1、December 2013Translation by DIN-Sprachendienst.English price group 14No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).IC
2、S 13.040.20; 43.020!%*zd“2078765www.din.deDDIN ISO 12219-1Interior air of road vehicles Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organiccompounds in cabin interiors (ISO 12219-1:2012),English translation of DIN ISO 12219-1:2013-12Innenraumluft von
3、 Straenfahrzeugen Teil 1: Gesamtfahrzeugprfkammer Spezifikation und Verfahren zur Bestimmung von flchtigen organischen Verbindungen inder Fahrgastzelle (ISO 12219-1:2012),Englische bersetzung von DIN ISO 12219-1:2013-12Air intrieur des vhicules routiers Partie 1: Enceinte dessai pour un vhicule comp
4、let Spcification et mthode de dtermination des composs organiques volatils dans leshabitacles dautomobiles (ISO 12219-1:2012),Traduction anglaise de DIN ISO 12219-1:2013-12www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 29 pages11.13Thi
5、s standard has been included in the VDI/DIN Handbooks on air quality, Volume 5.A comma is used as the decimal marker. Contents Page National foreword .3 National Annex NA (informative) Bibliography .5 Introduction .7 1 Scope .8 2 Normative references .9 3 Terms and definitions 9 4 Apparatus and mate
6、rials . 10 5 Principle . 11 6 Requirements of the whole vehicle test chamber, test vehicle and measurement procedures . 12 6.1 Requirements for the whole vehicle test chamber 12 6.2 Requirements for the test vehicle 14 6.3 Requirements for VOC and carbonyl compound air sampling and measurement metho
7、ds . 14 6.4 Blank measurements. 15 7 Standard test procedure . 16 7.1 General . 16 7.2 Pre-arrangements and preconditioning of the whole vehicle test chamber and the vehicle and performing the field blanks 16 7.3 Detailed description of the test procedure . 17 8 Calculation, presentation of results,
8、 and precision and uncertainty . 19 9 Performance characteristics 19 10 Quality assurance/quality control 19 Annex A (informative) Whole vehicle test chamber . 20 Annex B (informative) Temperature measuring points for parking mode . 21 Annex C (informative) Test report 22 Annex D (informative) Very
9、volatile organic compounds, volatile organic compounds, and semi-volatile organic compounds 27 Annex E (normative) Overview of the number of samples to be taken . 28 Bibliography . 29 2DIN ISO 12219-1:2013-12National foreword International technical regulation pertaining to indoor air This document
10、(ISO 12219-1:2013) has been prepared by Technical Committee ISO/TC 146 “Air quality”, Subcommittee SC 6 “Indoor air” and Technical Committee ISO/TC 22 “Road Vehicles”, Joint Working Group ISO/TC 22-ISO/TC 146/SC 6/WG 13 (JWG 13) “Determination of volatile organic components in car interiors” (Secret
11、ariat: DIN, Germany). The responsible German bodies involved in its preparation were the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section IV Umweltmesstechnik and the Working Group Innenraumemis
12、sion of the Verband der Automobilindustrie (VDA) (German Association of the Automotive Industry). The DIN Standards corresponding to the International Standards referred to in Clause 2 of this standard are as follows: ISO 3833 DIN 70010 ISO 16000-3 DIN ISO 16000-3 ISO 16000-6 DIN ISO 16000-6 ISO 160
13、17-1 DIN EN ISO 16017-1 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. National technical regulation pertaining to indoor air DIN ISO 12219 consists
14、 of the following parts, under the general title Interior air of road vehicles: Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors Part 2: Screening method for the determination of the emissions of volatile organic compo
15、unds from vehicle interior parts and materials Bag method Part 3: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Micro-scale chamber method Part 4: Screening method for the determination of the emissions of volatile org
16、anic compounds from vehicle interior parts and materials Small chamber method Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Static chamber method (in preparation) In addition to the DIN ISO 12219 series, the fo
17、llowing parts of DIN EN ISO/DIN ISO 16000 have been published dealing with the determination of VOCs: DIN ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method DIN ISO 16000-4, Indoor air Part 4: Determina
18、tion of formaldehyde Diffusive sampling method 3DIN ISO 12219-1:2013-12 DIN EN ISO 16000-5, Indoor air Part 5: Sampling strategy for volatile organic compounds (VOCs) DIN ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on
19、Tenax TA sorbent, thermal desorption and gas chromatography using MS/FID DIN EN ISO 16000-9, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN EN ISO 16000-10, Indoor air Part 10: Determination of the
20、 emission of volatile organic compounds from building products and furnishing Emission test cell method DIN EN ISO 16000-11, Indoor air Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test spec
21、imens DIN ISO 16000-24, Indoor air Part 24: Performance test for evaluating the reduction of volatile organic compounds and carbonyl compounds without formaldehyde concentrations by sorptive building materials DIN ISO 16000-25, Indoor air Part 25: Determination of the emission of semi-volatile organ
22、ic compounds by building products Micro-chamber method Further, reference is made to the following standards covering VOC measurement methods: DIN EN ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas ch
23、romatography Part 1: Pumped sampling and DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling 4DIN ISO 12219-1:2013-12National Annex NA (informative) Biblio
24、graphy DIN 70010, System of road vehicles Vocabulary of power-driven vehicles, combinations of vehicles and towed vehicles DIN EN 14412, Indoor air quality Diffusive samplers for the determination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 9169, Air qu
25、ality Definition and determination of performance characteristics of an automatic measuring system DIN EN ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling DIN EN
26、ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories DIN ISO
