、rovision of reliable, accurate and quality information for reporting and verification purposes. GHG emissions offset mechanisms, including but not limited to voluntary offset schemes or nationally or internationally recognized offset mechanisms, shall not be used at any point in the GHG assessment a
41、ccording to this standard. DIN EN 19694-5:2016-10 EN 19694-5:2016 (E) 6 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated refere
42、nces, the latest edition of the referenced document (including any amendments) applies. EN 459-2, Building lime Part 2: Test methods EN 932-1, Tests for general properties of aggregates Part 1: Methods for sampling EN 12485, Chemicals used for treatment of water intended for human consumption Calciu
43、m carbonate, high-calcium lime, half-burnt dolomite, magnesium oxide and calcium magnesium carbonate Test methods EN 13639, Determination of total organic carbon in limestone EN 15442, Solid recovered fuels Methods for sampling EN 19694-1:2016, Stationary source emissions Determination of greenhouse
44、 gas (GHG) emissions in energy-intensive industries Part 1: General aspects ISO 5069-1, Brown coals and lignites Principles of sampling Part 1: Sampling for determination of moisture content and for general analysis ISO 13909 (all parts), Hard coal and coke Mechanical sampling ISO 18283, Hard coal a
45、nd coke Manual sampling ISO 14064-1, Greenhouse gases Part 1: Specification with guidance at the organization level for quantification and reporting of greenhouse gas emissions and removals 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 19694-1 and t
46、he following apply. 3.1 activity data information on material flow, consumption of fuel, input material or production output Note 1 to entry: Expressed as energy GJ or as mass or volume t or m3N in the case of fuels and mass or volume in the case of raw materials or products t or m3N. 3.2 dolime pro
47、duct resulting from the calcination of kiln stone consisting of calcium carbonate and magnesium carbonate 3.3 downstream lime product downstream lime products including Run-Of-Kiln lime (ROK), Lime Kiln Dust (LKD) and products made from them at the plant including ground lime and hydrated lime DIN E
48、N 19694-5:2016-10 EN 19694-5:2016 (E) 7 3.4 free CaO and MgO calcium oxide or magnesium oxide that has been produced in the kiln during the decarbonation of calcium carbonate or magnesium carbonate Note 1 to entry: The terminology free CaO and MgO as used in this standard may differ from the termino
49、logy applied in other standards. 3.5 kiln battery group of kilns at the same plant and of the same design EXAMPLE Parallel Flow Regenerative Kilns, Annular Shaft Kilns, Mixed Feed Shaft Kilns, Preheater Rotary Kilns or Long Rotary Kilns 3.6 kiln stone limestone that is fed into the kiln 3.7 lime LI generic name for quicklime, dolime or sintered dolime 3.8 lime kiln dust LKD partly calcined kiln stone ma
