1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions Rev 04 2014 10 15 Re-Activated C. Mracna, NA 2010 01 07 N-STATUS No replacement named J. Crist, NA 1987 06 30 Released CZQ1-DR-535804-1 L.A. Graham B.M.M Controlled document at www.MATS Copyright 2014, Ford Global Technologies, LLC Page 1 of
2、3 NYLON/POLYPHENYLENE OXIDE ALLOY, PAINTABLE ESB-M4D545-A 1. SCOPE The material defined by this specification is an amorphous polyphenylene oxide polymer reinforcement of a crystalline polyamide (nylon). 2. APPLICATION This specification was released originally for material used for painted mirror h
3、ousings and plastic fender applications. NOTICE: This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties due to moisture absorption or loss in the service/assembly environment. Information on this material with respec
4、t to moisture should be obtained from the responsible PEO Materials Engineering Department. 3. REQUIREMENTS 3.0 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.3 CONDI
5、TIONING AND TEST CONDITIONS All test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% (test according to ISO R 960, Method B/ASTM D 789). All test materials immediately after processing have to be sealed in containers that are impermeable to water
6、vapor. If the moisture content exceeds 0.2%, condition the material for a minimum of 16 h at 40 - 50 C at a reduced pressure below 133 kPa. Conduct tests in a controlled atmosphere of 23 +/- 2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until i
7、mmediately before testing. 3.4 MOLDED TEST SPECIMEN 3.4.1 Preparation of Test Specimens All test specimens shall be injection molded in accordance with ISO 294/ASTM D 1897. The values of this specification are based on injection molded specimens unless otherwise specified. 3.4.2 Density 1.05 - 1.15
8、g/cm3 (ISO R 1183, Method A/ASTM D 792, Method A1) ENGINEERING MATERIAL SPECIFICATION ESB-M4D545-A Copyright 2014, Ford Global Technologies, LLC Page 2 of 3 3.4.3 Tensile Strength at Yield, min 55 MPa (ISO R 527/ASTM D 638, Type I, 3.2 x 12.7 x 165 mm specimens, 50 mm/min test speed) 3.4.3.1 Elongat
9、ion at Break, min 40% (Test Method acc. para 3.4.3) 3.4.4 Flexural Modulus, min 2.0 GPa (ISO 178/ASTM D 790, Method I, Procedure A, 3.2 x 12.7 x 127 mm specimen, 5 mm/min test speed) 3.4.5 Impact Strength, Izod, min (ISO 180, Method 4A/ASTM D 256, Method A, 3.2 x 12.7 x 63.5 mm specimen) 3.4.5.1 At
10、23 +/- 2 C 187 J/m 3.4.5.2 At -29 +/- 2 C 107 J/m 3.4.6 Vicat Softening Temperature, min (ISO 306, 10 x 10 x 3.2 +/- 0.2 mm specimens. Bath-silicone oil, temp. raise 50 +/- 5 C/h. Dial gage reset to “0“ after addition of weight.) 3.4.6.1 At 9.8 N 229 C 3.4.7 Instrumented Impact Strength (ASTM D 3763
11、, Dynatup) At -29 C 22.6 J 3.4.8 Heat Aging Performance (1000 h at 80 +/- 2 C) 3.4.8.1 Tensile Strength Change, max -10% (Test method per para 3.4.3) 3.4.8.2 Elongation Change, max -15% (Test method per para 3.4.3) 3.4.8.3 Impact Strength, Izod Change, max -25% (Test method per para 3.4.6.1) 3.4.9 W
12、ater Immersion, Expansion, max (FLTM BO 129-01) . After 24 h immersion 0.2% . After 240 h immersion 0.6% 3.4.10 Water Absorption, max (ISO 62/ASTM D 570) . 24 h immersion 0.5% . 240 h immersion 1.0% ENGINEERING MATERIAL SPECIFICATION ESB-M4D545-A Copyright 2014, Ford Global Technologies, LLC Page 3
13、of 3 3.5 FLAMMABILITY Burn Rate, max 100 mm/min (FLTM BN 024-02, without the lot sampling plan) In addition, the test specimen shall not exhibit any flashing or sudden flaming on either surface in excess of the above max value. 3.7 PAINTABILITY The material when painted must meet the requirements of
14、 engineering performance specifications shown on the engineering drawing, using coating materials approved by the responsible product materials engineering office. 5. GENERAL INFORMATION The information given below is provided for assistance and clarification in meeting the requirements of this spec
15、ification. Contact for questions concerning Engineering Material Specifications. 5.1 MOLD SHRINKAGE (ASTM D 955, after 48 h, injection molded sample) Unannealed 1.2 - 1.6% Annealed 1.5 - 1.7% (1 h at 163 C) 5.2 COEFFICIENT OF LINEAR THERMAL EXPANSION 9.0-12.6-5/ C (ASTM D 696, -30 to +30 C) 5.3 HEAT DEFLECTION TEMPERATURE, min (ISO 75/ASTM D 648, 3.2 x 12.7 x 127 mm specimen) 5.3.1 At 0.45 MPa 184 C 5.3.2 At 1.82 MPa 122 C