27、12884, Ambient air Determination of total (gas and particle phase) polycyclic aromatic hydrocarbons Collection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling
28、 method DIN ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS/FID DIN ISO 16362, Ambient air Determination of particle-phase polycyclic aromatic hydroca
29、rbons by high performance liquid chromatography DIN V ENV 13005, Guide to the expression of uncertainty in measurement VDA 276, Determination of organic substances as emitted from automotive interior products using a 1 m3test cabinet VDA 277, Non-metal automotive interior materials Determination of
30、the emission of organic compounds VDA 278, Thermal desorption analysis of organic emissions for the characterization of non-metallic materials for automobiles VDI 2464 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) GC/MS method for PCB 28, 52,
31、101, 138, 153, 180 VDI 2464 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) HR-GC/HR-MS method for coplanar PCBs VDI 2464 Part 3, Ambient air measurement Indoor air measurement Measurement of polybrominated diphenylether, hexabromocyclododecane
32、and hexabromobenzene VDI 3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with the sulfite pararosaniline method VDI 3484 Part 2, Gaseous ambient air measurements Indoor-air pollution measurements Me
33、asurement of the formaldehyde concentration with the acetylacetone method 5DIN ISO 12219-1:2013-12VDI 3498 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using large filters VDI 3498 Part 2, Ambient air measurement Ind
34、oor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4252 Part 2, Measurement of airborne microorganisms and viruses in ambient air Active sampling of bioaerosols Separation of airborne mould on gelatine/polycarbonate filters VDI 4253
35、Part 2, Measurement of airborne microorganisms and viruses in ambient air Culture based method for the determination of the concentration of mould in air Indirect method after sampling with gelatine/polycarbonate filters VDI 4300 Part 1, Indoor-air pollution measurement General aspects of measuremen
36、t strategy VDI 4300 Part 2, Indoor-air pollution measurement Measurement strategy for polycyclic aromatic hydro-carbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated biphenyls (PCBs) VDI 4300 Part 4, Indoor air pollution measurement Meas
37、urement strategy for pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Part 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Part 7, Indoor-air pollution measurement Measurement of indoor air change rate VDI 4300 Part 8, M
38、easurement of indoor air pollution Sampling of house dust VDI 4300 Part 9, Measurement of indoor air pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Part 10, Measurement of indoor air pollution Measurement strategies for determination of mould fungi in indoor environment VDI 4301 Pa
39、rt 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide Manual photometric method (Saltzman) VDI 4301 Part 2, Indoor air pollution measurement Measurement of pentachlorophenol (PCP) and -hexa-chlorocyclohexane (lindane) GC/MS-method VDI 4301 Part 3, Measurement
40、of indoor air pollution Measurement of pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) GC/ECD method VDI 4301 Part 4, Measurement of indoor air pollution Measurement of pyrethroids and piperonyl butoxide in air, house dust and solvent wipe samples VDI 4301 Part 5, Measurement of indoor
41、air pollution Measurement of flame retardants and plasticizers based on phosphor organic compounds Phosphoric acid ester VDI 4301 Part 6, Measurement of indoor air pollution Measurement of phthalates with GC/MS The following VDI Guideline is under preparation: VDI 4300 Part 11, Measurement of indoor
42、 air pollution Measurement strategies for determination of airborne particles in indoor environment PM2,5fraction 6DIN ISO 12219-1:2013-12IntroductionVolatile organic compounds (VOCs) are widely used in industry and can be emitted by many everyday products and materials. They have attracted attentio
43、n in recent years because of their impact on indoor air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is important to determine the material emissions of interior parts and to reduce them to an acceptable level, if required. Therefore it is necessary to obtain
44、 comprehensive and reliable information about the types of organic compounds in the interior air of vehicles and also their concentrations.This part of ISO 12219 outlines a method of measuring the types and levels of VOCs in vehicle cabin air under controlled conditions. It describes requirements fo
45、r a whole vehicle test chamber and a test protocol. Measurements are carried out according to ISO 16000-6 (VOCs) and ISO 16000-3 (carbonyl compounds).There are several national test methods available for measuring in-vehicle air quality, e.g. References 23. However, this part of ISO 12219 requires a
46、 fixed heating radiation system whereas the methods of References 23 define a fixed temperature programme.Before setting a fixed radiation density for heating the test vehicle, several validation measurements were performed (Reference 1).ISO 16000-3, ISO 16000-5,6ISO 16000-6, ISO 16000-9,7ISO 16000-
47、10,8ISO 16000-11,9ISO 16000-24,10ISO 16000-25,11as well as ISO 16017-1 and ISO 16017-212also focus on volatile organic compound (VOC) measurements.7DIN ISO 12219-1:2013-12WARNING It is the responsibility of the user of this part of ISO 12219 to establish appropriate safety and health practices and t
48、o determine the applicability of regulatory limitations prior to use. National regulations for precautions shall be followed.1 ScopeThis part of ISO 12219 describes and specifies the whole vehicle test chamber, the vapour sampling assembly and the operating conditions for the determination of volati
49、le organic compounds (VOCs), and carbonyl compounds in vehicle cabin air. There are three measurements performed: one (for VOCs and carbonyl compounds) during the simulation of ambient conditions (ambient mode) at standard conditions of 23 C with no air exchange; a second only for the measurement of formaldehyde at elevated temperatures (parking
